Iron-catalyzed β-hydroxymethylative carbonylation of styrene under photo-irradiation

Meng Guan, Ming Hou, Shuwang Tang, Guang Cheng, Xinyu Zhu, Yun-Hui Zhao, Ximei Tang, Hongwei Zhou and Guanyinsheng Qiu

Chem. Commun., 2023, 59, 13309
DOI: 10.1039/D3CC03919F

Efficient and high para-selective conversion of toluene with NO2 to para-nitrotoluene in an O2–Ac2O–HβD4 composite catalytic system

Renjie Deng, Huajie Liu, Haishuai Cui, Yao Tian and Hai Yang

Catal. Sci. Technol., 2024, 14, 1854
DOI: 10.1039/D3CY01045G

Investigation of arene and heteroarene nitration supported by high-throughput experimentation and machine learning

Taline Kerackian, Clément Wespiser, Matthieu Daniel, Eric Pasquinet and Eugénie Romero

Digital Discovery, 2025, 4, 1662
DOI: 10.1039/D5DD00086F

Carboxylato-prism[6]arene as a supramolecular catalyst in water: exploiting its deep hydrophobic cavity for green oxidation of aromatic amines

Rocco Del Regno, Giuseppa Campanile, Placido Neri, Carmen Talotta, Antonio Rescifina, Carmelo Sgarlata, Giuseppina D. G. Santonoceta, Carmine Gaeta and Margherita De Rosa

Chem. Sci., 2025, 16, 18223
DOI: 10.1039/D5SC03155A

tert-Butyl nitrite as a privileged reagent for a C–H bond (sub)nitration reaction in organic synthesis

Jiaoli Ma, Pinzhu Chen, Junli Zeng, Penghu Guo and Huicheng Cheng

New J. Chem., 2024, 48, 14128
DOI: 10.1039/D4NJ01802H

Efficient one-step synthesis of 3-nitroflavones via cascade nitration-cyclization

Yilin Yang, Chukai Shao, Ruirui Hua, Rui Tian, Ziang Wang, Hongquan Yin, Houhua Zhu and Fu-Xue Chen

Org. Biomol. Chem., 2026, 24, 2645
DOI: 10.1039/D6OB00238B

Trifunctionalization of CC bonds in vinyl azides to access densely functionalized phenanthridines enabled by the NCS/AgNO2 system

Shaobo Ren, Jian Zhu and Yunkui Liu

Org. Biomol. Chem., 2024, 22, 5982
DOI: 10.1039/D4OB00905C

Transition-metal-free photochemical reductive denitration of nitroarenes

Shuai Tang, Weidong Xu and Hua Zhang

Chem. Commun., 2024, 60, 13754
DOI: 10.1039/D4CC04982A

Three‐Component Synthesis of Thiazole‐2‐thione from Chalcone, Nitrobenzene and Carbon Disulfide

Fuhong Xiao, Enbo Yu, Ya Chen and Guo‐Jun Deng

Adv Synth Catal, 2023, 365, 4150
DOI: 10.1002/adsc.202300890

2‐Methoxyethyl Nitrite as a Reagent for Chemoselective On‐Water Nitration

Taku Kitanosono, Airu Hashidoko, Yasuhiro Yamashita and Shū Kobayashi

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200457

Acid‐free and highly efficient one‐step nitration of naphthalene with NO2 promoted by O2‐Ac2O in Fe‐ and Cu‐modified S2O82−/ZrO2 catalyst to 1,5‐dinitronaphthalene under mild conditions

Jiaqi Yan, Xiaowen Zhang, Fangfang Zhao, Kuiyi You and He'an Luo

Can J Chem Eng, 2024, 102, 3250
DOI: 10.1002/cjce.25252

Eine photochemische Strategie für die Synthese von ortho‐Aminophenolen durch dearomative‐rearomative Kupplung zwischen Arylaziden und Alkoholen

Bo Li, Alessandro Ruffoni and Daniele Leonori

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310540

Stereoselective Nitration of Olefins via Visible-Light-Induced Iron-Complex β-Homolysis

Ziyang Chen, Shuyang Liu, Ziyi Xu, Ziyu Gan, Ran Xu, Zhiyan Xue and Yunhe Jin

J. Org. Chem., 2025, 90, 7458
DOI: 10.1021/acs.joc.5c00908

Process hazard and thermal risk evaluation of m-xylene nitration with mixed acid

Hang Yao, Lei Ni, Yinshan Liu, Gang Fu, Juncheng Jiang, Zhen Cheng, Yuqing Ni and Zhiquan Chen

Process Safety and Environmental Protection, 2023, 175, 238
DOI: 10.1016/j.psep.2023.05.028

Chemo-and regioselective aqueous phase, co-acid free nitration of aromatics using traditional and nontraditional activation methods

Kelsey M. Plasse, Tara R. Mooney, Maxim Mastyugin, Maximilian Costa and Béla Török

Front. Chem., 2024, 12
DOI: 10.3389/fchem.2024.1400445

Nickel‐Catalyzed Remote C(sp2)−H Nitration of 8‐Aminoquinolines Using AgNO3 in Acetone

Priyanka Mishra and Ashok Kumar Pandey

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202502763

Catalytic ipso‐Nitration of Organosilanes Enabled by Electrophilic N‐Nitrosaccharin Reagent

Ivan Mosiagin, Anthony J. Fernandes, Alena Budinská, Liana Hayriyan, Kai E. O. Ylijoki and Dmitry Katayev

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310851

Deaminative Cyanation of Anilines by Oxylanion Radical Transfer

Deepak Behera, Tim Schulte, Ahmet Altun, Markus Leutzsch, Frank Neese and Tobias Ritter

Org. Lett., 2025, 27, 8921
DOI: 10.1021/acs.orglett.5c02410

Novel S2O82−/Fe-ZrO2 solid superacid catalyst combined with O2-Ac2O for highly efficient catalytic nitration of 1-nitronaphthalene with NO2 to 1,5-dinitronaphthalene

Jiaqi Yan, Xiaowen Zhang, Jiahong Yin, Fangfang Zhao, Kuiyi You and He’an Luo

Res Chem Intermed, 2023, 49, 3065
DOI: 10.1007/s11164-023-05029-z

Iron-Catalyzed Ipso-Nitration of Aryl Borides via Visible-Light-Induced β-Homolysis

Shuyang Liu, Yusheng Lu, Hongyao Wang, Zhiyan Xue, Ziyi Xu, Huihui Wan, Qingxin Yin, Tianming Lv, Shu-Xin Liu and Yunhe Jin

ACS Catal., 2025, 15, 3306
DOI: 10.1021/acscatal.4c07252

C–H Nitrooxylation: A Shortcut to Nitrate Esters

Masoud Sadeghi

Top Curr Chem (Z), 2026, 384
DOI: 10.1007/s41061-026-00542-2

Oxidative Nucleophilic Functionalization of Nitrobenzene and 3‐Nitroacetophenones with N−H Bonds

Duy T. M. Chung, Phuc Q. Le, Huy X. Le, Tien V. Huynh, Anh N. Q. Phan, Tung T. Nguyen and Nam T. S. Phan

ChemistrySelect, 2021, 6, 8971
DOI: 10.1002/slct.202102169

Experimental and Theoretical Investigation of the Catalytic Activities of Different Zeolites for the Nitration of Toluene

Renjie Deng, Yiming She, Botao Cao, Lele Huang, Junjie Zhu, Huajie Liu, Haishuai Cui, Yao Tian and Fangfang Zhao

Langmuir, 2024, 40, 27546
DOI: 10.1021/acs.langmuir.4c03939

Metal‐Free Nitration of Indazoles with tert‐Butyl Nitrile in Air to Prepare 3‐Nitroindazoles and 3‐Aminoindazoles

Xin‐Yue Zhang, Rong‐Ting Jiang, Xiu‐Qun Pan, Chun‐Hua Chen, Cui Liang and Dong‐Liang Mo

Chin. J. Chem., 2025, 43, 393
DOI: 10.1002/cjoc.202400845

Mechanochemical Nitration Studies of Aminotriazole Compounds

Jie Zhou, Yang Zhao, Jiaheng Wang, Haoxiang Yang, Jingyue He, Lingzhi Ma, Bozhou Wang and Yatang Dai

Langmuir, 2025, 41, 11746
DOI: 10.1021/acs.langmuir.5c01126

Eine durch Elektronen angetriebene Nitrierung von Kohlenwasserstoffen

Subrata Patra, Ivan Mosiagin, Rahul Giri, Thomas Nauser and Dmitry Katayev

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300533

Direct Synthesis of Unprotected Indolines Through Intramolecular sp3 C−H Amination Using Nitroarenes as Aryl Nitrene Precursors

Giedre Sirvinskaite, Celine S. Nardo, Patrick Müller, Aurelio C. Gasser and Bill Morandi

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301978

Electron‐Driven Nitration of Unsaturated Hydrocarbons

Subrata Patra, Ivan Mosiagin, Rahul Giri, Thomas Nauser and Dmitry Katayev

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300533

Electrophilic (Hetero)Arene C–H Nitration by Ferric Nitrate Nonahydrate in Hexafluoroisopropanol

Yuzhu Zheng, Zongyi Liu, Zhaobo Ying and Youwei Xie

J. Org. Chem., 2025, 90, 6926
DOI: 10.1021/acs.joc.5c00137

Nitration of Derivatives of Imidazo[1,5‐a]pyridine via C−H Functionalization with Fe(NO3)3 ⋅ 9H2O as a Promoter and a Nitro Source

Xiaohan Yang, Biqin Wang, Qian Zhang, Aron Szekely, Mengxiang Wu and Yahong Li

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202401114

Quantitative Scale for the Nitronium Cation-Donating Ability of Electrophilic Nitrating Reagents

Lu Yu, Yao Li and Xiao-Song Xue

J. Org. Chem., 2026, 91, 2394
DOI: 10.1021/acs.joc.5c02563

Ipso-Nitration of Boronic Esters Enabled by Ferric Nitrate Nonahydrate (Fe(NO3)3·9H2O) in HFIP

Yuzhu Zheng, Zongyi Liu, Qing Huang and Youwei Xie

Org. Lett., 2025, 27, 2997
DOI: 10.1021/acs.orglett.5c00635

Reduction of Nitroarenes to Anilines with an Air-Stable Bismuth Catalyst

Xiangrong Liu, Hye Won Moon and Josep Cornella

Synthesis, 2026, 58, 1003
DOI: 10.1055/a-2777-9562

The photocatalytic journey of heteroatoms: Illuminating aza-Henry reactions in organic synthesis

Vishwa K. Patel, Divyani P. Patel and Satish Kumar Singh

Tetrahedron, 2025, 185, 134803
DOI: 10.1016/j.tet.2025.134803

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

Harry Lecomte, Anthony J. Fernandes and Dmitry Katayev

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202526128

Green nitration of aromatics: Efficiency and selectivity with FeCl3-H2SiO3 catalysts and nitrogen dioxide

Renjie Deng, Yao Tian, Yanan Wei, Huajie Liu and Weiwei Yan

Separation and Purification Technology, 2026, 396, 137986
DOI: 10.1016/j.seppur.2026.137986

Organic Nitrating Reagents

Subrata Patra, Ivan Mosiagin, Rahul Giri and Dmitry Katayev

Synthesis, 2022, 54, 3432
DOI: 10.1055/s-0040-1719905

Late-Stage C–H Nitration of Unactivated Arenes by Fe(NO3)3·9H2O in Hexafluoroisopropanol

Yuzhu Zheng, Qi-Qi Hu, Qing Huang and Youwei Xie

Org. Lett., 2024, 26, 3316
DOI: 10.1021/acs.orglett.4c01006

Investigation on the decomposition kinetics, thermal safety and mechanism of the nitration products of m-xylene: experiment and DFT calculations

Juncheng Jiang, Hang Yao, Jialei Huang, Zhiquan Chen, Lei Ni and Yong Pan

Journal of the Taiwan Institute of Chemical Engineers, 2025, 175, 106287
DOI: 10.1016/j.jtice.2025.106287

Nanomagnetic picolylamine- based complex of palladium as an efficient heterogeneous catalyst for selective reduction of nitroarenes in water

Ammar Yasir Ahmed, Hamad AlMohamadi, Hazem Saed Zabibah, Subbulakshmi Ganesan, Vimal Arora, krithiga Thangavelu, Pusparaj Samantsinghar, Hamza Fadhel Hamzah, Basim Mohammed Saadi and Yasser Fakri Mustafa

Sci Rep, 2026, 16
DOI: 10.1038/s41598-026-35038-y

Ketone Oximes as NO2 Radical Precursors for Regioselective Iodo–Nitrosylative Cyclization of Unactivated 1,6-Enynes

Mohana Reddy Mutra, T. L. Chandana, Yu-Syuan Chu, Chien-Hung Li and Jeh-Jeng Wang

J. Org. Chem., 2026, 91, 966
DOI: 10.1021/acs.joc.5c02201

Ceric Ammonium Nitrate Promoted Highly Chemo‐ and Regioselective ortho‐Nitration of Anilines under Mild Conditions

Zafar Iqbal, Asha Joshi and Saroj Ranjan De

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200746

Nitration of chlorobenzene by ultrasonic-assisted synthesized sulfated ZrO2 catalyst with NO2

Renjie Deng, Haishuai Cui, Meilin Liu, Wenjin Ni, Yao Tian and Huajie Liu

Res Chem Intermed, 2023, 49, 3029
DOI: 10.1007/s11164-023-05020-8

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

Harry Lecomte, Anthony J. Fernandes and Dmitry Katayev

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202526128

Dinitro-5,5-Dimethylhydantoin: An Arene Nitration Reagent

Fuqiang Jia, Ao Li and Xiangdong Hu

Org. Lett., 2023, 25, 4605
DOI: 10.1021/acs.orglett.3c01023

Quantifying the Nitro‐Radical Donating Ability of Organic Nitrating Reagents

Lu Yu, Yao Li and Xiao‐Song Xue

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.70852

Acid-Free Copper-Catalyzed Electrophilic Nitration of Electron-Rich Arenes with Guanidine Nitrate

Wen-Pei Li, Guo Cheng, Si-Yuan Li, Cheng-Zhou Lin, Xiao-Yu Guan, De-Xian Bing, Jing Cao, Di Zhu and Qing-Hai Deng

J. Org. Chem., 2022, 87, 3834
DOI: 10.1021/acs.joc.1c03020

Palladium-catalyzed regioselective C1-selective nitration of carbazoles

Vikash Kumar, Jyothis Dharaniyedath, Aiswarya T P, Sk Ariyan, Chitrothu Venkatesh and Parthasarathy Gandeepan

Beilstein J. Org. Chem., 2025, 21, 2479
DOI: 10.3762/bjoc.21.190

Synthesis of N-Nitrobenzamides via tert-Butyl-nitrite-Mediated N-Nitration

Maulik Pethani, Yash Dhaduk, Arti Ramani, Prabhakara Madivalappa Davanagere, Hussain Bhukya, Kishor Padala and Togati Naveen

J. Org. Chem., 2026, 91, 8459
DOI: 10.1021/acs.joc.6c00761

Catalytic ipso‐Nitration of Organosilanes Enabled by Electrophilic N‐Nitrosaccharin Reagent

Ivan Mosiagin, Anthony J. Fernandes, Alena Budinská, Liana Hayriyan, Kai E. O. Ylijoki and Dmitry Katayev

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310851

Sustainable magnetic ZnFe2O4 Nanoparticles as a Potent heterogeneous catalyst for the synthesis of phenols and nitroarenes

Amar Jyoti Kalita, Aquif Suleman, Jyotismita Bora, Mayuri Dutta and Bolin Chetia

Tetrahedron, 2025, 178, 134582
DOI: 10.1016/j.tet.2025.134582

Decarboxylation of Paraconic Acids by a Silver(I) Nitrate/Persulfate Combination: An Entry to β-Nitro- and β-Hydroxy γ-Butyrolactones

Supasorn Phae-nok, Chutima Kuhakarn, Pawaret Leowanawat, Vichai Reutrakul and Darunee Soorukram

Synlett, 2022, 33, 1323
DOI: 10.1055/a-1792-7169

Ni(II)-Catalyzed Asymmetric Nitration of Oxindoles: Construction of Cipargamin Analogues

Mingjun Lv and Xiaoxun Li

ACS Catal., 2021, 11, 14829
DOI: 10.1021/acscatal.1c04460

Mechanochemically Driven Radical Nitration of Electron-Rich ortho and para Di- and Trialkoxyarenes Using Iron(III) Nitrate

Samuel Andrejčák, Peter Dudáš and Michal Májek

Synlett, 2025, 36, 1397
DOI: 10.1055/a-2547-8910

A Photochemical Strategy for ortho‐Aminophenol Synthesis via Dearomative‐Rearomative Coupling Between Aryl Azides and Alcohols

Bo Li, Alessandro Ruffoni and Daniele Leonori

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310540

A benign and efficient two-pot PMHS reductive amidation of nitroarenes and carboxylic acids

Musawenkosi H.L. Nyathi, Banele Vatsha and Paseka T. Moshapo

Results in Chemistry, 2025, 18, 102746
DOI: 10.1016/j.rechem.2025.102746