Antimony and bismuth cooperation to enhance the broad yellow photoluminescence of zero-dimensional hybrid halide

Jindong Cao, Jiawei Lin, Kunjie Liu, Yan Xiong, Na Wang, Shihui He, Xusheng Zhang, Zhongnan Guo, Xin Chen, Jing Zhao and Quanlin Liu

J. Mater. Chem. C, 2022, 10, 9841
DOI: 10.1039/D2TC01672A

Solvent-free mechanochemical syntheses of microscale lead-free hybrid manganese halides as efficient green light phosphors

Yue-Yu Ma, Ying-Rui Song, Wen-Jie Xu, Qian-Qian Zhong, Han-Qi Fu, Xue-Lei Liu, Cheng-Yang Yue and Xiao-Wu Lei

J. Mater. Chem. C, 2021, 9, 9952
DOI: 10.1039/D1TC02330F

Unravelling the structure–luminescence relationship in two dimensional antimony(iii)-doped cadmium(ii) halide hybrids

Ashwath Kudlu, Dhritismita Sarma, Deep Kumar Das, Alisha Basheer Shamla, Rangarajan Bakthavatsalam, Venkatesha R. Hathwar, Arup Mahata and Janardan Kundu

J. Mater. Chem. C, 2025, 13, 808
DOI: 10.1039/D4TC03543G

Synergistic electronic coupling/cross-talk between the isolated metal halide units of zero dimensional heterometallic (Sb, Mn) halide hybrid with enhanced emission

Anupam Biswas, Rangarajan Bakthavatsalam, Deep K. Das, Jisvin Sam, Bhupendra P. Mali, Chinmoy Biswas, Narugopal Maana, Stuart Thomson, Sai Santosh Kumar Raavi, Sreekumar Kurungot, Rajesh G. Gonnade, Sudipta Dutta and Janardan Kundu

J. Mater. Chem. C, 2022, 10, 360
DOI: 10.1039/D1TC04704C

Modulating photoelectron localization degree to achieve controllable photoluminescence quenching and activation of 0D hybrid antimony perovskites

Dong-Yang Li, Yu Cheng, Yu-Han Hou, Jun-Hua Song, Chuan-Ju Sun, Cheng-Yang Yue, Zhi-Hong Jing and Xiao-Wu Lei

J. Mater. Chem. C, 2022, 10, 3746
DOI: 10.1039/D1TC05807J

Intrinsic vs. extrinsic STE emission enhancement in ns2 ion doped metal (Cd, In) halide hybrids

Deep Kumar Das, Rangarajan Bakthavatsalam, Venkatesha R. Hathwar, Raghavaiah Pallepogu and Janardan Kundu

J. Mater. Chem. C, 2023, 11, 3855
DOI: 10.1039/D2TC04361K

Linear optical afterglow and nonlinear optical harmonic generation from chiral tin(iv) halides: the role of lattice distortions

Xiao Han, Puxin Cheng, Rongchao Shi, Yongshen Zheng, Siming Qi, Jialiang Xu and Xian-He Bu

Mater. Horiz., 2023, 10, 1005
DOI: 10.1039/D2MH01429G

Lead-free zero dimensional tellurium(iv) chloride-organic hybrid with strong room temperature emission as a luminescent material

Anupam Biswas, Rangarajan Bakthavatsalam, Vir Bahadur, Chinmoy Biswas, Bhupendra P. Mali, Sai Santosh Kumar Raavi, Rajesh G. Gonnade and Janardan Kundu

J. Mater. Chem. C, 2021, 9, 4351
DOI: 10.1039/D0TC05752E

Synthesis and structure-dependent optical properties of two new organic–inorganic hybrid antimony(iii) chlorides

Xuemei Wen, Juan Cheng, Peiqi Qian, Zhizhuan Zhang, Hongmei Zeng, Ling Huang, Guohong Zou and Zhien Lin

Dalton Trans., 2024, 53, 260
DOI: 10.1039/D3DT02867D

Modulating organic functional groups in stimuli-responsive luminescent antimony chlorides

Yi Liu, Dan-Dan Huang, Zhi-Zhuan Zhang, Hao-Wei Lin, Ke-Zhao Du, Ze-Ping Wang and Xiao-Ying Huang

J. Mater. Chem. C, 2024, 12, 11426
DOI: 10.1039/D4TC01344A

On structural factors determining the nature of the fluorescent properties of OIHMs based on 8-hydroxyquinoline

Marta Bogdan, Tomasz Sierański, Marcin Świątkowski and Agata Trzęsowska-Kruszyńska

CrystEngComm, 2023, 25, 1993
DOI: 10.1039/D3CE00061C

Bright and stable quaternary ammonium antimony halides for solid-state lighting

Shiqi Sui, Chuying Wang, Guangcai Hu, Yacong Li, Wen Meng, Jingwei Luo, Guangyong Xu and Zhengtao Deng

J. Mater. Chem. C, 2022, 10, 8938
DOI: 10.1039/D2TC00903J

Stabilized photoemission from organic molecules in zero-dimensional hybrid Zn and Cd halides

Tielyr D. Creason, Hadiah Fattal, Isaiah W. Gilley, Brett N. Evans, Jie Jiang, Ruth Pachter, Daniel T. Glatzhofer and Bayram Saparov

Inorg. Chem. Front., 2022, 9, 6202
DOI: 10.1039/D2QI01293F

Secret agent in the secret service: Utilization of Sb(iii)-based complexes’ emission properties for the study of forgery and document authenticity

Magdalena Rok, Aleksandra Krupińska, Marta Gordel-Wójcik, Przemysław Szklarz, Przemysław Starynowicz, Piotr Durlak, Rafał Janicki, Magdalena Malik, Ryszard Jakubas, Grażyna Bator and Anna Piecha-Bisiorek

J. Mater. Chem. C, 2025, 13, 17241
DOI: 10.1039/D5TC01333J

Advanced Optoelectronic Properties of Sb(III) based Metal Halides: Opportunities and Challenges

Tao Huang, Hui Peng, Ruosheng Zeng and Bingsuo Zou

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202511803

Low‐Melting Perovskite Glass for Multimodal Anti‐Counterfeiting and X‐Ray Imaging

Yuanyuan Wang, Xixi Cheng, Bobo Yang, Rongrong Hu, Qiaoyun Wu, Yukai Liu, Zhanyang Yu, Xiaoyan Yang, Qing Xia and Jun Zou

Advanced Optical Materials, 2025, 13
DOI: 10.1002/adom.202401950

Effects of Cl/Br substitution of antimony octahedra on photoluminescence and a new engineering strategy for performance optimization

J. Ding, X. Cui, Q. Ren, Y. Mao, J. Zhang, G. Zhou and X.-M. Zhang

Materials Today Chemistry, 2023, 27, 101275
DOI: 10.1016/j.mtchem.2022.101275

Realizing efficient emission and triple‐mode photoluminescence switching in air‐stable tin(IV)‐based metal halides via antimony doping and rational structural modulation

Xuefei He, Hui Peng, Qilin Wei, Zhijie Zhou, Guolun Zhang, Zhentao Du, Jialong Zhao and Bingsuo Zou

Aggregate, 2024, 5
DOI: 10.1002/agt2.407

Mn2+-Activated Zero-Dimensional Metal (Cd, Zn) Halide Hybrids with Near-Unity PLQY and Zero Thermal Quenching

Jumana Hasin Marayathungal, Deep Kumar Das, Rangarajan Bakthavatsalam, Jisvin Sam, Venkatesha R. Hathwar, Raghavaiah Pallepogu, Sudipta Dutta and Janardan Kundu

J. Phys. Chem. C, 2023, 127, 8618
DOI: 10.1021/acs.jpcc.2c08264

Achieving efficient self-trapped excitons emission by suppressing defect level in Sb3+ doped metal halide

Rong Chen, Fang Lin, Wenqing Wei, Mei Liu, Wanxu Zhang, Yongzhuo Zheng, Juan Wang and Fengwan Guo

Optical Materials, 2024, 157, 116196
DOI: 10.1016/j.optmat.2024.116196

Realizing High-Efficiency Yellow Emission of Organic Antimony Halides via Rational Structural Design

Hui Peng, Xuefei He, Qilin Wei, Ye Tian, Wenchao Lin, Shangfei Yao and Bingsuo Zou

ACS Appl. Mater. Interfaces, 2022, 14, 45611
DOI: 10.1021/acsami.2c14169

Bulk Coassembly of Zero-Dimensional Heterometallic Halide Hybrids for Broadband White Light Emission and Optical Thermometry

Jumana Hasin Marayathungal, Neeraja Puthuparambil, Deep K Das, Mini Kalyani, Rangarajan Bakthavatsalam and Janardan Kundu

J. Phys. Chem. C, 2023, 127, 18474
DOI: 10.1021/acs.jpcc.3c03645

Achieving Highly Efficient Orange Emission in Tin (IV)‐Based Metal Halides with Outstanding Anti‐Water Stability Through Antimony Doping and Reasonable Structural Modulation

Bao Ke, Hui Peng, Qilin Wei, Chengzhi Yang, Xueping Li, Weiguo Huang, Zhentao Du, Jialong Zhao and Bingsuo Zou

Advanced Optical Materials, 2024, 12
DOI: 10.1002/adom.202301665

Zero-dimensional antimony(III) halides templated by ruthenium complexes: photoluminescence, thermochromism and photo/electrical performances

Naixin Wu, Chun Chen, Shitong Lin, Haohong Li, Peipei He and Huidong Zheng

Inorganic and Nano-Metal Chemistry, 2023, 53, 428
DOI: 10.1080/24701556.2022.2075387

Insight into efficient photoluminescence regulation mechanism by lattice distortion and Mn2+ doping in organic-inorganic hybrid perovskites

Hui Wang, Chao Wang, Mengjiao Sun, Zhen Zhang and Guangjiu Zhao

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2023, 299, 122821
DOI: 10.1016/j.saa.2023.122821

Luminescent Behavior of Sb3+-Activated Luminescent Metal Halide

Tao Huang and Bingsuo Zou

Nanomaterials, 2023, 13, 2867
DOI: 10.3390/nano13212867

Breaking the Zero Dimensional Illusion in Te(IV) Metal Halide Hybrids via Electronic Dimensionality Control

Deep Kumar Das, Dhritismita Sarma, Venkatesha R. Hathwar, Arup Mahata and Janardan Kundu

J. Phys. Chem. Lett., 2026, 17, 761
DOI: 10.1021/acs.jpclett.5c03705

Tuning the Structure and Photoluminescence of [SbCl5]2−-Based Halides via Modification of Imidazolium-Based Cations

Guoyang Chen, Xinping Guo, Haowei Lin, Zhizhuan Zhang, Abdusalam Ablez, Yuwei Ren, Kezhao Du and Xiaoying Huang

Molecules, 2025, 30, 3431
DOI: 10.3390/molecules30163431

Modified luminescent properties from green afterglow to efficient orange emission in zirconium-based organometallic chloride scintillator by Sb3+ doping

R. Teng, P. Cai, X. Pu, X. Wang, Q. Ai, J. Si, X. Yao and Z. Liu

Materials Today Chemistry, 2023, 30, 101527
DOI: 10.1016/j.mtchem.2023.101527

Photo-excited carrier behaviors of two-dimensional tin halide perovskite single crystals

Yahui Li, Hongzhi Zhou, Zhihao Gong, Ming Xia, Yanxin Han, Xin Sheng, Tianyu Wang, Hua Wang, Haiming Zhu and Enzheng Shi

Cell Reports Physical Science, 2024, 5, 102020
DOI: 10.1016/j.xcrp.2024.102020

Achieving Dual-Color Luminescence via Halogen Regulation in Copper-Based Halides for Anticounterfeiting

Chenyi Zhang, Chuanrui Zhu, Baopeng Shan, Jiaxi Ding, Xiaowu Lei, Longyun Xu and Chuanying Shen

Inorg. Chem., 2025, 64, 17561
DOI: 10.1021/acs.inorgchem.5c03271

Sustainable and Efficient Low‐Energy Light Emitters: A Series of One‐Dimensional d10 Coinage Metal–Organic Chalcogenolates, [M(o‐SPhCO2H)]n

Oleksandra Veselska, Nathalie Guillou, Maria Diaz‐Lopez, Pierre Bordet, Gilles Ledoux, Sébastien Lebègue, Adel Mesbah, Alexandra Fateeva and Aude Demessence

ChemPhotoChem, 2022, 6
DOI: 10.1002/cptc.202200030

Discerning the Structure–Photophysical Property Correlation in Zero-Dimensional Antimony(III)-Doped Indium(III) Halide Hybrids

Alisha Basheer Shamla, Dhritismita Sarma, Deep Kumar Das, Vishnu Anilkumar, Rangarajan Bakthavatsalam, Arup Mahata and Janardan Kundu

J. Phys. Chem. Lett., 2024, 15, 8224
DOI: 10.1021/acs.jpclett.4c01839

Efficient tunable white emission and multiple reversible photoluminescence switching in organic Tin(IV) chlorides via regulating the host lattice environment of antimony ions for multifunctional applications

Linghang Kong, Hui Peng, Qilin Wei, Qihua Liang, Jialong Zhao and Bingsuo Zou

Journal of Colloid and Interface Science, 2024, 666, 560
DOI: 10.1016/j.jcis.2024.04.052

Predict before You Precipitate: Learning Templating Effects in Hybrid Antimony and Bismuth Halides

Jakob Blahusch, Konstantin S. Jakob, Johannes T. Margraf, Karsten Reuter and Bettina V. Lotsch

Chem. Mater., 2025, 37, 5027
DOI: 10.1021/acs.chemmater.5c00350

Competitive Dual-Emission-Induced Thermochromic Luminescence in Organic–Metal Halides

Zhi-Cheng Zhang, Tie Zhang, Chang-Yuan Su, Meng-Meng Lun, Yi Zhang, Da-Wei Fu and Qi Wu

Inorg. Chem., 2022, 61, 13322
DOI: 10.1021/acs.inorgchem.2c01182

Crystal structure, DFT calculations, vibrational characterization, and Hirshfeld surface analysis of a novel zero-dimensional metal-halide hybrid (C6H7ClN)3.[SbCl5].Cl exhibiting exceptional green emission

Assala Bahloul, Mehdi Messaad, Slim Salhi, Christelle Delaite, Thameur Dammak and Mohamed Abdelhedi

Journal of Molecular Structure, 2025, 1325, 141044
DOI: 10.1016/j.molstruc.2024.141044

Flexible Luminescent Fibers Based on Novel Antimony Halides Toward Advanced Anti‐Counterfeiting and Information Encryption

Tianrui Zhou, Yunluo Wang, Lin Zhou, Jianghua Wu, Zesheng Pan, Futing Sun, Hao Gu, Ruifeng Liu, Tingting Ye, Jingshan Hou, Yongzheng Fang, Jixuan Liu, Bin Liu, Minghui Wang, Haijie Chen, Lianjun Wang and Wan Jiang

Advanced Optical Materials, 2025, 13
DOI: 10.1002/adom.202402641

Environment-friendly and highly efficiency organic antimony halide scintillator for light emitting diode and X-ray imaging

Yijia Wang, Sijun Cao, Jun’an Lai, Kang An, Daofu Wu, Jinquan Chen, Haimen Mu, Zixian Wang, Linfeng Guo, Peng He and Xiaosheng Tang

Journal of Alloys and Compounds, 2025, 1024, 180205
DOI: 10.1016/j.jallcom.2025.180205

Low Dimensional, Broadband, Luminescent Organic‐Inorganic Hybrid Materials for Lighting Applications

Janardan Kundu and Deep Kumar Das

Eur J Inorg Chem, 2021, 2021, 4508
DOI: 10.1002/ejic.202100685

Structure–Property Relationships in Photoluminescent Bismuth Halide Organic Hybrid Materials

R. Lee Ayscue, Valérie Vallet, Jeffery A. Bertke, Florent Réal and Karah E. Knope

Inorg. Chem., 2021, 60, 9727
DOI: 10.1021/acs.inorgchem.1c01025

(C16H28N)2SbCl5: A new lead-free zero-dimensional metal-halide hybrid with bright orange emission

Hui Peng, Ye Tian, Zongmian Yu, Xinxin Wang, Bao Ke, Yueting Zhao, Tiantian Dong, Jianping Wang and Bingsuo Zou

Sci. China Mater., 2022, 65, 1594
DOI: 10.1007/s40843-021-1937-y

Antimony Doped Hybrid Zinc Halide Crystals with Tunable Light Emission and Long‐Term Stability

Yaqing Zhang, Yan Jiang, Qi Zhang, Qingyi Liu, Weiping Guo, Wei Zhang, Lingyun Li, Ya‐Nan Feng and Yan Yu

Advanced Optical Materials, 2024, 12
DOI: 10.1002/adom.202302641

Dual Monomeric Inorganic Units Constructed Bright Emissive Zero-Dimensional Antimony Chlorides with Solvent-Induced Reversible Structural Transition

Yue Guo, Shu-Fang Yan, Wen-Dong Yao, Hao-Yu Chen, Wenlong Liu, Jiajing Wu and Sheng-Ping Guo

Inorg. Chem., 2023, 62, 13692
DOI: 10.1021/acs.inorgchem.3c02135

Self-Trapped Exciton Emission in a Zero-Dimensional (TMA)2SbCl5·DMF Single Crystal and Molecular Dynamics Simulation of Structural Stability

Qilin Wei, Tong Chang, Ruosheng Zeng, Sheng Cao, Jialong Zhao, Xinxin Han, Lishuang Wang and Bingsuo Zou

J. Phys. Chem. Lett., 2021, 12, 7091
DOI: 10.1021/acs.jpclett.1c02119

Zero-dimensional antimony-based halides with efficient photoluminescence properties for visible light communication and nonlinear optics response

Yue Han, Sijun Cao, Peng He, Peng Feng, Hao Cui, Xiaoliang Xu, Xirong Ke, Mengyue Wu, Chen Chen and Xiaosheng Tang

Journal of Alloys and Compounds, 2025, 1044, 184506
DOI: 10.1016/j.jallcom.2025.184506

Sequential and Reversible Phase Transformations in Zero‐Dimensional Organic‐Inorganic Hybrid Sb‐based Halides towards Multiple Emissions

Bohan Li, Jiance Jin, Meijuan Yin, Xinlei Zhang, Maxim S. Molokeev, Zhiguo Xia and Yan Xu

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202212741

Improving Photoelectron Localization to Significantly Enhanced Broadband Orange‐Light Emission in Hybrid Antimony Halides with Sb─Cl Secondary Bonding

Jiantao Yuan, Zhikai Qi, Jian Zhang, Nan Zhang and Xian‐Ming Zhang

Laser & Photonics Reviews, 2024, 18
DOI: 10.1002/lpor.202301264

Facile preparation and crystallographic characterization of a new zero-dimensional antimony (III)-based organic-inorganic material with white light emission properties

Sahar Jarboui, Chakib Hrizi, Ali Ben Ahmed, Michael Knorr, Annika Schmidt, Carsten Strohmann and Fatma Zouari

Journal of Molecular Structure, 2025, 1338, 142329
DOI: 10.1016/j.molstruc.2025.142329

Halogen-Engineered Copper-Based Materials with Multicolor Emission for Dual-Functional Anticounterfeiting and LED Applications

Chenyi Zhang, Duanliang Wang, Chuanrui Zhu, Xiaowu Lei, Lingqiang Meng and Chuanying Shen

ACS Appl. Mater. Interfaces, 2025, 17, 43298
DOI: 10.1021/acsami.5c11245

Strong Dopant–Dopant Electronic Coupling in Emissive Codoped Two Dimensional Metal Halide Hybrid

Ashwath Kudlu, Deep Kumar Das, Rangarajan Bakthavatsalam, Jisvin Sam, Soumyadip Ray, Padmabati Mondal, Sudipta Dutta, Venkatesha R Hathwar, Raghavaiah Pallepogu and Janardan Kundu

J. Phys. Chem. Lett., 2023, 14, 4933
DOI: 10.1021/acs.jpclett.3c00902

Structural evolution and photoluminescence properties of hybrid antimony halides

Yue-Yu Ma, Hong-Mei Pan, Dong-Yang Li, Yu-Hang Liu, Tian Lu, Xiao-Wu Lei and Zhihong Jing

Journal of Solid State Chemistry, 2022, 314, 123404
DOI: 10.1016/j.jssc.2022.123404

New Strategy for Optimizing the Properties of Copper Halide Organic‐Inorganic Hybrid Lighting‐emitting Materials

Wei Liu, Zhennan Zhou, Haibo Li, Yi Lv, Hua Tong, Jialin Zhu and Gangfeng Ouyang

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202202478

Impact of Chiral Symmetry Breaking on Spin-Texture and Lone Pair Expression in Chiral Crystals of Hybrid Antimony and Bismuth Halides

Annalise E. Maughan, Gabrielle Koknat, Peter C. Sercel, Manoj K. Jana, Roman Brunecky, David B. Mitzi, Joseph J. Berry, Volker Blum and Matthew C. Beard

Chem. Mater., 2023, 35, 9086
DOI: 10.1021/acs.chemmater.3c01733

Light-Emitting 0D Hybrid Metal Halide (C3H12N2)2Sb2Cl10 with Antimony Dimers

Mingyang Li, Jiawei Lin, Kunjie Liu, Liubing Fan, Na Wang, Zhongnan Guo, Wenxia Yuan, Jing Zhao and Quanlin Liu

Inorg. Chem., 2021, 60, 11429
DOI: 10.1021/acs.inorgchem.1c01440

The effect of solvent on the formation of low-dimensional metal halides and their self-trapped exciton emission

Xiaochen Wang, Tianxin Bai, Jinglu Sun, Jianyong Liu, Yan Su and Junsheng Chen

Chemical Engineering Journal, 2024, 486, 150257
DOI: 10.1016/j.cej.2024.150257

Zhihong Jing

Yue-Yu Ma, Hong-Mei Pan, Dong-Yang Li, Yu-Hang Liu, Tian Lu, Xiao-Wu Lei and Zhihong Jing

SSRN Journal, 2022
DOI: 10.2139/ssrn.4092675

Precise Manipulation the Efficient Multi‐Exciton Emission with High Thermal Stability in Hybrid Manganese‐Antimony Chloride for Optical Thermometry, Anti‐Counterfeiting, and Information Encryption

Tao Huang, Qilin Wei, Tongzhou Li, Quan Niu, Weijian Li, Guanhan Huang and Bingsuo Zou

Advanced Optical Materials, 2024, 12
DOI: 10.1002/adom.202302384

Photoluminescence Enhancement through Anion Sublattice Engineering in (dien)In(Cl1–xBrx)6 Hybrid Halides

Aleksandra D. Valueva, Emily M. Chopra, Hope A. Long, Sergei A. Novikov and Vladislav V. Klepov

Chem. Mater., 2026
DOI: 10.1021/acs.chemmater.5c02901

Sequential and Reversible Phase Transformations in Zero‐Dimensional Organic‐Inorganic Hybrid Sb‐based Halides towards Multiple Emissions

Bohan Li, Jiance Jin, Meijuan Yin, Xinlei Zhang, Maxim S. Molokeev, Zhiguo Xia and Yan Xu

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202212741

Stepwise Crystalline Structural Transformation in 0D Hybrid Antimony Halides with Triplet Turn-on and Color-Adjustable Luminescence Switching

Jian-Qiang Zhao, Yue-Yu Ma, Xue-Jie Zhao, Yu-Jia Gao, Zi-Yan Xu, Pan-Chao Xiao, Cheng-Yang Yue and Xiao-Wu Lei

Research, 2023, 6
DOI: 10.34133/research.0094