Issue 1, 2017

Dendron engineering in self-host blue iridium dendrimers towards low-voltage-driving and power-efficient nondoped electrophosphorescent devices

Abstract

Dendron engineering in self-host blue Ir dendrimers is reported to develop power-efficient nondoped electrophosphorescent devices for the first time, which can be operated at low voltage close to the theoretical limit (Eg/e: corresponding to the optical bandgap divided by the electron charge). With increasing dendron's HOMO energy levels from B-POCz to B-CzCz and B-CzTA, effective hole injection is favored to promote exciton formation, resulting in a significant reduction of driving voltage and improvement of power efficiency. Consequently, the nondoped device of B-CzTA achieves extremely low driving voltages of 2.7/3.4/4.4 V and record high power efficiencies of 30.3/24.4/16.3 lm W−1 at 1, 100 and 1000 cd m−2, respectively. We believe that this work will pave the way to the design of novel power-efficient self-host blue phosphorescent dendrimers used for energy-saving displays and solid-state lightings.

Graphical abstract: Dendron engineering in self-host blue iridium dendrimers towards low-voltage-driving and power-efficient nondoped electrophosphorescent devices

Supplementary files

Article information

Article type
Communication
Submitted
31 окт. 2016
Accepted
25 ноем. 2016
First published
25 ноем. 2016

Chem. Commun., 2017,53, 180-183

Dendron engineering in self-host blue iridium dendrimers towards low-voltage-driving and power-efficient nondoped electrophosphorescent devices

Y. Wang, S. Wang, J. Ding, L. Wang, X. Jing and F. Wang, Chem. Commun., 2017, 53, 180 DOI: 10.1039/C6CC08722A

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