Issue 22, 2022

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Abstract

Novel two-dimensional kagome metal–organic frameworks with mononuclear Zr4+/Hf4+ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.

Graphical abstract: Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
13 јан. 2022
Accepted
25 јан. 2022
First published
26 јан. 2022

Chem. Commun., 2022,58, 3601-3604

Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks

Q. Lai, Z. Chu, X. Xiao, D. Dai, T. Song, T. Luo, W. Tang, X. Feng, Z. Zhang, T. Li, H. Xiao, J. Su and C. Liu, Chem. Commun., 2022, 58, 3601 DOI: 10.1039/D2CC00213B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements