Issue 37, 2016

Aerobic epoxidation catalysed by transition metal substituted polyfluorooxometalates

Abstract

First row transition metal substituted polyfluorooxmetalates with quasi Wells–Dawson structures and a nitro terminal ligand, [NaH2M(NO2)W17F6O55]q, were used as catalysts for the aerobic epoxidation of cyclic alkenes. The Cu(NO2) analog combined the best traits of conversion and selectivity. Some C–C bond cleavage was also observed and cis isomers reacted preferentially without stereochemical inversion indicating an oxygen atom to double bond concerted reaction.

Graphical abstract: Aerobic epoxidation catalysed by transition metal substituted polyfluorooxometalates

Article information

Article type
Communication
Submitted
15 мај 2016
Accepted
19 јул. 2016
First published
20 јул. 2016

Dalton Trans., 2016,45, 14534-14537

Aerobic epoxidation catalysed by transition metal substituted polyfluorooxometalates

M. Bugnola and R. Neumann, Dalton Trans., 2016, 45, 14534 DOI: 10.1039/C6DT01928E

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