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Abstract | Cited by

In this study, we report on a fluorinated photoactive metal–organic framework (MOF), Zn-TFBD, capable of excellent light harvesting ability and higher water-assisted proton conductivity. Upon visible-light irradiation, selective 2,2,2-trifluoroethylation of 4-methoxystyrene was achieved on the heterogeneous photocatalyst, Zn-TFBD. This work has enriched the applications of fluorinated MOFs in the field of water-mediated organic transformations.

Graphical abstract: Integrating a fluorinated photoactive chromophore into metal–organic frameworks for selective trifluoroethylation of styrenes

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