Issue 20, 2021

Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

Abstract

Argentophilic forces are formed in a coordination complex based on silver(I) trifluoromethanesulfonate and 4-stilbazole as a ligand. The forces are absent at low temperature and form as a result of an order–disorder phase transition that occurs upon heating. Colossal positive thermal expansion also precedes the phase transition.

Graphical abstract: Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

Supplementary files

Article information

Article type
Communication
Submitted
19 јан. 2021
Accepted
30 апр. 2021
First published
03 мај 2021

New J. Chem., 2021,45, 8898-8901

Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

N. Juneja, D. K. Unruh, R. H. Groeneman and K. M. Hutchins, New J. Chem., 2021, 45, 8898 DOI: 10.1039/D1NJ00312G

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