Metal-stabilised catenanes comprising two porphyrinoid-like macrocycles were obtained via the self-assembly of bipyrrole and dipyrromethane dialdehydes with bipyridyl-based diamine in the presence of a metal template. Reported architectures exhibited conformational flexibility and distinct photophysical properties, with dipyrrin-based systems displaying strong luminescence.
A. Sarwa, M. Matviyishyn, J. P. Perdek, B. Trzaskowski, D. Kulesza, E. Zych and B. Szyszko, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC05702G
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