Recent progress in the catalytic transformation of acetylene

Xin Yu and Shifa Zhu

Chem. Soc. Rev., 2025, 54, 5586
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Photoinduced synthesis of C2-linked phosphine oxides via radical difunctionalization of acetylene

Kangkui Li, Jiazhen Deng, Xianyang Long and Shifa Zhu

Green Chem., 2023, 25, 7253
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Bifunctional two-carbon reagent made from acetylene via 1,2-difunctionalization and its applications

Bo Yang, Kangkui Li, Yongdong Wang and Shifa Zhu

Sci. China Chem., 2024, 67, 936
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Photoredox/Ni-Catalytic Synthesis of cis-Vinyl Iodides from Acetylene

Kangkui Li, Yue Huang, Xianyang Long, Dong Zhu, Yang Chen and Shifa Zhu

J. Am. Chem. Soc., 2025, 147, 37157
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1,2,4‐Triazines and Calcium Carbide in the Catalyst‐Free Synthesis of 2,3,6‐Trisubstituted Pyridines and Their D‐, 13C‐, and Doubly D2‐13C2‐Labeled Analogues

Vladimir V. Voronin, Mikhail V. Polynski and Maria S. Ledovskaya

Chemistry An Asian Journal, 2023, 18
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Ligand Control of Copper-Mediated Cycloadditions of Acetylene to Azides: Chemo- and Regio-Selective Formation of Deutero- and Iodo-Substituted 1,2,3-Triazoles

Dongying Li, Shanguang Qiu, Yunlong Wei, Yanmei Zhao and Luyong Wu

J. Org. Chem., 2024, 89, 825
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Gold(I)-Catalyzed Intermolecular Aryloxyvinylation with Acetylene Gas

Tania Medina-Gil, Anna Sadurní, L. Anders Hammarback and Antonio M. Echavarren

ACS Catal., 2023, 13, 10751
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Nickel-Catalyzed Quinoline Synthesis through Skeletal Editing Strategy Using Calcium Carbide as an Inorganic C2 Source

Zhiqiang Wang, Wei Chen, Jinhui Yang and Zheng Li

Org. Lett., 2025, 27, 13362
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Synthesis of E-Dienyl Esters Using Acetylene as C2 Synthon

Boxiang Liu, Zhicong Lin, Tairan Cheng, Tongxiang Cao and Shifa Zhu

Org. Lett., 2023, 25, 3573
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Densely Packed Chemical Synthesis Equipment by 3D Spatial Design and Additive Manufacturing: Acetylene Generation Cartridge

Kirill S. Erokhin and Valentine P. Ananikov

Org. Process Res. Dev., 2023, 27, 1144
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Calcium carbide: Highly potent solid reagent for the construction of heterocycles

Maria S. Ledovskaya and Vladimir V. Voronin

Tetrahedron, 2023, 149, 133720
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Modular and Diverse Synthesis of Acrylamides by Palladium‐Catalyzed Hydroaminocarbonylation of Acetylene

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angew Chem Int Ed, 2024, 63
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Rhodium‐Catalysed Selective C−H Allylation of 1H‐Indazoles with Vinylethylene Carbonate: Easily Introducing Allylic Alcohol

Xiang Zhao, Junwei Huang, Yadong Feng and Xiuling Cui

Eur J Org Chem, 2023, 26
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Cu-Catalyzed Z-Selective Carboboration of Acetylene with Hindered Michael Acceptors Enabled by a Buffering Borinate Additive

Yu Wang, Tairan Cheng, Lin Chen, Youwei Feng, Siju Li and Shifa Zhu

Org. Lett., 2026, 28, 5859
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Synthesis of branched and linear aryl allylic alcohols: C H bond allylation of 2-aryl-3H-indoles with vinyl cyclic carbonates

Fan Yu, Bin Li, Xinying Zhang and Xuesen Fan

Tetrahedron Letters, 2024, 147, 155225
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Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products

Andrés M. Álvarez‐Constantino, Andrea Chaves‐Pouso and Martín Fañanás‐Mastral

Angew Chem Int Ed, 2024, 63
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Construction of 3-Methyl-2-Substituted Benzo[b]furans and 3-Methyl-2-Substituted Benzo[b]thiophenes Using Solid Calcium Carbide as a Substitute for Gaseous Acetylene

Zhiqiang Wang, Zhenrong Liu, Ting Shao and Zheng Li

J. Org. Chem., 2024, 89, 7182
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An arrayed carbon-fiber reactor for enhanced yield of acetylene from methane pyrolysis by pulsed Joule-heating

Mingze Chen, Yue Pan, Lu Yao, Chi Zhang and Songyuan Ding

Chemical Engineering Journal, 2026, 537, 176432
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Three-Component Gold(I)-Catalyzed Alkoxyvinylation

L. Anders Hammarback, Tania Medina-Gil, Anna Sadurní and Antonio M. Echavarren

Org. Lett., 2024, 26, 6375
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Palladium‐Catalyzed Four‐Component Carbonylation Reactions of Acetylene: Synthesis of β‐Perfluoroalkyl Acrylamides

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Eur J Org Chem, 2024, 27
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Photoredox/Nickel Dual Catalysis-Enabled Modular Synthesis of Arylallyl Alcohols with Acetylene as the Two-Carbon Synthon

Kangkui Li, Xianyang Long and Shifa Zhu

ACS Catal., 2023, 13, 2422
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Synthesis of N-Sulfonyl Acetamidine Using Calcium Carbide as the Alkynyl Source and Ammonium Bicarbonate as the Amine Source

Rui An, Peiming Gu and Meng-Xue Wei

J. Org. Chem., 2025, 90, 14205
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Modular and Diverse Synthesis of Acrylamides by Palladium‐Catalyzed Hydroaminocarbonylation of Acetylene

Zhusong Cao, Qiang Wang, Helfried Neumann and Matthias Beller

Angewandte Chemie, 2024, 136
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Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products

Andrés M. Álvarez‐Constantino, Andrea Chaves‐Pouso and Martín Fañanás‐Mastral

Angewandte Chemie, 2024, 136
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