Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Qiuxue Lai; Zhao-Qin Chu; Xinyi Xiao; Dejun Dai; Ting Song; Tian-Yi Luo; Wenlei Tang; Xuan Feng; Zhiyuan Zhang; Tao Li; Hai Xiao; Jing Su; Chong Liu

doi:10.1039/D2CC00213B

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks†

Qiuxue Lai,^a Zhao-Qin Chu,^b Xinyi Xiao,^a Dejun Dai,^c Ting Song,^a Tian-Yi Luo,

^d Wenlei Tang,^a Xuan Feng,^a Zhiyuan Zhang,^a Tao Li,

^c Hai Xiao,

^e Jing Su

*^b and Chong Liu

*^a

Author affiliations

* Corresponding authors

^a School of Chemical Engineering, Sichuan University, Chengdu, China
E-mail: liuchong@scu.edu.cn

^b College of Chemistry, Sichuan University, Chengdu, China
E-mail: jingsu@scu.edu.cn

^c School of Physical Science and Technology, ShanghaiTech University, Shanghai, China

^d Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD 21218, USA

^e Department of Chemistry, Tsinghua University, Beijing, China

Abstract

Novel two-dimensional kagome metal–organic frameworks with mononuclear Zr⁴⁺/Hf⁴⁺ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.

This article is part of the themed collections: ChemComm Milestones – First Independent Articles and Chemical Communications HOT Articles 2022

Chemical Communications

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Social activity

Search articles by author

Spotlight

Advertisements