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Addition of cadmium(II) nitrate to gallium-coordinated metal–organic C-alkylpyrogallol[4]arene nano-capsules affords a variation of the near spherical hexamer motif, structural changes in which are induced by the markedly different nature of the secondary incorporated metal.

Graphical abstract: Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres

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