Issue 74, 2024
From the journal:

Chemical Communications

Photochemical α-amination of carbonyl groups with iodinanes†

Suyuan He,a   Boya Feng, ORCID logo a   Yiben Tang,a   Ruiping Chen,a   Yujing Guoa  and  Rene M. Koenigs ORCID logo *a  

* Corresponding authors

a RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074 Aachen, Germany
E-mail: rene.koenigs@rwth-aachen.de

Abstract

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes. This aza Rubottom reaction provides a direct access towards α-amino carbonyl compounds under catalyst free reaction conditions with light as the sole source of energy. Control experiments suggest the participation of triplet nitrene intermediates.

Graphical abstract: Photochemical α-amination of carbonyl groups with iodinanes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D4CC03564J
Article type
Communication
Submitted
17 јул. 2024
Accepted
14 авг. 2024
First published
15 авг. 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 10128-10131

Permissions

Request permissions

Photochemical α-amination of carbonyl groups with iodinanes

S. He, B. Feng, Y. Tang, R. Chen, Y. Guo and R. M. Koenigs, Chem. Commun., 2024, 60, 10128 DOI: 10.1039/D4CC03564J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements