Issue 36, 2018

Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds

Abstract

The intramolecular C(sp3)–H/C(sp2)–H cross-coupling of 1,3-dicarbonyl compounds has been achieved through Cp2Fe-catalyzed electrochemical oxidation. The key to the success of these dehydrogenative cyclization reactions is the selective activation of the acidic α-C–H bond of the 1,3-dicarbonyl moiety to generate a carbon-centered radical.

Graphical abstract: Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds

Supplementary files

Article information

Article type
Communication
Submitted
27 мар. 2018
Accepted
12 апр. 2018
First published
19 апр. 2018

Chem. Commun., 2018,54, 4601-4604

Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds

Z. Wu, S. Li, H. Long and H. Xu, Chem. Commun., 2018, 54, 4601 DOI: 10.1039/C8CC02472C

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