The chemically reversible reduction of [Cr(TPP)(L)Cl](L =N-methylimidazole or pyridine; TPP = tetraphenylporphyrin) has been observed by low temperature cyclic voltammetry in dichloromethane at ca.–90°C.
P. O'Brien and D. A. Sweigart, J. Chem. Soc., Chem. Commun., 1986, 198 DOI: 10.1039/C39860000198
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