Solid-state molecular organometallic chemistry (SMOM): a user guide to in crystallo single-crystal to single-crystal transformations using solid/gas methods

Kristof M. Altus, Samantha K. Furfari, Joe C. Goodall, Matthew R. Gyton, Jack H. Heaton, Chloe L. Johnson, Alasdair I. McKay, Mads Sondrup Møller, Sebastian D. Pike and Andrew S. Weller

Dalton Trans., 2026, 55, 6649
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Templated synthesis of zirconium(iv)-based metal–organic layers (MOLs) with accessible chelating sites

Pol Gimeno-Fonquernie, Weibin Liang, Jorge Albalad, Andrew Kuznicki, Jason R. Price, Eric D. Bloch, Christian J. Doonan and Christopher J. Sumby

Chem. Commun., 2022, 58, 957
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MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

Jian Liu, Timothy A. Goetjen, Qining Wang, Julia G. Knapp, Megan C. Wasson, Ying Yang, Zoha H. Syed, Massimiliano Delferro, Justin M. Notestein, Omar K. Farha and Joseph T. Hupp

Chem. Soc. Rev., 2022, 51, 1045
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Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

David Z. Zee and T. David Harris

Chem. Sci., 2020, 11, 5447
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A metal–organic framework supported iridium catalyst for the gas phase hydrogenation of ethylene

Ricardo A. Perlata, Michael T. Huxley, Zhaolin Shi, Yue-Biao Zhang, Christopher J. Sumby and Christian J. Doonan

Chem. Commun., 2020, 56, 15313
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Decoding host–guest interactions: tuning pore functionality in MOFs for efficient capture of short- and long-chain PFAS

Lidia García, Patricia García-Atienza, Sergio Armenta, José Manuel Herrero-Martínez, Mario Prejanò, Tiziana Marino, Donatella Armentano, Thais Grancha, Jesús Ferrando-Soria and Emilio Pardo

J. Mater. Chem. A, 2025, 13, 42204
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Understanding the opportunities of metal–organic frameworks (MOFs) for CO2capture and gas-phase CO2conversion processes: a comprehensive overview

J. Gandara-Loe, L. Pastor-Perez, L. F. Bobadilla, J. A. Odriozola and T. R. Reina

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A hierarchical porous P-doped carbon electrode through hydrothermal carbonization of pomelo valves for high-performance supercapacitors

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Nanoscale Adv., 2020, 2, 3284
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The chemistry of phosphines in constrained, well-defined microenvironments

Georgia R. F. Orton, Ben S. Pilgrim and Neil R. Champness

Chem. Soc. Rev., 2021, 50, 4411
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Studying manganese carbonyl photochemistry in a permanently porous metal–organic framework

Rosemary J. Young, Michael T. Huxley, Lingjun Wu, Jack Hart, James O'Shea, Christian J. Doonan, Neil R. Champness and Christopher J. Sumby

Chem. Sci., 2023, 14, 9409
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Nanoconfinement and mass transport in metal–organic frameworks

Conor H. Sharp, Brandon C. Bukowski, Hongyu Li, Eric M. Johnson, Stefan Ilic, Amanda J. Morris, Dilip Gersappe, Randall Q. Snurr and John R. Morris

Chem. Soc. Rev., 2021, 50, 11530
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Synthesis of atomically precise single-crystalline Ru2-based coordination polymers

Wen-Yang Gao, Gerard Pierre Van Trieste III and David C. Powers

Dalton Trans., 2020, 49, 16077
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Bioinspired metal–organic frameworks for aqueous environment decontamination: from laboratory scale to real-world technologies

Cristina Negro, Walter D. Guerra, Donatella Armentano, Jesús Ferrando-Soria, Thais Grancha and Emilio Pardo

Chem. Commun., 2024, 60, 14935
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In crystallo organometallic chemistry

Kaleb A. Reid and David C. Powers

Chem. Commun., 2021, 57, 4993
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Historical and contemporary perspectives on metal–organic frameworks for gas sensing applications: a review

Gia Huy Pham and Cerasela Zoica Dinu

RSC Sustainability, 2023, 1, 1125
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Copper–Vit B3 MOF preparation, characterization and catalytic evaluation in a one-pot synthesis of benzoxanthenones with docking validation as anti H. pylori

Asma S. Al-Wasidi, Mahmoud Tarek, Gehad E. Said, Ahmed M. Naglah, Abdulrahman A. Almehizia and Tamer K. Khatab

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Efficient removal of drugs of abuse from drinking water using metal–organic frameworks

Thais Grancha, Patricia Garcia-Atienza, Sergio Armenta, José Manuel Herrero-Martínez, Rita Maria Percoco, Donatella Armentano, Jesús Ferrando-Soria and Emilio Pardo

J. Mater. Chem. A, 2025, 13, 24473
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MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF5)2C6H3)4]− anion, via on-grid solid/gas single-crystal to single-crystal reactivity

Laurence R. Doyle, Emily A. Thompson, Arron L. Burnage, Adrian C. Whitwood, Huw T. Jenkins, Stuart A. Macgregor and Andrew S. Weller

Dalton Trans., 2022, 51, 3661
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Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: formation, metal sites in catalysis and thin films

Miguel Rivera-Torrente, Laurens D. B. Mandemaker, Matthias Filez, Guusje Delen, Beatriz Seoane, Florian Meirer and Bert M. Weckhuysen

Chem. Soc. Rev., 2020, 49, 6694
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Elucidating pore chemistry within metal–organic frameworks via single crystal X-ray diffraction; from fundamental understanding to application

Jorge Albalad, Christopher J. Sumby, Daniel Maspoch and Christian J. Doonan

CrystEngComm, 2021, 23, 2185
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Epoxidation vs. dehydrogenation of allylic alcohols: heterogenization of the VO(acac)2 catalyst in a metal–organic framework

Cristina Negro, Cristina Bilanin, Xiaoni Qu, Judit Oliver-Meseguer, Jesús Ferrando-Soria, Antonio Leyva-Pérez, Donatella Armentano and Emilio Pardo

Chem. Commun., 2022, 58, 5578
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Porphyrin-based heterogeneous photocatalysts for solar energy conversion

Yuheng Zhang, Kang Ren, Lu Wang, Lin Wang and Zhuangjun Fan

Chinese Chemical Letters, 2022, 33, 33
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Highly Efficient Removal of Neonicotinoid Insecticides by Thioether-Based (Multivariate) Metal–Organic Frameworks

Cristina Negro, Héctor Martínez Pérez-Cejuela, Ernesto F. Simó-Alfonso, José Manuel Herrero-Martínez, Rosaria Bruno, Donatella Armentano, Jesús Ferrando-Soria and Emilio Pardo

ACS Appl. Mater. Interfaces, 2021, 13, 28424
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Click amidations, esterifications and one–pot reactions catalyzed by Cu salts and multimetal–organic frameworks (M–MOFs)

Rossella Greco, Estefanía Tiburcio, Brenda Palomar-De Lucas, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo and Antonio Leyva-Pérez

Molecular Catalysis, 2022, 522, 112228
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Metal–Organic Frameworks with Low‐Valent Metal Nodes

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Angew Chem Int Ed, 2022, 61
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Highly Active Gas Phase Organometallic Catalysis Supported Within Metal–Organic Framework Pores

Ricardo A. Peralta, Michael T. Huxley, Jack D. Evans, Thomas Fallon, Haijie Cao, Maoxia He, Xiu Song Zhao, Stefano Agnoli, Christopher J. Sumby and Christian J. Doonan

J. Am. Chem. Soc., 2020, 142, 13533
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Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

Ricardo A. Peralta, Pengbo Lyu, Alfredo López‐Olvera, Juan L. Obeso, Carolina Leyva, Nak Cheon Jeong, Ilich A. Ibarra and Guillaume Maurin

Angewandte Chemie, 2022, 134
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Quest for Multifunctionality: Current Progress in the Characterization of Heterometallic Metal–Organic Frameworks

R. Eric Sikma, Kimberly S. Butler, Dayton J. Vogel, Jacob A. Harvey and Dorina F. Sava Gallis

J. Am. Chem. Soc., 2024, 146, 5715
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Metal–Organic Frameworks with Zero and Low‐Valent Metal Nodes Connected by Tetratopic Phosphine Ligands

R. Eric Sikma and Seth M. Cohen

Angew Chem Int Ed, 2022, 61
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Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

Marta Viciano-Chumillas, Xiangyu Liu, Antonio Leyva-Pérez, Donatella Armentano, Jesús Ferrando-Soria and Emilio Pardo

Coordination Chemistry Reviews, 2022, 451, 214273
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Application of metal-organic frameworks for sensing of VOCs and other volatile biomarkers

Pegah Hajivand, Johannes Carolus Jansen, Emilio Pardo, Donatella Armentano, Teresa F. Mastropietro and Amirreza Azadmehr

Coordination Chemistry Reviews, 2024, 501, 215558
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Metal–Organic Framework Supported Low‐Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol

Bing Shao, Du Huang, Rui‐Kang Huang, Xing‐Lu He, Yan Luo, Yi‐Lei Xiang, Lin‐bin Jiang, Min Dong, Shixiong Li, Zhong Zhang and Jin Huang

Angew Chem Int Ed, 2024, 63
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Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Estefanía Tiburcio, Rossella Greco, Marta Mon, Jordi Ballesteros-Soberanas, Jesús Ferrando-Soria, Miguel López-Haro, Juan Carlos Hernández-Garrido, Judit Oliver-Meseguer, Carlo Marini, Mercedes Boronat, Donatella Armentano, Antonio Leyva-Pérez and Emilio Pardo

J. Am. Chem. Soc., 2021, 143, 2581
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Single-Crystal-to-Single-Crystal Transformations of Metal–Organic-Framework-Supported, Site-Isolated Trigonal-Planar Cu(I) Complexes with Labile Ligands

Ricardo A. Peralta, Michael T. Huxley, Jorge Albalad, Christopher J. Sumby and Christian J. Doonan

Inorg. Chem., 2021, 60, 11775
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Metal‐Organic Frameworks and Metal‐Organic Cages – A Perspective

Ben S. Pilgrim and Neil R. Champness

ChemPlusChem, 2020, 85, 1842
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Solid/Gas In Crystallo Reactivity of an Ir(I) Methylidene Complex

Kristof M. Altus, M. Arif Sajjad, Matthew R. Gyton, Adrian C. Whitwood, Samuel J. Page, Stuart A. Macgregor and Andrew S. Weller

Organometallics, 2024, 43, 3137
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CTAB-caped Cu nanoparticles doped on zeolitic imidazolate framework-ZIF-67 as bifunctional catalysts for oxygen-reduction and evolution reactions in alkaline media

Anand Parkash

J Porous Mater, 2021, 28, 1245
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Boronate Covalent and Hybrid Organic Frameworks Featuring PIII and P=O Lewis Base Sites

Piotr Pacholak, Krzysztof Gontarczyk, Radosław Kamiński, Krzysztof Durka and Sergiusz Luliński

Chemistry A European J, 2020, 26, 12758
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A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane

Alexander J. Bukvic, Arron L. Burnage, Graham J. Tizzard, Antonio J. Martínez-Martínez, Alasdair I. McKay, Nicholas H. Rees, Bengt E. Tegner, Tobias Krämer, Heather Fish, Mark R. Warren, Simon J. Coles, Stuart A. Macgregor and Andrew S. Weller

J. Am. Chem. Soc., 2021, 143, 5106
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Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction

Estefanía Tiburcio, Yongkun Zheng, Marta Mon, Nuria Martín, Jesús Ferrando−Soria, Donatella Armentano, Antonio Leyva−Pérez and Emilio Pardo

Inorg. Chem., 2022, 61, 11796
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Chemoselective Oxidation of Alkenes by Metal‐Organic Framework‐Supported Copper Catalyst

Rahul Kalita, Wahida Begum, Poorvi Gupta, Manav Chauhan, Naved Akhtar, Rajashree Newar and Kuntal Manna

Eur J Inorg Chem, 2023, 26
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Metal Center-Tuned Photocatalytic Carbon Dioxide Reduction for Frameworks with the Tetraphenylethene–Imidazole Ligand

Zhao-Feng Qiu, Peng Wang, Kai-Yang Zhang, Yue Zhao and Wei-Yin Sun

Inorg. Chem., 2024, 63, 18193
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Hydrolase–like catalysis and structural resolution of natural products by a metal–organic framework

Marta Mon, Rosaria Bruno, Sergio Sanz-Navarro, Cristina Negro, Jesús Ferrando-Soria, Lucia Bartella, Leonardo Di Donna, Mario Prejanò, Tiziana Marino, Antonio Leyva-Pérez, Donatella Armentano and Emilio Pardo

Nat Commun, 2020, 11
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Metal–Organic Framework Supported Low‐Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol

Bing Shao, Du Huang, Rui‐Kang Huang, Xing‐Lu He, Yan Luo, Yi‐Lei Xiang, Lin‐bin Jiang, Min Dong, Shixiong Li, Zhong Zhang and Jin Huang

Angewandte Chemie, 2024, 136
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Photodegradation of Brilliant Green Dye by a Zinc bioMOF and Crystallographic Visualization of Resulting CO2

Paula Escamilla, Marta Viciano-Chumillas, Rosaria Bruno, Donatella Armentano, Emilio Pardo and Jesús Ferrando-Soria

Molecules, 2021, 26, 4098
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Thermal Elimination of Ethylene from Cyclobutyl Groups Characterized by X‐ray Crystallography in a Metal–Organic Framework Matrix

Adil Alkaş, Laurine E. S. Friche, Shikeale N. Harris and Shane G. Telfer

Chemistry A European J, 2020, 26, 10321
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Nanoparticles derived from naturally occurring metal chelators for theranostic applications

Wonsik Jung, Dong Yun Lee, Eugene Moon and Sangyong Jon

Advanced Drug Delivery Reviews, 2022, 191, 114620
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Metal–Organic Frameworks with Zero and Low‐Valent Metal Nodes Connected by Tetratopic Phosphine Ligands

R. Eric Sikma and Seth M. Cohen

Angewandte Chemie, 2022, 134
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CO2 Fixation and Release Mediated by Carbonate-Based Coordination Polymers

Kentaro Kadota, Sae Matsui, Ayoub Traverson, Yuta Hori, Kanchana Sotho, Kei Morisato, Yoshitaka Aoyama, Yasuteru Shigeta, Yusuke Nishiyama and Satoshi Horike

J. Am. Chem. Soc., 2025, 147, 30022
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MOF-based DNA hydrolases optimized by atom engineering for the removal of antibiotic-resistant genes from aquatic environment

Ge Fang, Ruonan Kang, Yu Chong, Liming Wang, Chuanqiang Wu and Cuicui Ge

Applied Catalysis B: Environmental, 2023, 320, 121931
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Hierarchical porosity and tailored surface functionality synergism enabling high-selectivity and capacity CH4/N2 separation for coalbed methane purification

Zhi Cui, Yizhong Li, Guanhao Zeng, Xiaoqing Yan, Jingkang Yuan, Shuyuan Gao, Qiudi Yue and Guidong Yang

Chemical Engineering Science, 2026, 321, 122890
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Metal‐Organic Frameworks as Unique Platforms to Gain Insight of σ‐Hole Interactions for the Removal of Organic Dyes from Aquatic Ecosystems

Cristina Negro, Paula Escamilla, Rosaria Bruno, Jesus Ferrando‐Soria, Donatella Armentano and Emilio Pardo

Chemistry A European J, 2022, 28
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Multi-Point Solid-Supported Phosphines for Highly Active Heterogeneous Transition-Metal Catalysts

Tomohiro Iwai

J. Synth. Org. Chem. Jpn., 2022, 80, 198
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Ag2(0) dimers within a thioether-functionalized MOF catalyze the CO2 to CH4 hydrogenation reaction

Yongkun Zheng, Nuria Martín, Mercedes Boronat, Jesús Ferrando-Soria, Marta Mon, Donatella Armentano, Emilio Pardo and Antonio Leyva-Pérez

Sci Rep, 2023, 13
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Supramolecular Chemistry in Metal–Organic Framework Materials

Eugenia Miguel‐Casañ, Georgia R. F. Orton, Danielle E. Schier and Neil R. Champness

Advanced Materials, 2025, 37
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Rhodium Carbonyl Complexes within the Tunable Microenvironments of UiO-66 Analogues

Rashid G Siddique, Thomas E. Anthony, Jack D. Evans, Christopher J. Sumby and Christian J. Doonan

Inorg. Chem., 2025, 64, 22533
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Atomic-Scale Elucidation of Unusually Distorted Dimeric Complexes Confined in a Zr-Based Metal–Organic Framework

Pol Gimeno-Fonquernie, Jorge Albalad, Jack D. Evans, Jason Price, Christian J. Doonan and Christopher J. Sumby

Inorg. Chem., 2023, 62, 19208
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Conceptual and Practical Aspects of Metal–Organic Frameworks for Solid–Gas Reactions

Andrei Iliescu, Julius J. Oppenheim, Chenyue Sun and Mircea Dincǎ

Chem. Rev., 2023, 123, 6197
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Organoarsine Metal–Organic Framework as a Solid-State Ligand for Rhodium(I) Olefin Hydroformylation Catalysis

Venkatesh Piradi, Wenrui Chai, Samuel K. Emslie, R. Eric Sikma, Chuning Zhang, Serhii Vasylevskyi, Graeme Henkelman and Simon M. Humphrey

J. Am. Chem. Soc., 2025, 147, 29119
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Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs

R. Eric Sikma, Naman Katyal, Su-Kyung Lee, Joseph W. Fryer, Catherine G. Romero, Samuel K. Emslie, Elinor L. Taylor, Vincent M. Lynch, Jong-San Chang, Graeme Henkelman and Simon M. Humphrey

J. Am. Chem. Soc., 2021, 143, 13710
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Supramolecular Chemistry: An Enabling Tool for Asymmetric Catalysis

Laura Cunningham

Synlett, 2025, 36, 1189
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Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State

Samantha K. Furfari, Bengt E. Tegner, Arron L. Burnage, Laurence R. Doyle, Alexander J. Bukvic, Stuart A. Macgregor and Andrew S. Weller

Chemistry A European J, 2021, 27, 3177
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Multivariate Metal–Organic Framework/Single-Walled Carbon Nanotube Buckypaper for Selective Lead Decontamination

Mariafrancesca Baratta, Teresa Fina Mastropietro, Rosaria Bruno, Antonio Tursi, Cristina Negro, Jesús Ferrando-Soria, Alexander I. Mashin, Aleksey Nezhdanov, Fiore P. Nicoletta, Giovanni De Filpo, Emilio Pardo and Donatella Armentano

ACS Appl. Nano Mater., 2022, 5, 5223
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One-Pot, Room-Temperature Conversion of CO2 into Porous Metal–Organic Frameworks

Kentaro Kadota, You-lee Hong, Yusuke Nishiyama, Easan Sivaniah, Daniel Packwood and Satoshi Horike

J. Am. Chem. Soc., 2021, 143, 16750
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Metal–Organic Frameworks with Low‐Valent Metal Nodes

R. Eric Sikma, Krista P. Balto, Joshua S. Figueroa and Seth M. Cohen

Angewandte Chemie, 2022, 134
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Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

Ricardo A. Peralta, Pengbo Lyu, Alfredo López‐Olvera, Juan L. Obeso, Carolina Leyva, Nak Cheon Jeong, Ilich A. Ibarra and Guillaume Maurin

Angew Chem Int Ed, 2022, 61
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An Operationally Unsaturated Iridium-Pincer Complex That C–H Activates Methane and Ethane in the Crystalline Solid-State

Matthew R. Gyton, M. Arif Sajjad, Daniel J. Storm, Kristof M. Altus, Joe C. Goodall, Chloe L. Johnson, Samuel J. Page, Alison J. Edwards, Ross O. Piltz, Simon B. Duckett, Stuart A. Macgregor and Andrew S. Weller

J. Am. Chem. Soc., 2025, 147, 8706
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N, N’-bidentate ligand anchored palladium catalysts on MOFs for efficient Heck reaction

Xiao-Li Xu, Nian-Nian Wang, Yong-Hao Zou, Xiao Qin, Peng Wang, Xiang-Yu Lu, Xiao-Yu Zhang, Wei-Yin Sun and Yi Lu

Nat Commun, 2024, 15
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MOF-Triggered Synthesis of Subnanometer Ag02 Clusters and Fe3+ Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions

Estefanía Tiburcio, Yongkun Zheng, Cristina Bilanin, Juan Carlos Hernández-Garrido, Alejandro Vidal-Moya, Judit Oliver-Meseguer, Nuria Martín, Marta Mon, Jesús Ferrando-Soria, Donatella Armentano, Antonio Leyva-Pérez and Emilio Pardo

J. Am. Chem. Soc., 2023, 145, 10342
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Heterogeneous Nanosized Metal (Metallic Compound)@Metal‐Organic Framework Composites: Recent Advances in the Preparation and Applications

Yang Cui, Yujie Zhao, Jie Wu and Hongwei Hou

Adv Funct Materials, 2023, 33
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Isolation of a Terminal Cobalt Nitride in a Metal–Organic Framework

Jonas Börgel, Nicole Removski, Jordan W. Taylor, Zikri Hasanbasri, Khetpakorn Chakarawet, Alexander J. Heyer, Patrick W. Smith, N. Isaac Zakaria, Danh X. Ngo, Ryan A. Klein, Maria V. Paley, Vincent R. Allen, Chaochao Dun, Henry Z. H. Jiang, Nykita Z. Rustad, Tieyan Chang, Ying-Pin Chen, Mauricio Lopez Luna, Wanli Yang, Brandon R. Barnett, Jeffrey A. Reimer, Yu-Sheng Chen, Jeffrey J. Urban, Monika Blum, Stefan G. Minasian, Edward I. Solomon, R. David Britt, T. David Harris and Jeffrey R. Long

J. Am. Chem. Soc., 2026, 148, 837
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Crystallographic Visualization of a Double Water Molecule Addition on a Pt1‐MOF during the Low‐temperature Water‐Gas Shift Reaction

Cristina Bilanin, Estefanía Tiburcio, Jesús Ferrando‐Soria, Donatella Armentano, Antonio Leyva‐Pérez and Emilio Pardo

ChemCatChem, 2021, 13, 1195
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