Issue 23, 2013
From the journal:

RSC Advances

Dialkyl phosphite as a highly selective mono-N-alkylating agent using indium triflate under microwave irradiation†

Shrishnu Kumar Kundu,*a   Kanchan Mitraa  and  Adinath Majee*b  

* Corresponding authors

a Department of Chemistry, Jhargram Raj College, Midnapore(W), Jhargram, WB-721507, India
E-mail: shrishnuk@gmail.com

b Department of Chemistry, Visva-Bharati (A Central University), Santiniketan-731235, India
E-mail: adinath.majee@visva-bharati.ac.in

Abstract

Indium triflate catalyzed selective mono-N-alkylation of primary amines is reported using dialkyl phosphite as an alkylating agent under microwave irradiation. The mono-N-alkyl selectivity is largely accelerated when the conventional heating was replaced by the “greener” microwave irradiation. The overall procedure is operationally simple, mild, eco-friendly and straightforward.

Graphical abstract: Dialkyl phosphite as a highly selective mono-N-alkylating agent using indium triflate under microwave irradiation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3RA40509E
Article type
Communication
Submitted
29 Jan 2013
Accepted
08 Apr 2013
First published
10 Apr 2013

RSC Adv., 2013,3, 8649-8651

Permissions

Request permissions

Dialkyl phosphite as a highly selective mono-N-alkylating agent using indium triflate under microwave irradiation

S. K. Kundu, K. Mitra and A. Majee, RSC Adv., 2013, 3, 8649 DOI: 10.1039/C3RA40509E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements