Issue 7, 2018

Catalytic N–Si coupling as a vehicle for silane dehydrocoupling via α-silylene elimination

Abstract

Exploration of (N3N)ZrNMe2 (1, N3N = N(CH2CH2NSiMe3)33–) as a catalyst for the cross-dehydrocoupling or heterodehydrocoupling of silanes and amines suggested silylene reactivity. Further studies of the catalysis and stoichiometric modeling reactions hint at α-silylene elimination as the pivotal mechanistic step, which expands the 3p elements known to engage in this catalysis and provides a new strategy for the catalytic generation of low-valent fragments.

Graphical abstract: Catalytic N–Si coupling as a vehicle for silane dehydrocoupling via α-silylene elimination

Supplementary files

Article information

Article type
Communication
Submitted
30 ноем. 2017
Accepted
10 јан. 2018
First published
11 јан. 2018

Dalton Trans., 2018,47, 2138-2142

Catalytic N–Si coupling as a vehicle for silane dehydrocoupling via α-silylene elimination

K. A. Erickson, M. P. Cibuzar, N. T. Mucha and R. Waterman, Dalton Trans., 2018, 47, 2138 DOI: 10.1039/C7DT04507G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements