A comprehensive experimental, multivariate statistical, and DFT computational analysis of the catalytic oxidation of benzyl alcohols mediated by Mn(iii) and Fe(iii) metalloporphyrins

Larissa Chimilouski, Sheetal Ranaut, William Henrique Slominski, Patrícia Salvador Tessaro, Gilson DeFreitas-Silva, Edmar Martendal, Cláudio N. Verani, Shivnath Mazumder and Fernando Roberto Xavier

Dalton Trans., 2026, 55, 5117
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An iron(iv)–oxo intermediate on a carbanionic ligand framework: reactivity and decay pathways

Arghyadip Bhowmik, Shreetama Bhattacharya, Sridhar Banerjee, Satadal Paul and Tapan Kanti Paine

Dalton Trans., 2026, 55, 3037
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A 5,000-fold increase in the HAT reactivity of a nonheme Fe IV =O complex simply by replacing two pyridines of the pentadentate N4Py ligand with pyrazoles

Nabhendu Pal, Jin Xiong, Mehmet Jahja, Sami Mahri, Victor G. Young, Yisong Guo, Marcel Swart and Lawrence Que

Proc. Natl. Acad. Sci. U.S.A., 2025, 122
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Trinuclear μ3-Oxo complexes: Correlating structural and electronic features with antimicrobial activity

Bruno R. de Lima, Francielli S. Santana, Eduardo M. Iwaya, Renan B. Campos, Giselle M. Maciel and Dayane M. Reis

Journal of Molecular Structure, 2026, 1349, 143951
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A Tetrapodal Penta‐Carbene Ligand and Iron(III) Complex

Michael R. Gau, Peter Kurta, Taylor M. Keller and Jeremiah J. Scepaniak

Eur J Inorg Chem, 2023, 26
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NMR and Mössbauer Studies Reveal a Temperature-Dependent Switch from S = 1 to 2 in a Nonheme Oxoiron(IV) Complex with Faster C–H Bond Cleavage Rates

Waqas Rasheed, Nabhendu Pal, Ahmed M. Aboelenen, Saikat Banerjee, Williamson N. Oloo, Johannes E. M. N. Klein, Ruixi Fan, Jin Xiong, Yisong Guo and Lawrence Que

J. Am. Chem. Soc., 2024, 146, 3796
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C–H Bond Oxidation by MnIV–Oxo Complexes: Hydrogen-Atom Tunneling and Multistate Reactivity

Priya Singh, Allyssa A. Massie, Melissa C. Denler, Yuri Lee, Jaycee R. Mayfield, Markell J. A. Lomax, Reena Singh, Ebbe Nordlander and Timothy A. Jackson

Inorg. Chem., 2024, 63, 7754
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Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano and Giorgio Olivo

Angew Chem Int Ed, 2024, 63
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Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation

Alessandro Fagnano, Federico Frateloreto, Roberta Paoloni, Carla Sappino, Osvaldo Lanzalunga, Miquel Costas, Stefano Di Stefano and Giorgio Olivo

Angewandte Chemie, 2024, 136
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Stereoelectronic Tuning of Bioinspired Nonheme Iron(IV)-Oxo Species by Amide Groups in Primary and Secondary Coordination Spheres for Selective Oxygenation Reactions

Rahul Dev Jana, Abhishek Das, Rajib Samanta, Sridhar Banerjee, Satadal Paul and Tapan Kanti Paine

Inorg. Chem., 2024, 63, 21042
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Electronic Modification of a Reduced Mononuclear Nonheme Iron Nitrosyl Complex Leads to HNO Release

Jacob A. Wade, Aniruddha Dey, Alex Confer, Sudha Yadav, Maxime A. Siegler, Therese Albert, Pierre Moënne-Loccoz, Yisong Guo, V. Sara Thoi and David P. Goldberg

J. Am. Chem. Soc., 2025, 147, 27624
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Functional Model of Compound II of Cytochrome P450: Spectroscopic Characterization and Reactivity Studies of a FeIV–OH Complex

Kritika Keshari, Aakash Santra, Lucía Velasco, Maxime Sauvan, Simarjeet Kaur, Ashok D. Ugale, Sandip Munshi, J. F. Marco, Dooshaye Moonshiram and Sayantan Paria

JACS Au, 2024, 4, 1142
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Homo- and Heterogeneous Benzyl Alcohol Catalytic Oxidation Promoted by Mononuclear Copper(II) Complexes: The Influence of the Ligand upon Product Conversion

Larissa Chimilouski, William H. Slominski, Ana I. Tillmann, Daniella Will, Aaron M. dos Santos, Giliandro Farias, Edmar Martendal, Karine P. Naidek and Fernando R. Xavier

Molecules, 2024, 29, 2634
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How Does Tuning of the Primary Coordination Sphere Around Ferryl–Oxo Intermediates Affect Structure and Reactivity? Insights into Axial and Equatorial Ligand Field Effects

Gourab Mukherjee, Payal Panwar, Chivukula V. Sastri, Jagnyesh K. Satpathy and Sam P. de Visser

JACS Au, 2026, 6, 2136
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Influence of Asymmetrical Ligand Substitution on the Formation, Stability, and Reactivity of Ruthenium(III)‐Hypochlorite Complexes

Payal Panwar, Shreya Rawat, Rolly Yadav, Jason Z. He, Henrik P. H. Wong, Chivukula V. Sastri and Sam P. de Visser

Chemistry A European J, 2025, 31
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Bioinspired oxidation of benzyl alcohol: The role of environment and nuclearity of the catalyst evaluated by multivariate analysis

Larissa Chimilouski, Fredricka Morgan, Danushka Ekanayake, Nour El-Harakeh, Rosely A. Peralta, Edmar Martendal, Cláudio N. Verani and Fernando R. Xavier

Journal of Inorganic Biochemistry, 2023, 240, 112095
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Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode

Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen and Yuan-Bin She

Molecular Catalysis, 2022, 531, 112676
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Syntheses and structures of transition metal complexes of quinoline-containing multidentate amine ligands

Bronte Carr, Cassandra L. Fleming and Allan G. Blackman

Coordination Chemistry Reviews, 2024, 502, 215599
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High-Valent Late Transition Metal-Oxo Complexes: Breaking Boundaries at the Oxo Wall and Beyond

Nabhendu Pal, Nicole A. Fritsch, Jason Shearer and Nicolai Lehnert

Chem. Rev., 2026, 126, 5178
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Enhanced Understanding of Structure–Function Relationships for Oxomanganese(IV) Complexes

Priya Singh, Yuri Lee, Jaycee R. Mayfield, Reena Singh, Melissa C. Denler, Shannon D. Jones, Victor W. Day, Ebbe Nordlander and Timothy A. Jackson

Inorg. Chem., 2023, 62, 18357
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Unravelling the Effect of Acid‐Driven Electron Transfer in High‐Valent FeIV=O/MnIV=O Species and Its Implications for Reactivity

Neethinathan Johnee Britto, Asmita Sen and Gopalan Rajaraman

Chemistry An Asian Journal, 2023, 18
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Nonheme FeIV═O Complexes Supported by Four Pentadentate Ligands: Reactivity toward H- and O- Atom Transfer Processes

Yong Li, Reena Singh, Arup Sinha, George C. Lisensky, Matti Haukka, Justin Nilsson, Solomon Yiga, Serhiy Demeshko, Sophie Jana Gross, Sebastian Dechert, Ana Gonzalez, Giliandro Farias, Ola F. Wendt, Franc Meyer and Ebbe Nordlander

Inorg. Chem., 2023, 62, 18338
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