Issue 17, 2010
From the journal:

Chemical Communications

Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides†‡

Chun-Hui Xing,a   Yuan-Xi Liao,a   Ping Hea  and  Qiao-Sheng Hu*a  

* Corresponding authors

a Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, 2800 Victory Boulevard, Staten Island, New York 10314, USA
E-mail: qiaosheng.hu@csi.cuny.edu
Fax: (+1) 718-982-3910
Tel: (+1) 718-982-3901

Abstract

Transition metal-catalyzed addition of arylboronic acids to 2-formylbenzoates afforded 3-substituted phthalides. By using SPINOL-based phosphites as ligands, a Rh(I)-catalyzed asymmetric version of such an addition reaction was achieved.

Graphical abstract: Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C001104E
Article type
Communication
Submitted
18 јан. 2010
Accepted
18 фев. 2010
First published
25 мар. 2010

Chem. Commun., 2010,46, 3010-3012

Permissions

Request permissions

Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides

C. Xing, Y. Liao, P. He and Q. Hu, Chem. Commun., 2010, 46, 3010 DOI: 10.1039/C001104E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements