Issue 6, 2007

The first example of a coordination polymer from the expanded 4,4′-bipyridineligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

Abstract

The complex cation ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine) is an expanded 4,4′-bipyridine; we describe the first example of a coordination polymer in which [Ru(pytpy)2]2+ plays the role of a bridging bidentate ligand.

Graphical abstract: The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

Supplementary files

Article information

Article type
Communication
Submitted
09 мар. 2007
Accepted
22 мар. 2007
First published
02 апр. 2007

CrystEngComm, 2007,9, 456-459

The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

J. E. Beves, E. C. Constable, C. E. Housecroft, C. J. Kepert and D. J. Price, CrystEngComm, 2007, 9, 456 DOI: 10.1039/B703622A

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