Issue 58, 2020

A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands

Abstract

Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp) ligands, Cp2Mo2H8 (1), from the reaction of CpMoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 °C to afford a μ-benzene complex Cp2Mo2H2(μ-C6H6) (2).

Graphical abstract: A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands

Supplementary files

Article information

Article type
Communication
Submitted
07 мај 2020
Accepted
09 јун. 2020
First published
11 јун. 2020

Chem. Commun., 2020,56, 8035-8038

A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands

Y. Ohki, K. Ishihara, M. Yaoi, M. Tada, W. M. C. Sameera and R. E. Cramer, Chem. Commun., 2020, 56, 8035 DOI: 10.1039/D0CC03274C

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