Issue 12, 1987

Rapid formation of a potent nitrosating agent by solvolysis of ionic nitrite in dichloromethane

Abstract

Bis(triphenylphosphine)nitrogen(1+) nitrite reacted extensively with dichloromethane at 25 °C to produce an intermediate that converted secondary amines also present in these solutions into carcinogenic nitrosamines in high yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 955-956

Rapid formation of a potent nitrosating agent by solvolysis of ionic nitrite in dichloromethane

J. C. Fanning and L. K. Keefer, J. Chem. Soc., Chem. Commun., 1987, 955 DOI: 10.1039/C39870000955

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