Kaili Liu, Pengfei Cao, Wei Chen, Collins I. Ezeh, Zijian Chen, Yonglan Luo, Qian Liu, Haitao Zhao, Zhenhua Rui, Shuyan Gao, Zongyou Yin, Xuping Sun and Xuefeng Yu

Mater. Adv., 2022, 3, 1359
DOI: 10.1039/D1MA00814E

Atomically dispersed metal catalysts for the electrochemical nitrogen reduction reaction

Hongfei Gu, Wenxing Chen and Xinyuan Li

J. Mater. Chem. A, 2022, 10, 22331
DOI: 10.1039/D2TA06187B

Facile, cost-effective plasma synthesis of self-supportive FeSx on Fe foam for efficient electrochemical reduction of N2 under ambient conditions

Wei Xiong, Zheng Guo, Shijun Zhao, Qian Wang, Qiyong Xu and Xinwei Wang

J. Mater. Chem. A, 2019, 7, 19977
DOI: 10.1039/C9TA07790A

One-pot synthesis of bi-metallic PdRu tripods as an efficient catalyst for electrocatalytic nitrogen reduction to ammonia

Hongjing Wang, Yinghao Li, Chunjie Li, Kai Deng, Ziqiang Wang, You Xu, Xiaonian Li, Hairong Xue and Liang Wang

J. Mater. Chem. A, 2019, 7, 801
DOI: 10.1039/C8TA09482A

Recent advances in catalysts, electrolytes and electrode engineering for the nitrogen reduction reaction under ambient conditions

Junbo Hou, Min Yang and Junliang Zhang

Nanoscale, 2020, 12, 6900
DOI: 10.1039/D0NR00412J

Effective electrode design and the reaction mechanism for electrochemical promotion of ammonia synthesis using Fe-based electrode catalysts

Chien-I. Li, Hiroki Matsuo and Junichiro Otomo

Sustainable Energy Fuels, 2021, 5, 188
DOI: 10.1039/D0SE01385D

Single atom catalysis for electrocatalytic ammonia synthesis

Jieying Wan, Jiageng Zheng, Hao Zhang, Angjian Wu and Xiaodong Li

Catal. Sci. Technol., 2022, 12, 38
DOI: 10.1039/D1CY01442K

Methanol-assisted energy-efficient water splitting over rambutan-like Au@PdRu core–shell nanocatalysts

Hongjing Wang, Lin Cui, Shuli Yin, Hongjie Yu, Kai Deng, You Xu, Xin Wang, Ziqiang Wang and Liang Wang

J. Mater. Chem. A, 2022, 10, 18889
DOI: 10.1039/D2TA04440D

Single transition metal atom embedded into a MoS2 nanosheet as a promising catalyst for electrochemical ammonia synthesis

Jia Zhao, Jingxiang Zhao and Qinghai Cai

Phys. Chem. Chem. Phys., 2018, 20, 9248
DOI: 10.1039/C7CP08626A

Recent progress in the development of electrocatalysts for the electrochemical N2reduction reaction

Kousik Bhunia, Sanjeev Kumar Sharma, Biraj Kanta Satpathy and Debabrata Pradhan

Mater. Adv., 2022, 3, 888
DOI: 10.1039/D1MA00680K

A thermodynamic and kinetic study of the catalytic performance of Fe, Mo, Rh and Ru for the electrochemical nitrogen reduction reaction

Jun-Lin Shi, Shi-Qin Xiang, Wei Zhang and Liu-Bin Zhao

Phys. Chem. Chem. Phys., 2020, 22, 25973
DOI: 10.1039/D0CP05072E

Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage

Turgut M. Gür

Energy Environ. Sci., 2018, 11, 2696
DOI: 10.1039/C8EE01419A

Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids

Fengling Zhou, Luis Miguel Azofra, Muataz Ali, Mega Kar, Alexandr N. Simonov, Ciaran McDonnell-Worth, Chenghua Sun, Xinyi Zhang and Douglas R. MacFarlane

Energy Environ. Sci., 2017, 10, 2516
DOI: 10.1039/C7EE02716H

Recent advances on electrocatalytic fixation of nitrogen under ambient conditions

Bin Wu, Yichao Lin, Xuezhen Wang and Liang Chen

Mater. Chem. Front., 2021, 5, 5516
DOI: 10.1039/D1QM00269D

A two-dimensional Ru@MXene catalyst for highly selective ambient electrocatalytic nitrogen reduction

Anmin Liu, Mengfan Gao, Xuefeng Ren, Fanning Meng, Yanan Yang, Qiyue Yang, Weixin Guan, Liguo Gao, Xingyou Liang and Tingli Ma

Nanoscale, 2020, 12, 10933
DOI: 10.1039/D0NR00788A

Elementary kinetics of nitrogen electroreduction to ammonia on late transition metals

Gholamreza Rostamikia, Sharad Maheshwari and Michael J. Janik

Catal. Sci. Technol., 2019, 9, 174
DOI: 10.1039/C8CY01845F

Ru–polyoxometalate as a single-atom electrocatalyst for N2 reduction to NH3 with high selectivity at applied voltage: a perspective from DFT studies

Linghui Lin, Liye Gao, Ke Xie, Rong Jiang and Sen Lin

Phys. Chem. Chem. Phys., 2020, 22, 7234
DOI: 10.1039/D0CP00698J

Computational screening of a single transition metal atom supported on the C2N monolayer for electrochemical ammonia synthesis

Zhongxu Wang, Zhigang Yu and Jingxiang Zhao

Phys. Chem. Chem. Phys., 2018, 20, 12835
DOI: 10.1039/C8CP01215F

A small change in the local atomic environment for a big improvement in single-atom catalysis

Hao Li, Bing Yu, Zechao Zhuang, Wenping Sun, Baohua Jia and Tianyi Ma

J. Mater. Chem. A, 2021, 9, 4184
DOI: 10.1039/D0TA10823E

Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design

Wenhan Guo, Kexin Zhang, Zibin Liang, Ruqiang Zou and Qiang Xu

Chem. Soc. Rev., 2019, 48, 5658
DOI: 10.1039/C9CS00159J

Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction

Suzanne Z. Andersen, Michael J. Statt, Vanessa J. Bukas, Sarah G. Shapel, Jakob B. Pedersen, Kevin Krempl, Mattia Saccoccio, Debasish Chakraborty, Jakob Kibsgaard, Peter C. K. Vesborg, Jens Nørskov and Ib Chorkendorff

Energy Environ. Sci., 2020, 13, 4291
DOI: 10.1039/D0EE02246B

A DFT screening of single transition atoms supported on MoS2 as highly efficient electrocatalysts for the nitrogen reduction reaction

Xingwu Zhai, Lei Li, Xiaoyue Liu, Yafei Li, Jueming Yang, Dezheng Yang, Jinli Zhang, Hongxia Yan and Guixian Ge

Nanoscale, 2020, 12, 10035
DOI: 10.1039/D0NR00030B

A universal descriptor for two-dimensional carbon nitride-based single-atom electrocatalysts towards the nitrogen reduction reaction

Mengmeng Xu, Yujin Ji, Yuyang Qin, Huilong Dong and Youyong Li

J. Mater. Chem. A, 2024, 12, 28046
DOI: 10.1039/D4TA05067C

Computational screening of single-atom alloys TM@Ru(0001) for enhanced electrochemical nitrogen reduction reaction

Gurpreet Kour, Xin Mao and Aijun Du

J. Mater. Chem. A, 2022, 10, 6204
DOI: 10.1039/D1TA08246A

High-throughput design of bimetallic core–shell catalysts for the electrochemical nitrogen reduction reaction

Sooyeon Kim, Min-Cheol Kim, Byung Chul Yeo and Sang Soo Han

J. Mater. Chem. A, 2023, 11, 24686
DOI: 10.1039/D3TA05408J

Electrochemical ammonia synthesis: fundamental practices and recent developments in transition metal boride, carbide and nitride-class of catalysts

Ashmita Biswas, Sakshi Bhardwaj, Tribani Boruah and Ramendra Sundar Dey

Mater. Adv., 2022, 3, 5207
DOI: 10.1039/D2MA00279E

Exploring the synergistic effect of B–N doped defective graphdiyne for N2 fixation

Jingeng Cao, Nan Li and Xin Zeng

New J. Chem., 2021, 45, 6327
DOI: 10.1039/D1NJ00163A

Theoretical study of single transition metal atom modified MoP as a nitrogen reduction electrocatalyst

Miaomiao Han, Guozhong Wang, Haimin Zhang and Huijun Zhao

Phys. Chem. Chem. Phys., 2019, 21, 5950
DOI: 10.1039/C9CP00621D

Mechanistic aspects of ammonia synthesis on Ta3N5 surfaces in the presence of intrinsic nitrogen vacancies

Constantinos D. Zeinalipour-Yazdi

Phys. Chem. Chem. Phys., 2021, 23, 6959
DOI: 10.1039/D1CP00275A

Electro-reduction of N2 on nanostructured materials and the design strategies of advanced catalysts based on descriptors

Chenxu Zhao, Menghui Xi, Jinrong Huo, Chaozheng He and Ling Fu

Materials Today Physics, 2022, 22, 100609
DOI: 10.1016/j.mtphys.2022.100609

Robust Copper-Based Nanosponge Architecture Decorated by Ruthenium with Enhanced Electrocatalytic Performance for Ambient Nitrogen Reduction to Ammonia

Kui Li, Lei Ding, Zhiqiang Xie, Gaoqiang Yang, Shule Yu, Weitian Wang, David A. Cullen, Harry M. Meyer, Guoxiang Hu, Panchapakesan Ganesh, Thomas R. Watkins and Feng-Yuan Zhang

ACS Appl. Mater. Interfaces, 2023, 15, 11703
DOI: 10.1021/acsami.2c20809

Single-atom catalysts boost nitrogen electroreduction reaction

Yanling Zhai, Zhijun Zhu, Chengzhou Zhu, Kyle Chen, Xueji Zhang, Jing Tang and Jun Chen

Materials Today, 2020, 38, 99
DOI: 10.1016/j.mattod.2020.03.022

Progress in Computational and Machine‐Learning Methods for Heterogeneous Small‐Molecule Activation

Geun Ho Gu, Changhyeok Choi, Yeunhee Lee, Andres B. Situmorang, Juhwan Noh, Yong‐Hyun Kim and Yousung Jung

Advanced Materials, 2020, 32
DOI: 10.1002/adma.201907865

Recent progress in the electrochemical ammonia synthesis under ambient conditions

Runbo Zhao, Hongtao Xie, Le Chang, Xiaoxue Zhang, Xiaojuan Zhu, Xin Tong, Ting Wang, Yonglan Luo, Peipei Wei, Zhiming Wang and Xuping Sun

EnergyChem, 2019, 1, 100011
DOI: 10.1016/j.enchem.2019.100011

Engineering of electrocatalyst/electrolyte interface for ambient ammonia synthesis

Lei Du, Lixin Xing, Gaixia Zhang, Xianhu Liu, Diane Rawach and Shuhui Sun

SusMat, 2021, 1, 150
DOI: 10.1002/sus2.7

Computational design of two-dimensional transition metal supported biphenylene as efficient electrocatalysts toward nitrogen reduction reaction

Dinesh Kumar Dhanthala Chittibabu and Hsin-Tsung Chen

Electrochimica Acta, 2024, 497, 144578
DOI: 10.1016/j.electacta.2024.144578

Design Refinement of Catalytic System for Scale-Up Mild Nitrogen Photo-Fixation

Xiao Hu Wang, Bin Wu, Yongfa Zhu, Dingsheng Wang, Nian Bing Li, Zhichuan J. Xu and Hong Qun Luo

Nano-Micro Lett., 2025, 17
DOI: 10.1007/s40820-025-01695-3

V2O4 Nanowires/rGO Hybrid for Electrocatalytic Nitrogen Fixation

Shaona Chen, Yanhua Liang, Mengke Bu, Zhongxu Dai and Jinjin Shi

Catal Lett, 2024, 154, 1795
DOI: 10.1007/s10562-023-04415-x

Robust Analysis of 4e– Versus 6e– Reduction of Nitrogen on Metal Surfaces and Single-Atom Alloys

Lydia Maria Tsiverioti, Lance Kavalsky and Venkatasubramanian Viswanathan

J. Phys. Chem. C, 2022, 126, 12994
DOI: 10.1021/acs.jpcc.2c01630

Recent progress in noble metal electrocatalysts for nitrogen-to-ammonia conversion

Xufeng Rao, Minmin Liu, Meifang Chien, Chihiro Inoue, Jiujun Zhang and Yuyu Liu

Renewable and Sustainable Energy Reviews, 2022, 168, 112845
DOI: 10.1016/j.rser.2022.112845

Electrochemical synthesis of ammonia using ruthenium–platinum alloy at ambient pressure and low temperature

Revanasiddappa Manjunatha and Alex Schechter

Electrochemistry Communications, 2018, 90, 96
DOI: 10.1016/j.elecom.2018.04.008

Theoretical insights into electronic structure and NRR catalytic mechanism based on halide perovskites CsPbBr3-xIx

Yuzhen Fang, Shuangxin Dou, Qianqian Shang, Dongting Wang, Junhai Liu and Xiangjin Kong

Computational Materials Science, 2022, 212, 111576
DOI: 10.1016/j.commatsci.2022.111576

Prussian Blue-Derived Fe@NC as an Efficient Electrocatalyst for Ammonia Synthesis under Ambient Conditions

Xiao Ma, Shuhao Yan, Wei Yi, Jing He and Lanhua Yi

ACS Sustainable Chem. Eng., 2022, 10, 12148
DOI: 10.1021/acssuschemeng.2c02596

Highly Efficient Ammonia Synthesis by Gas–Liquid Interface Pulsed Discharge Plasma: A Synthesis Method without Hydrogen

Yuanyuan Wang, Qiuying Wang, Shaohua Sun, Yanbin Xin, Xiaomei Zhu and Bing Sun

ACS Sustainable Chem. Eng., 2023, 11, 13070
DOI: 10.1021/acssuschemeng.3c03021

Comparing B3LYP and B97 Dispersion‐corrected Functionals for Studying Adsorption and Vibrational Spectra in Nitrogen Reduction

Esther F. Grossman, Damilola A. Daramola and Gerardine G. Botte

ChemistryOpen, 2021, 10, 316
DOI: 10.1002/open.202000158

Coupling ZnN4 Atomic Sites with Graphitic Nitrogen for Enhanced Ammonium Production via Electrocatalytic Nitrate Reduction

Qianghua Li, Yixuan Ma, Qingling Zeng, Wenjun Liu, Chunfeng Wang, Shun Han, Peijiang Cao, Deliang Zhu and Ming Fang

Small, 2025, 21
DOI: 10.1002/smll.202409925

Prediction of single-boron anchored on MXene catalysts for high-efficient electrocatalytic nitrogen reduction reaction

Ning Zhang, Mei-yan Wang and Jing-Yao Liu

Molecular Catalysis, 2022, 531, 112658
DOI: 10.1016/j.mcat.2022.112658

Plasma Radicals as Kinetics-Controlling Species during Plasma-Assisted Catalytic NH3 Formation: Support from Microkinetic Modeling

Tsung-Wei Liu, Fnu Gorky, Maria L. Carreon and Diego A. Gomez-Gualdron

ACS Sustainable Chem. Eng., 2023, 11, 16749
DOI: 10.1021/acssuschemeng.3c03813

Elucidating the Mechanism of Electrochemical N2 Reduction at the Ru(0001) Electrode

Ebrahim Tayyebi, Younes Abghoui and Egill Skúlason

ACS Catal., 2019, 9, 11137
DOI: 10.1021/acscatal.9b03903

Powerful Orbital Hybridization of Copper–Silver Bimetallic Nanosheets for Electrocatalytic Nitrogen Reduction to Ammonia

Xiaoying Lu, Jian Li, Fen Liu, Yantao Wang, Xiaohai Tang, Hua Li, Yong Peng and Cailing Xu

Inorg. Chem., 2023, 62, 12148
DOI: 10.1021/acs.inorgchem.3c01766

Iron-group single-atom catalysts for ammonia synthesis and decomposition

Filippo Bossola, Giulia Tuci, Nicola Sangiorgi, Alessandra Sanson, Vladimiro Dal Santo, Rinaldo Psaro and Giuliano Giambastiani

Rend. Fis. Acc. Lincei, 2025, 36, 659
DOI: 10.1007/s12210-025-01329-1

Rational catalyst design and mechanistic evaluation for electrochemical nitrogen reduction at ambient conditions

Muhammad Ibrar Ahmed, David Brynn Hibbert and Chuan Zhao

Green Energy & Environment, 2023, 8, 1567
DOI: 10.1016/j.gee.2022.10.001

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Shivaraj B. Patil and Di‐Yan Wang

Small, 2020, 16
DOI: 10.1002/smll.202002885

Asymmetric hydrogenation-driven enhancement of activity and selectivity in V-anchored N3-doped graphene catalysts for nitrogen reduction

Wenming Lu, Kai Guo, Daifei Ye, Xiaxia Gong, Wei Liu and Jing Xu

International Journal of Hydrogen Energy, 2025, 162, 150787
DOI: 10.1016/j.ijhydene.2025.150787

A Plasmon Resonance Enhanced Photo‐Electrode to Promote NH3 Yield in Sustainable N2 Conversion

Haonan Wang, Chuanqi Cheng, Kun Du, Zongwei Xu, Erling Zhao, Ning Lan, Peng‐Fei Yin and Tao Ling

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300204

A comparative analysis of the mechanisms of ammonia synthesis on various catalysts using density functional theory

Constantinos D. Zeinalipour-Yazdi, Justin S. J. Hargreaves, Said Laassiri and C. Richard A. Catlow

R. Soc. open sci., 2021, 8
DOI: 10.1098/rsos.210952

Simplification of solvation shell with water clusters in the simulation of electrochemical nitrogen reduction reaction

Han-Xuan Liu, Zheng-Qing Huang, Xin Gao, Guidong Yang and Chun-Ran Chang

The Journal of Chemical Physics, 2024, 161
DOI: 10.1063/5.0230137

Electron-driven heterogeneous catalytic synthesis of ammonia: Current states and perspective

Ke Wang, Daniel Smith and Ying Zheng

Carbon Resources Conversion, 2018, 1, 2
DOI: 10.1016/j.crcon.2018.06.004

Single-atomic site catalysts for electrochemical nitrogen fixation

Mingwei Chang, Jing Wu, Li Xu and Liming Zhang

Materials Research Letters, 2023, 11, 697
DOI: 10.1080/21663831.2023.2209156

Sulfur vacancies-doped Sb2S3 nanorods as high-efficient electrocatalysts for dinitrogen fixation under ambient conditions

Xuyan Wang, Jianwei Bai, Yantao Wang, Xiaoying Lu, Zehua Zou, Junfeng Huang and Cailing Xu

Green Energy & Environment, 2022, 7, 755
DOI: 10.1016/j.gee.2020.11.016

Screening of transition metal single-atom catalysts doped on γ-graphyne-like BN sheet for efficient nitrogen reduction reaction

Tongtong Li, Yibo Wu and Mengying Pei

Journal of Alloys and Compounds, 2022, 908, 164675
DOI: 10.1016/j.jallcom.2022.164675

Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design

Huidong Shen, Changhyeok Choi, Justus Masa, Xin Li, Jieshan Qiu, Yousung Jung and Zhenyu Sun

Chem, 2021, 7, 1708
DOI: 10.1016/j.chempr.2021.01.009

The Pulsed Electrocatalysis of Humidified Air for Selective Ammonia Production

Amir H. Aslambakhsh, Sandra E. Kentish and Colin A. Scholes

ACS Appl. Energy Mater., 2025, 8, 10392
DOI: 10.1021/acsaem.5c01302

Single Mo1(Cr1) Atom on Nitrogen-Doped Graphene Enables Highly Selective Electroreduction of Nitrogen into Ammonia

Wanghui Zhao, Lifu Zhang, Qiquan Luo, Zhenpeng Hu, Wenhua Zhang, Sean Smith and Jinlong Yang

ACS Catal., 2019, 9, 3419
DOI: 10.1021/acscatal.8b05061

Theoretical Insights on Au‐based Bimetallic Alloy Electrocatalysts for Nitrogen Reduction Reaction with High Selectivity and Activity

Jun‐Lin Shi, Shi‐Qin Xiang, Dai‐Jian Su, Xiaohong Liu, Wei Zhang and Liu‐Bin Zhao

ChemSusChem, 2021, 14, 4525
DOI: 10.1002/cssc.202101462

gt-C3N4 coordinated single atom as an efficient electrocatalyst for nitrogen reduction reaction

Lifu Zhang, Wanghui Zhao, Wenhua Zhang, Jing Chen and Zhenpeng Hu

Nano Res., 2019, 12, 1181
DOI: 10.1007/s12274-019-2378-8

Role of Protons in Electrochemical Ammonia Synthesis Using Solid-State Electrolytes

Chung-Yul Yoo, Jong Hyun Park, Kwiyong Kim, Jong-In Han, Eun-Young Jeong, Chan-Hee Jeong, Hyung Chul Yoon and Jong-Nam Kim

ACS Sustainable Chem. Eng., 2017, 5, 7972
DOI: 10.1021/acssuschemeng.7b01515

Molecular single iron site catalysts for electrochemical nitrogen fixation under ambient conditions

Xiaoxuan Yang, Sai Sun, Ling Meng, Ke Li, Shreya Mukherjee, Xinyu Chen, Jiaqi Lv, Song Liang, Hong-Ying Zang, Li-Kai Yan and Gang Wu

Applied Catalysis B: Environmental, 2021, 285, 119794
DOI: 10.1016/j.apcatb.2020.119794

Vacancy-rich 1T-MoS2 monolayer confined to MoO3 matrix: An interface-engineered hybrid for efficiently electrocatalytic conversion of nitrogen to ammonia

Xiangrong Zi, Jin Wan, Xiaohui Yang, Wu Tian, Huijuan Zhang and Yu Wang

Applied Catalysis B: Environmental, 2021, 286, 119870
DOI: 10.1016/j.apcatb.2020.119870

Composition-dependent electrochemical activity of Ag-based alloy nanotubes for efficient nitrogen reduction under ambient conditions

Qiwen Zhang, Yongli Shen, Yufan Hou, Liting Yang, Baili Chen, Zhen Lei and Weiqing Zhang

Electrochimica Acta, 2019, 321, 134691
DOI: 10.1016/j.electacta.2019.134691

Tuning nitrogen reduction reaction activity via controllable Fe magnetic moment: A computational study of single Fe atom supported on defective graphene

Xiangyu Guo and Shiping Huang

Electrochimica Acta, 2018, 284, 392
DOI: 10.1016/j.electacta.2018.07.168

Selective Electrochemical Nitrogen Reduction Driven by Hydrogen Bond Interactions at Metal–Ionic Liquid Interfaces

Manuel A. Ortuño, Oldamur Hollóczki, Barbara Kirchner and Núria López

J. Phys. Chem. Lett., 2019, 10, 513
DOI: 10.1021/acs.jpclett.8b03409

Activating nano-bulk interplays for sustainable ammonia electrosynthesis

Meng Li, Bin Hua, Wei Wu, Lu-Cun Wang, Yong Ding, Märtha M. Welander, Robert A. Walker and Dong Ding

Materials Today, 2022, 60, 31
DOI: 10.1016/j.mattod.2022.09.011

Rational Design of Atomic Site Catalysts for Electrocatalytic Nitrogen Reduction Reaction: One Step Closer to Optimum Activity and Selectivity

Yiran Ying, Ke Fan, Jinli Qiao and Haitao Huang

Electrochem. Energy Rev., 2022, 5
DOI: 10.1007/s41918-022-00164-4

Theoretical Design and Screening of Bimetal-Doped Graphite Nitride Electrocatalysts for Nitrogen Reduction Reaction

Hongyun Cui, Shilong Li, Jirui Du, Haohao Wang, Ning Ma, Min Pu and Ming Lei

Chem. Mater., 2025, 37, 3392
DOI: 10.1021/acs.chemmater.5c00207

Ion-conducting ceramic membrane reactors for high-temperature applications

Wendelin Deibert, Mariya E. Ivanova, Stefan Baumann, Olivier Guillon and Wilhelm A. Meulenberg

Journal of Membrane Science, 2017, 543, 79
DOI: 10.1016/j.memsci.2017.08.016

Ru-doped barium strontium titanates of the cathode for the electrochemical synthesis of ammonia

Hwan Kim, Yong Sik Chung, Taewook Kim, Heechul Yoon, Jae Gi Sung, Han Kyu Jung, Won Bae Kim, Lauren Beverly Sammes and Jong Shik Chung

Solid State Ionics, 2019, 339, 115010
DOI: 10.1016/j.ssi.2019.115010

Understanding the Electrocatalytic Interface for Ambient Ammonia Synthesis

Lin Hu, Zhuo Xing and Xiaofeng Feng

ACS Energy Lett., 2020, 5, 430
DOI: 10.1021/acsenergylett.9b02679

Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts

Olivia Westhead, Jesús Barrio, Alexander Bagger, James W. Murray, Jan Rossmeisl, Maria-Magdalena Titirici, Rhodri Jervis, Andrea Fantuzzi, Andrew Ashley and Ifan E. L. Stephens

Nat Rev Chem, 2023, 7, 184
DOI: 10.1038/s41570-023-00462-5

Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water

Yu-Chen Hao, Yu Guo, Li-Wei Chen, Miao Shu, Xin-Yu Wang, Tong-An Bu, Wen-Yan Gao, Nan Zhang, Xin Su, Xiao Feng, Jun-Wen Zhou, Bo Wang, Chang-Wen Hu, An-Xiang Yin, Rui Si, Ya-Wen Zhang and Chun-Hua Yan

Nat Catal, 2019, 2, 448
DOI: 10.1038/s41929-019-0241-7

Attenuated total reflection infrared spectroscopy for studying electrochemical cycling of hydrogen, carbon, and nitrogen-containing molecules

Xuezhao Liu, Pengcheng Zhao, Feifei Liu, Richen Lin, Huifeng Yao and Shangqian Zhu

Journal of Energy Chemistry, 2024, 99, 495
DOI: 10.1016/j.jechem.2024.08.008

Understanding potential-dependent competition between electrocatalytic dinitrogen and proton reduction reactions

Changhyeok Choi, Geun Ho Gu, Juhwan Noh, Hyun S. Park and Yousung Jung

Nat Commun, 2021, 12
DOI: 10.1038/s41467-021-24539-1

Hierarchical hollow nanotubes of NiFeV-layered double hydroxides@CoVP heterostructures towards efficient, pH-universal electrocatalytical nitrogen reduction reaction to ammonia

Muhammad Arif, Ghulam Yasin, Lan Luo, Wen Ye, Muhammad Asim Mushtaq, Xiaoyu Fang, Xu Xiang, Shengfu Ji and Dongpeng Yan

Applied Catalysis B: Environmental, 2020, 265, 118559
DOI: 10.1016/j.apcatb.2019.118559

Geometric and Electronic Effects Contributing to N2 Dissociation Barriers on a Range of Active Sites on Ru Nanoparticles

Caitlin A. Casey-Stevens, Stephanie G. Lambie, Charlie Ruffman, Egill Skúlason and Anna L. Garden

J. Phys. Chem. C, 2019, 123, 30458
DOI: 10.1021/acs.jpcc.9b09563

Density Functional Theory Study of Nitrogen Reduction to Ammonia on Bilayer Borophene

Fuyong Qin

Catalysts, 2025, 15, 603
DOI: 10.3390/catal15060603

Design of a High-Performance Electrocatalyst for N2 Conversion to NH3 by Trapping Single Metal Atoms on Stepped CeO2

Jiamin Qi, Liye Gao, Fenfei Wei, Qiang Wan and Sen Lin

ACS Appl. Mater. Interfaces, 2019, 11, 47525
DOI: 10.1021/acsami.9b15570

Identification and elimination of false positives in electrochemical nitrogen reduction studies

Jaecheol Choi, Bryan H. R. Suryanto, Dabin Wang, Hoang-Long Du, Rebecca Y. Hodgetts, Federico M. Ferrero Vallana, Douglas R. MacFarlane and Alexandr N. Simonov

Nat Commun, 2020, 11
DOI: 10.1038/s41467-020-19130-z

Ammonia Synthesis Using Single-Atom Catalysts Based on Two-Dimensional Organometallic Metal Phthalocyanine Monolayers under Ambient Conditions

Chun-Xiang Huang, Guoliang Li, Li-Ming Yang and Eric Ganz

ACS Appl. Mater. Interfaces, 2021, 13, 608
DOI: 10.1021/acsami.0c18472

Bioinspired Mo tape-porphyrin as an efficient and selective electrocatalyst for ammonia synthesis

Renyi Li, Zhen Feng, Yi Li, Xianqi Dai, Yaqiang Ma and Yanan Tang

Applied Surface Science, 2020, 520, 146202
DOI: 10.1016/j.apsusc.2020.146202

Engineering electrocatalyst for low-temperature N2 reduction to ammonia

Faisal Rehman, Md Delowar Hossain, Abhishek Tyagi, Dong Lu, Bin Yuan and Zhengtang Luo

Materials Today, 2021, 44, 136
DOI: 10.1016/j.mattod.2020.09.006

Electronic Structural Origin of the Catalytic Activity Trend of Transition Metals for Electrochemical Nitrogen Reduction

Byung Chul Yeo, Jimin Kong, Donghun Kim, William A. Goddard, Hyun S. Park and Sang Soo Han

J. Phys. Chem. C, 2019, 123, 31026
DOI: 10.1021/acs.jpcc.9b08729

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction

Hengcong Tao, Changhyeok Choi, Liang-Xin Ding, Zheng Jiang, Zishan Han, Mingwen Jia, Qun Fan, Yunnan Gao, Haihui Wang, Alex W. Robertson, Song Hong, Yousung Jung, Shizhen Liu and Zhenyu Sun

Chem, 2019, 5, 204
DOI: 10.1016/j.chempr.2018.10.007

On the role of metal cation in MXene in boosting the catalytic activity of single/double atom toward electrochemical NH3 production

Ho Chang Song and Hyung Chul Ham

Chemical Engineering Journal, 2023, 470, 144243
DOI: 10.1016/j.cej.2023.144243

Recent Advances in Electrochemical Synthesis of Ammonia through Nitrogen Reduction under Ambient Conditions

Jia Wang, Silong Chen, Zijian Li, Guangkai Li and Xien Liu

ChemElectroChem, 2020, 7, 1067
DOI: 10.1002/celc.201901967

Regulating the spin state of single-atom doped covalent triazine frameworks for efficient nitrogen fixation

Lei Fang, Gaozhang Gou, Jin Shang, Mingxian Liu, Qinfen Gu and Liangchun Li

Journal of Colloid and Interface Science, 2022, 627, 931
DOI: 10.1016/j.jcis.2022.07.090

Mechanistic Insights and Catalyst Exploration for Photothermal Catalytic Ammonia Synthesis

Zijing Zhang, Shuai Yin, Yuqiao Li, Jingran Mao, Suwei Wang, Hao Zhou, Guodong Deng, Wei Jiang and Guigao Liu

Langmuir, 2026, 42, 8251
DOI: 10.1021/acs.langmuir.5c06443

Development of Electrocatalysts for Efficient Nitrogen Reduction Reaction under Ambient Condition

Dong Liu, Mingpeng Chen, Xinyu Du, Haoqiang Ai, Kin Ho Lo, Shuangpeng Wang, Shi Chen, Guichuan Xing, Xuesen Wang and Hui Pan

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202008983

Recent Progress of Electrochemical Nitrate Reduction to Ammonia on Copper‐Based Catalysts: From Nanoparticles to Single Atoms

Zixun Yu, Mingyao Gu, Yangyang Wang, Hao Li, Yuan Chen and Li Wei

Adv Energy and Sustain Res, 2024, 5
DOI: 10.1002/aesr.202300284

Rational design of metal–organic framework-nanoparticle composite electrocatalysts for sustainable nitrogen electrochemistry

Sixiao Liu, Jun Lu, Xu Yu, Huan Pang, Qiang Zhang and Ho Seok Park

eScience, 2025, 5, 100378
DOI: 10.1016/j.esci.2025.100378

Mechanisms of electrochemical nitrogen gas reduction to ammonia under ambient conditions: a focused review

Anjali Kaiprathu, Parthiban Velayudham, Hanan Teller and Alex Schechter

J Solid State Electrochem, 2022, 26, 1897
DOI: 10.1007/s10008-022-05228-5

Protonic ceramic electrochemical cells: Opportunities and challenges for ammonia synthesis

Qinyi Hu, Chuan Tian, Di Bao, Haixia Zhong and Xinbo Zhang

Next Energy, 2024, 4, 100144
DOI: 10.1016/j.nxener.2024.100144

Ultrafine RuP2 nanoparticles supported on nitrogen-doped carbon based on coordination effect for efficient hydrogen evolution

Bao-Yu Guo, Xin-Yu Zhang, Jing-Yi Xie, Yuan-Hang Shan, Ruo-Yao Fan, Wen-Li Yu, Meng-Xuan Li, Da-Peng Liu, Yong-Ming Chai and Bin Dong

International Journal of Hydrogen Energy, 2021, 46, 7964
DOI: 10.1016/j.ijhydene.2020.12.021

Recent Advances and Challenges of Electrocatalytic N2Reduction to Ammonia

Geletu Qing, Reza Ghazfar, Shane T. Jackowski, Faezeh Habibzadeh, Mona Maleka Ashtiani, Chuan-Pin Chen, Milton R. Smith and Thomas W. Hamann

Chem. Rev., 2020, 120, 5437
DOI: 10.1021/acs.chemrev.9b00659

Ambient N2 Reduction to NH3 Electrocatalyzed by ZIF-67-Derived Nitrogen-Doped Porous Carbon Supported Co9S8 Nanomaterials

Huanhuan Zhang, Shuhao Yan, Wei Yi, Xiao Ma, Jing He, Yebo Lu, Lanhua Yi and Xingzhu Wang

ACS Sustainable Chem. Eng., 2024, 12, 2893
DOI: 10.1021/acssuschemeng.3c08087

Ambient Electrochemical Ammonia Synthesis with High Selectivity on Fe/Fe Oxide Catalyst

Lin Hu, Asim Khaniya, Jun Wang, Gang Chen, William E. Kaden and Xiaofeng Feng

ACS Catal., 2018, 8, 9312
DOI: 10.1021/acscatal.8b02585

Favorable Role of the Metal–Support Perimeter Region in Electrochemical NH3 Synthesis: A Density Functional Theory Study on Ru/BaCeO3

Atsushi Ishikawa, Fumiya Murase, Yoshitaka Tateyama and Junichiro Otomo

ACS Omega, 2022, 7, 26107
DOI: 10.1021/acsomega.2c01222

Theoretical study of ligand field modulation in TM@N2C2 single-atom catalysts for boosting electrocatalytic nitrogen reduction activity and selectivity

Shuxin Kuai and Jingyao Liu

Fuel, 2026, 406, 136929
DOI: 10.1016/j.fuel.2025.136929

Non-Monotonic Trends of Hydrogen Adsorption on Single Atom Doped g-C3N4

Hao Li, Zhien Zhang and Zhijian Liu

Catalysts, 2019, 9, 84
DOI: 10.3390/catal9010084

Electrochemical Synthesis of Ammonia via Nitrogen Reduction and Oxygen Evolution Reactions—A Comprehensive Review on Electrolyte-Supported Cells

Hizkia Manuel Vieri, Moo-Chang Kim, Arash Badakhsh and Sun Hee Choi

Energies, 2024, 17, 441
DOI: 10.3390/en17020441

Electrochemical Nitrogen Reduction Reaction on Ruthenium

Yao Yao, Haijiang Wang, Xiao-zi Yuan, Hui Li and Minhua Shao

ACS Energy Lett., 2019, 4, 1336
DOI: 10.1021/acsenergylett.9b00699

A General Two‐Step Strategy–Based High‐Throughput Screening of Single Atom Catalysts for Nitrogen Fixation

Chongyi Ling, Yixin Ouyang, Qiang Li, Xiaowan Bai, Xin Mao, Aijun Du and Jinlan Wang

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800376

Hierarchical Polymer Composites as Smart Reactor for Formulating Simple/Tandem-Commutative Catalytic Ability

Gang Luo, Yansong Lu, Shuping Wu, Xiaojuan Shen, Maiyong Zhu and Songjun Li

J Inorg Organomet Polym, 2020, 30, 4394
DOI: 10.1007/s10904-020-01583-w

Vanadium doped B 5 N 3 and B 7 N 5 monolayer as single atom catalyst for nitrogen reduction reaction – a first-principles study

Nandhini Panjulingam and Senthilkumar Lakshmipathi

Molecular Physics, 2024, 122
DOI: 10.1080/00268976.2023.2299232

Efficient electrocatalytic N2 fixation over BC3N2 monolayer: A computational screening of single-atom catalysts

Chaozheng He, Ye Shen, Long Lin, Kun Xie, Songshan Gao and Yaowei Liu

Molecular Catalysis, 2025, 577, 114931
DOI: 10.1016/j.mcat.2025.114931

Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances, challenges and perspectives

Xiaolan Xue, Renpeng Chen, Changzeng Yan, Peiyang Zhao, Yi Hu, Wenjun Zhang, Songyuan Yang and Zhong Jin

Nano Res., 2019, 12, 1229
DOI: 10.1007/s12274-018-2268-5

Facile synthesis of bimetallic N-doped carbon hybrid material for electrochemical nitrogen reduction

Linchuan Cong, Kaida Yao, Siqi Zhang, Ziqi Zhang, Zhuochen Yu, Miaomiao Qian, Lina Qu and Weimin Huang

Journal of Energy Chemistry, 2021, 59, 715
DOI: 10.1016/j.jechem.2020.12.012

Thermodynamic and Kinetic Insights into Hydrogen Adsorption and Dissociation on the Ru (0001) Surface under STM and Catalytic Conditions

Fabio Colasuonno and Martina Lessio

J. Phys. Chem. C, 2023, 127, 23645
DOI: 10.1021/acs.jpcc.3c05348

Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction

Xue Zhao, Guangzhi Hu, Gao‐Feng Chen, Haibo Zhang, Shusheng Zhang and Haihui Wang

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202007650

Efficient Electrocatalytic N2fixation Over Bc3n2monolayer: A Computational Screening of Single-Atom Catalysts

Chaozheng He, Kun Xie, Long Lin, Jinrong Huo, Chenxu Zhao and Lixin Li

SSRN Journal, 2022
DOI: 10.2139/ssrn.4066356

Progress in Single/Multi Atoms and 2D‐Nanomaterials for Electro/Photocatalytic Nitrogen Reduction: Experimental, Computational and Machine Leaning Developments

Aditya Narayan Singh, Rohit Anand, Mohammad Zafari, Miran Ha and Kwang S. Kim

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202304106

Transition metal single-atom supported on W2N3 as efficient electrocatalysts for the nitrogen reduction reaction: A DFT study

Huaping Xiong, Yue Meng, Shuirong Gu, Zufan Yang, Bo Xie, Zheming Ni and Shengjie Xia

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 698, 134583
DOI: 10.1016/j.colsurfa.2024.134583

Advancements in Electrocatalytic Nitrogen Reduction: A Comprehensive Review of Single‐Atom Catalysts for Sustainable Ammonia Synthesis

Xianhu Long, Fan Huang, Zhangnan Yao, Ping Li, Tao Zhong, Huinan Zhao, Shuanghong Tian, Dong Shu and Chun He

Small, 2024, 20
DOI: 10.1002/smll.202400551

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

Xiaoyang Cui, Cheng Tang and Qiang Zhang

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201800369

Bimodal nanoporous Pd3Cu1 alloy with restrained hydrogen evolution for stable and high yield electrochemical nitrogen reduction

Fangjie Pang, Zhifeng Wang, Kai Zhang, Jia He, Weiqing Zhang, Chunxian Guo and Yi Ding

Nano Energy, 2019, 58, 834
DOI: 10.1016/j.nanoen.2019.02.019

Revealing the Origin of Nitrogen Electroreduction Activity of Molybdenum Disulfide Supported Iron Atoms

Ke Xie, Feiteng Wang, Fenfei Wei, Jia Zhao and Sen Lin

J. Phys. Chem. C, 2022, 126, 5180
DOI: 10.1021/acs.jpcc.2c00632

Unsaturated p-Metal-Based Metal–Organic Frameworks for Selective Nitrogen Reduction under Ambient Conditions

Yang Fu, Kangkang Li, Munkhbayar Batmunkh, Hai Yu, Scott Donne, Baohua Jia and Tianyi Ma

ACS Appl. Mater. Interfaces, 2020, 12, 44830
DOI: 10.1021/acsami.0c13902

Heterogeneous metal trimer catalysts on Mo2TiC2O2 MXene for highly active N2 conversion to NH3

Pengfei Shu, Xiaosi Qi, Qiong Peng, Yanli Chen, Xiu Gong, Yue Zhang, Fangping Ouyang and Zhimei Sun

Molecular Catalysis, 2023, 539, 113036
DOI: 10.1016/j.mcat.2023.113036

Efficient and Stable Electrochemical Ammonia Synthesis Promoted by in Situ Alloying in Tubular Protonic Ceramic Electrolysis Cells

Xingzhi Zhu, Xiaoyun Miao, Chu Chen, Xiaofeng Ye, Yucun Zhou and Zhaoyin Wen

Advanced Energy Materials, 2026, 16
DOI: 10.1002/aenm.202504493

Energetics of Reaction Pathways Enabled by N and H Radicals during Catalytic, Plasma-Assisted NH3 Synthesis

Tsung-Wei Liu, Fnu Gorky, Maria L. Carreon and Diego A. Gómez-Gualdrón

ACS Sustainable Chem. Eng., 2022, 10, 2034
DOI: 10.1021/acssuschemeng.1c05660

Doping C60 with single or dual fe atoms for nitrogen reduction reaction: a DFT study

Zhi-Wen Ji, Xiao-Meng Huang, Xun-Lei Ding, Yan Chen, Wei Li, Jiao-Jiao Chen, Shao-Peng Xu and Lin-Lin Li

Phys. Scr., 2025, 100, 055949
DOI: 10.1088/1402-4896/adca6a

Hydrogen generation from NaBH4 hydrolysis using biomass-derived seed shell supported Co–La–B catalysts: A comparative study of sunflower, pumpkin and watermelon shell supports

Mehmet Salih Keskin

International Journal of Hydrogen Energy, 2026, 226, 154579
DOI: 10.1016/j.ijhydene.2026.154579

Advances in electrocatalytic ammonia synthesis under mild conditions

Guoyi Duan, Yongmei Chen, Yang Tang, Khaled A.M. Gasem, Pingyu Wan, Dong Ding and Maohong Fan

Progress in Energy and Combustion Science, 2020, 81, 100860
DOI: 10.1016/j.pecs.2020.100860

Single-Atom Catalysts on GaN Nanowires: A Computational Discovery for Efficient Electrochemical Nitrogen Fixation

Ling Ren, Zehui Fang, Guoning Feng, Yujie Sun, Xin Chen, Rongjian Sa, Qiaohong Li and Ma Zuju

Langmuir, 2025, 41, 26983
DOI: 10.1021/acs.langmuir.5c04015

h-MBenes (M/B = 1:1) as Promising Electrocatalysts for Nitrogen Reduction Reaction: A Theoretical Study

Shuang Feng, Yufang Yao, Jean-Christophe Charlier, Gian-Marco Rignanese and Junjie Wang

Chem. Mater., 2023, 35, 9019
DOI: 10.1021/acs.chemmater.3c01656

Layer structured materials for ambient nitrogen fixation

Yang Fu, Yuan Liao, Peng Li, Hui Li, Shuaiyu Jiang, Hongwei Huang, Wenping Sun, Tianyan Li, Hai Yu, Kangkang Li, Hao Li, Baohua Jia and Tianyi Ma

Coordination Chemistry Reviews, 2022, 460, 214468
DOI: 10.1016/j.ccr.2022.214468

p‐d Orbital Hybridization Engineered Single‐Atom Catalyst for Electrocatalytic Ammonia Synthesis

Jingkun Yu, Xue Yong and Siyu Lu

Energy & Environ Materials, 2024, 7
DOI: 10.1002/eem2.12587

Identification of Active Sites for Ammonia Electrosynthesis on Ruthenium

Lin Hu, Hemanth Somarajan Pillai, Corbin Feit, Kaige Shi, Zhengning Gao, Parag Banerjee, Hongliang Xin and Xiaofeng Feng

ACS Energy Lett., 2022, 7, 4290
DOI: 10.1021/acsenergylett.2c02175

Tuning the Catalytic Preference of Ruthenium Catalysts for Nitrogen Reduction by Atomic Dispersion

Bing Yu, Hao Li, Jai White, Scott Donne, Jiabao Yi, Shibo Xi, Yang Fu, Graeme Henkelman, Hai Yu, Zuliang Chen and Tianyi Ma

Adv Funct Materials, 2020, 30
DOI: 10.1002/adfm.201905665

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes

Shreya Mukherjee, David A. Cullen, Stavros Karakalos, Kexi Liu, Hao Zhang, Shuai Zhao, Hui Xu, Karren L. More, Guofeng Wang and Gang Wu

Nano Energy, 2018, 48, 217
DOI: 10.1016/j.nanoen.2018.03.059

Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis

Pengzuo Chen, Nan Zhang, Sibo Wang, Tianpei Zhou, Yun Tong, Chengcheng Ao, Wensheng Yan, Lidong Zhang, Wangsheng Chu, Changzheng Wu and Yi Xie

Proc. Natl. Acad. Sci. U.S.A., 2019, 116, 6635
DOI: 10.1073/pnas.1817881116

Screening of Transition Metal Single-Atom Catalysts Doped on Γ-Graphyne-Like BN Sheet for Efficient Nitrogen Reduction Reaction

Tongtong Li, Cheng He, Yibo Wu and Mengying Pei

SSRN Journal, 2021
DOI: 10.2139/ssrn.3989386

Hypes and hopes on the materials development strategies to produce ammonia at mild conditions

Swati Singh, Abdul Khayum Mohammed, Ali Abdulkareem AlHammadi, Dinesh Shetty and Kyriaki Polychronopoulou

International Journal of Hydrogen Energy, 2023, 48, 34700
DOI: 10.1016/j.ijhydene.2023.05.206

Computational insights into nitrogen reduction reaction catalyzed by transition metal doped graphene: Comparative investigations

Juan Xie, Huilong Dong, Xiaohua Cao and Youyong Li

Materials Chemistry and Physics, 2020, 243, 122622
DOI: 10.1016/j.matchemphys.2020.122622

Recent progress in electrocatalytic nitrogen reduction to ammonia (NRR)

Zanling Huang, Madiha Rafiq, Abebe Reda Woldu, Qing-Xiao Tong, Didier Astruc and Liangsheng Hu

Coordination Chemistry Reviews, 2023, 478, 214981
DOI: 10.1016/j.ccr.2022.214981

Electrochemical Synthesis of Ammonia from Nitrogen Under Mild Conditions: Current Status and Challenges

Yao Yao, Jing Wang, Usman Bin Shahid, Meng Gu, Haijiang Wang, Hui Li and Minhua Shao

Electrochem. Energ. Rev., 2020, 3, 239
DOI: 10.1007/s41918-019-00061-3

Impact of Vacancy Defects on Electrochemical Nitrogen Reduction Reaction Performance of MXenes

Hardik L. Kagdada and Ankit Jain

ChemPhysChem, 2024, 25
DOI: 10.1002/cphc.202300993

Account of eco‐friendly energy conversion reaction: Iron‐based nitrogen electrofixation

Liyuan Xu, Zheng Zhu, Jingjing Duan and Sheng Chen

Electron, 2024, 2
DOI: 10.1002/elt2.40

Ammonia Synthesis over Transition Metal Catalysts: Reaction Mechanisms, Rate-Determining Steps, and Challenges

Pradeep R. Varadwaj, Helder M. Marques and Ireneusz Grabowski

IJMS, 2025, 26, 4670
DOI: 10.3390/ijms26104670

General Design Concept for Single‐Atom Catalysts toward Heterogeneous Catalysis

Wenxin Guo, Zhiyuan Wang, Xiaoqian Wang and Yuen Wu

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202004287

Onsite ammonia synthesis from water vapor and nitrogen in the air

Xiaowei Song, Chanbasha Basheer, Jinheng Xu and Richard N. Zare

Sci. Adv., 2024, 10
DOI: 10.1126/sciadv.ads4443

Ruthenium/titanium oxide interface promoted electrochemical nitrogen reduction reaction

Weizheng Cai, Ya-Fei Jiang, Jincheng Zhang, Hongbin Yang, Junming Zhang, Cong-Qiao Xu, Wei Liu, Jun Li and Bin Liu

Chem Catalysis, 2022, 2, 1764
DOI: 10.1016/j.checat.2022.05.009

Homogeneous, Heterogeneous, and Biological Catalysts for Electrochemical N2 Reduction toward NH3 under Ambient Conditions

Huimin Liu, Li Wei, Fei Liu, Zengxia Pei, Jeffrey Shi, Zhou-jun Wang, Dehua He and Yuan Chen

ACS Catal., 2019, 9, 5245
DOI: 10.1021/acscatal.9b00994

Artificial N2 fixation to NH3 by electrocatalytic Ru NPs at low overpotential

Lei Zhao, Jie Zhao, Jinxiu Zhao, Lunwen Zhang, Dan Wu, Huan Wang, Jingwen Li, Xiang Ren and Qin Wei

Nanotechnology, 2020, 31, 29LT01
DOI: 10.1088/1361-6528/ab814e

Defect engineering for electrochemical nitrogen reduction reaction to ammonia

Chenhuai Yang, Yating Zhu, Jiaqi Liu, Yuchen Qin, Haiqing Wang, Huiling Liu, Yanan Chen, Zhicheng Zhang and Wenping Hu

Nano Energy, 2020, 77, 105126
DOI: 10.1016/j.nanoen.2020.105126

High-throughput identification of high activity and selectivity transition metal single-atom catalysts for nitrogen reduction

Zhe Xue, Xinyu Zhang, Jiaqian Qin and Riping Liu

Nano Energy, 2021, 80, 105527
DOI: 10.1016/j.nanoen.2020.105527

A Trilaminar-Thermosensitive Hydrogel Catalytic Reactor Capable of Single/Tandem Catalytic Switchable Ability

Lei Pu, Gang Luo, Maiyong Zhu, Xiaojuan Shen, Wenjing Wei and Songjun Li

J Inorg Organomet Polym, 2023, 33, 462
DOI: 10.1007/s10904-022-02513-8

Electrochemical ammonia synthesis through N2 and H2O under ambient conditions: Theory, practices, and challenges for catalysts and electrolytes

Hui Xu, Kemakorn Ithisuphalap, Yi Li, Shreya Mukherjee, Judith Lattimer, Grigorii Soloveichik and Gang Wu

Nano Energy, 2020, 69, 104469
DOI: 10.1016/j.nanoen.2020.104469

Heterogeneous N-heterocyclic carbenes supported single-atom catalysts for nitrogen fixation: A combined density functional theory and machine learning study

Jingchao Sun, Dian Zheng, Fei Deng, Sitong Liu, Yunhao Xie, Ying Liu, Jing Xu and Wei Liu

Applied Surface Science, 2024, 644, 158802
DOI: 10.1016/j.apsusc.2023.158802

Two-dimensional conductive covalent organic framework for efficient electrocatalytic nitrogen reduction reaction

Ning Zhang, Mei-Yan Wang and Jing-Yao Liu

Vacuum, 2023, 210, 111852
DOI: 10.1016/j.vacuum.2023.111852

Highly Efficient Ammonia Synthesis Electrocatalyst: Single Ru Atom on Naturally Nanoporous Carbon Materials

Yongyong Cao, Yijing Gao, Hu Zhou, Xianlang Chen, Hui Hu, Shengwei Deng, Xing Zhong, Guilin Zhuang and Jianguo Wang

Advcd Theory and Sims, 2018, 1
DOI: 10.1002/adts.201800018

Atomic-Scale Synergy of Dynamic Electric Fields and Ru Catalyst Architectures in Plasma-Catalyst NH3 Synthesis: A ReaxFF MD/DFT Mechanistic Study and Experiment

Xingyu Lu, Qi Chen, Jie Chen, Minghui Liang and Siyin Zhou

ACS Sustainable Chem. Eng., 2025, 13, 15016
DOI: 10.1021/acssuschemeng.5c05345

DFT study of Ru/graphene as high-performance electrocatalyst for NRR

Anmin Liu, Mengfan Gao, Yanchao Gao, Xuefeng Ren, Yanan Yang, Qiyue Yang, Yanqiang Li, Liguo Gao, Xingyou Liang and Tingli Ma

Inorganic Chemistry Communications, 2020, 120, 108169
DOI: 10.1016/j.inoche.2020.108169

Achieving High Activity and Selectivity of Nitrogen Reduction via Fe–N3 Coordination on Iron Single-Atom Electrocatalysts at Ambient Conditions

Haidong Yang, Yang Liu, Yutong Luo, Shiqing Lu, Bitao Su and Jiantai Ma

ACS Sustainable Chem. Eng., 2020, 8, 12809
DOI: 10.1021/acssuschemeng.0c02701

Current Progress of Electrocatalysts for Ammonia Synthesis Through Electrochemical Nitrogen Reduction Under Ambient Conditions

Anmin Liu, Yanan Yang, Xuefeng Ren, Qidong Zhao, Mengfan Gao, Weixin Guan, Fanning Meng, Liguo Gao, Qiyue Yang, Xingyou Liang and Tingli Ma

ChemSusChem, 2020, 13, 3766
DOI: 10.1002/cssc.202000487

Rational design of highly efficient electrocatalytic single-atom catalysts for nitrogen reduction on nitrogen-doped graphene and g-C2N supports

Shize Liu and Jing-yao Liu

Journal of Power Sources, 2022, 535, 231449
DOI: 10.1016/j.jpowsour.2022.231449