Reversible and efficient SO2 capture by a chemically stable MOF CAU-10: experiments and simulations

J. Antonio Zárate; Eduardo Domínguez-Ojeda; Elí Sánchez-González; Eva Martínez-Ahumada; Valeria B. López-Cervantes; Daryl R. Williams; Vladimir Martis; Ilich A. Ibarra; José Alejandre

doi:10.1039/D0DT01595D

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Reversible and efficient SO₂ capture by a chemically stable MOF CAU-10: experiments and simulations†

J. Antonio Zárate,

‡^a Eduardo Domínguez-Ojeda,

‡^b Elí Sánchez-González,

^c Eva Martínez-Ahumada,^a Valeria B. López-Cervantes,^a Daryl R. Williams,^d Vladimir Martis,^e Ilich A. Ibarra

*^a and José Alejandre*^b

Author affiliations

* Corresponding authors

^a Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán, Ciudad de México, Mexico
E-mail: argel@unam.mx
Fax: +52 55 5622 4595

^b Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, C. P. 09340 Ciudad de México, Mexico
E-mail: jra@xanum.uam.mx

^c Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

^d Surfaces and Particle Engineering Laboratory (SPEL), Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, UK

^e Surface Measurement Systems, Unit 5, Wharfside, Rosemont Road, London HA0 4PE, UK

Abstract

The adsorption of sulphur dioxide (SO₂) in CAU-10 is obtained with the use of advanced experimental and computational tools to gain insight into the molecular mechanisms responsible for the adsorption of SO₂. It is shown that the adsorption by CAU-10 is highly energy efficient and that van der Waals interactions are the driving force that controls adsorption in this system.

This article is part of the themed collection: Celebrating Latin American Talent in Chemistry

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Article information

DOI: https://doi.org/10.1039/D0DT01595D
Article type: Communication
Submitted: 01 мај 2020
Accepted: 21 јун. 2020
First published: 22 јун. 2020

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Dalton Trans., 2020,49, 9203-9207

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Reversible and efficient SO₂ capture by a chemically stable MOF CAU-10: experiments and simulations

J. A. Zárate, E. Domínguez-Ojeda, E. Sánchez-González, E. Martínez-Ahumada, V. B. López-Cervantes, D. R. Williams, V. Martis, I. A. Ibarra and J. Alejandre, Dalton Trans., 2020, 49, 9203 DOI: 10.1039/D0DT01595D

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Dalton Transactions