Issue 37, 2009
From the journal:

Chemical Communications

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions†‡

Xiaochen Wang,a   Zhuoyan Lia  and  Michael P. Doyle*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
E-mail: mdoyle3@umd.edu
Fax: +1 301-314-2779
Tel: +1 301-405-1788

Abstract

Lewis bases, including reactant aldehydes, inhibit the rate of conversion for cycloaddition and those, like aldehydes or nitriles, cause a decrease in enantiocontrol due to the Lewis acidity of the activated complex.

Graphical abstract: Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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Article information

DOI
https://doi.org/10.1039/B913019E
Article type
Communication
Submitted
01 ဇူ 2009
Accepted
14 ဩ 2009
First published
26 ဩ 2009

Chem. Commun., 2009, 5612-5614

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Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

X. Wang, Z. Li and M. P. Doyle, Chem. Commun., 2009, 5612 DOI: 10.1039/B913019E

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