We report the preparation and characterisation of a cocrystal of triphenylphosphine with 1,3,5-trifluoro-2,4,6-triiodobenzene. The structure features a rare example of phosphorus acting as a halogen bond acceptor.
Y. Xu, J. Huang, B. Gabidullin and D. L. Bryce, Chem. Commun., 2018, 54, 11041 DOI: 10.1039/C8CC06019C
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