Issue 4, 2020

Nucleation and crystal growth control for scalable solution-processed organic–inorganic hybrid perovskite solar cells

Abstract

Over the past decade, intensive research efforts have been directed toward the field of organic–inorganic hybrid perovskites, with dramatic progress made in both the photovoltaic performance and device stability. Therefore, it has become the fastest growing photovoltaic research area. Perovskite materials use low-cost earth-abundant elements and can be solution-processed; furthermore, the technology is compatible with large-scale roll-to-roll manufacturing. Recently, the successful demonstration of the photovoltaic performance of perovskites reaching that of the commercialized monosilicon photovoltaic technology combined with the significantly improved stability has made scaling-up the perovskite PV technology to become a new research area, which is the topic of this review. First, the fundamental background knowledge of classical nucleation and crystal growth from a solution is summarized along with its application in perovskite film evolution. We then discuss the common perovskite PV device architectures and perovskite layer deposition methods, followed by summarizing scalable solution approaches with recent progress and related challenges for the scaling-up process. Upon the introduction of the current in-depth understanding of perovskite nucleation and crystal growth, external strategies (including both physical and chemical approaches) controlling the perovskite film formation are reviewed in diverse scalable manufacturing methods. Overall, aiming at overcoming the challenges of transferring from laboratory research, we provide an overview of achieving high-performance perovskite solar cells by using scalable fabrication methods via precise nucleation and crystal growth control during the perovskite film formation process.

Graphical abstract: Nucleation and crystal growth control for scalable solution-processed organic–inorganic hybrid perovskite solar cells

Article information

Article type
Review Article
Submitted
12 окт. 2019
Accepted
09 дек. 2019
First published
10 дек. 2019

J. Mater. Chem. A, 2020,8, 1578-1603

Nucleation and crystal growth control for scalable solution-processed organic–inorganic hybrid perovskite solar cells

H. Hu, M. Singh, X. Wan, J. Tang, C. Chu and G. Li, J. Mater. Chem. A, 2020, 8, 1578 DOI: 10.1039/C9TA11245F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements