Issue 2, 2022

Nucleophilic borylation of fluorobenzenes with reduced arylboranes

Abstract

Two challenging but rewarding topics in chemical synthesis are C–F-bond activation and the development of B-centered nucleophiles. We have now tackled both subjects simultaneously by forming aryl–B bonds via SNAr-type reactions on fluorobenzenes under mild conditions using Na2[FluB[double bond, length as m-dash]BFlu], Li2[HBFlu], and Li2[Me2DBA] (BFlu = 9-borafluorenyl, Me2DBA = 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene).

Graphical abstract: Nucleophilic borylation of fluorobenzenes with reduced arylboranes

Supplementary files

Article information

Article type
Communication
Submitted
04 ноем. 2021
Accepted
29 ноем. 2021
First published
29 ноем. 2021

Chem. Commun., 2022,58, 254-257

Nucleophilic borylation of fluorobenzenes with reduced arylboranes

H. Budy, S. E. Prey, C. D. Buch, M. Bolte, H. Lerner and M. Wagner, Chem. Commun., 2022, 58, 254 DOI: 10.1039/D1CC06225E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements