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Pd-Catalyzed Alkyne and Aryne Annulations: Synthesis and Photophysical Properties of π-Extended Coumarins

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Catalytic Oxidative C–H Annulation of Arylthiol Derivatives with 1,3-Diynes toward 3,3′-Bibenzothiophenes

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Rhodium(III)-Catalyzed C–H Functionalization of 1-(2H)-Phthalazinones at C8

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Rhodium(III)‐Catalyzed Thiolation of Azobenzenes

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Rhodium-Catalyzed Asymmetric (3 + 2 + 2) Annulation via N–H/C–H Dual Activation and Internal Alkyne Insertion toward N-Fused 5/7 Bicycles

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Propargylic Alcohols as Coupling Partners in Transition‐Metal‐Catalyzed Arene C−H Activation

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Enantioselective Twofold C−H Annulation of Formamides and Alkynes without Built‐in Chelating Groups

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Pd-Catalyzed Direct C–H Functionalization/Annulation of BODIPYs with Alkynes to Access Unsymmetrical Benzo[b]-Fused BODIPYs: Discovery of Lysosome-Targeted Turn-On Fluorescent Probes

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Rh(III)-catalyzed oxidative CH annulation of 3-arylisoquinolin-1-ones with diarylalkynes: Direct access to fused isoquinolinone frameworks

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Formal Lossen Rearrangement/Alkenylation or Annulation Cascade of Heterole Carboxamides with Alkynes Catalyzed by CpRhIII Complexes with Pendant Amides

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3d Transition Metals for C–H Activation

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Rh(III)-Catalyzed Oxidative C–H Activation/Domino Annulation of Anilines with 1,3-Diynes: A Rapid Access to Blue-Emitting Tricyclic N,O-Heteroaromatics

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Easy Access to Versatile Catalytic Systems for C−H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium(III) Complexes

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Chemistry A European J, 2021, 27, 10903
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Rhodium(III)‐Catalyzed Tandem [2+2+2] Annulation–Lactamization of Anilides with Two Alkynoates via Cleavage of Two Adjacent C−H or C−H/C−O bonds

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Ru(II)‐Catalyzed Aldehyde‐Directed Cascade Annulation of Aromatic Aldehydes With Acrylates to Access Indenes

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Formal Lossen Rearrangement/[3+2] Annulation Cascade Catalyzed by a Modified Cyclopentadienyl RhIII Complex

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Rhodium(III)‐Catalyzed Atroposelective Synthesis of Biaryls by C−H Activation and Intermolecular Coupling with Sterically Hindered Alkynes

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Ir(III)-Catalyzed Tandem Annulation of Aromatic Amides with 1,6-Diynes via Dual C–H Bond Activation

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Transition Metal‐Catalyzed C−H Activation/Annulation Approaches to Isoindolo[2,1‐b]isoquinolin‐5(7H)‐ones

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Three-Component Couplings among Heteroarenes, Difluorocyclopropenes, and Water via C–H Activation

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Construction of (Dihydro)naphtho[1,8-bc]pyrans via Rh(III)-Catalyzed Twofold C–H Activation of Benzoylacetonitriles

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Synthesis of Heteroaryl Triazenes via Rh(III)‐catalyzed Annulation Reactions with Alkynyl Triazenes

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Ni-Catalyzed Dual C–H Annulation of Benzimidazoles with Alkynes for Synthesis of π-Extended Heteroarenes

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Ligand‐Assisted Heteroaryl C(sp2)−H Bond Activation by a Cationic Ruthenium(II) Complex for Alkenylation of Heteroarenes with Alkynes Directed by Biorelevant Heterocycles

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C–H Bond Alkylation of Cyclic Amides with Maleimides via a Site-Selective-Determining Six-Membered Ruthenacycle

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Ligand-Enabled Ni–Al Bimetallic Catalysis for Nonchelated Dual C–H Annulation of Arylformamides and Alkynes

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Cascade C–H Annulation Reaction of Benzaldehydes, Anilines, and Alkynes toward Dibenzo[a,f]quinolizinium Salts: Discovery of Photostable Mitochondrial Trackers at the Nanomolar Level

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Recent Developments in Transition‐Metal‐Catalyzed Tandem CH Activation/Cyclization of α,ω‐Diynes

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Enantioselective Twofold C−H Annulation of Formamides and Alkynes without Built‐in Chelating Groups

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Aldehyde as a Traceless Directing Group for Regioselective C–H Alkylation Catalyzed by Rhodium(III) in Air

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Palladium‐Catalyzed Annulation of Aryltriazoles and Arylisoxazoles with Alkynes

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Synthesis of Benzoquinolizinium Salts by Rh(III)-Catalyzed Cascade Double N-Annulation Reactions of Allylamines, Diarylacetylenes, and HBF4

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Oxidative Annulation of Acetanilides with Alkynes Catalyzed by Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides

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Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores

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Rh/Cu‐Catalyzed Cascade [4+2] Vinylic C−H O‐Annulation and Ring Contraction of α‐Aryl Enones with Alkynes in Air

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Rhodium‐Catalyzed Cyclization of O,ω‐Unsaturated Alkoxyamines: Formation of Oxygen‐Containing Heterocycles

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Naphthalene-benzoindole derived two novel fluorometric pH-Responsive probes for environmental systems and bioimaging

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Rhodium(III)-Catalyzed Chemo-divergent Couplings of Sulfoxonium Ylides with Oxa/azabicyclic Olefins

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Synthesis of γ-Spirolactams via Rh(III)-Catalyzed C–H Activation/Directing Group Migration/Dearomatization/Spiroannulation of Indoles with 1,3-Enynes

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One-Pot Synthesis of Dihydrobenzo[a]fluorenes via Cascade C–H Annulation of Thiobenzamide with Alkynes

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Selective Synthesis of Isoquinolines by Rhodium(III)-Catalyzed C–H/N–H Functionalization with α-Substituted Ketones

Jie Li, Zhao Zhang, Mengyao Tang, Xiaolei Zhang and Jian Jin

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Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products

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Rhodium-Catalyzed Atroposelective Synthesis of Conformationally Stable C(sp2)–C(sp3) Atropisomers via C–H Activation and Annulation with 9-Fluorenylacetylene

Xiaomei Wang, Shunle Hu, Yue Shi, Genping Huang, Ruijie Mi and Xingwei Li

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Gold‐Catalyzed Synthesis of Spirocycles: Recent Advances

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Synthesis of 2‐Substituted Quinolines via Rhodium(III)‐Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

Xukai Zhou, Zisong Qi, Songjie Yu, Lingheng Kong, Yang Li, Wan‐Fa Tian and Xingwei Li

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Programmable zigzag π-extension toward graphene-like molecules by the stacking of naphthalene blocks

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Synthesis of Cinnolines and Cinnolinium Salt Derivatives by Rh(III)-Catalyzed Cascade Oxidative Coupling/Cyclization Reactions

Yanwei Wang, Bin Li and Baiquan Wang

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Transition Metals Catalyzed Direct C-H Chalcogenation of Arenes and Heteroarenes

Atanu Mahata, Madhusudan Garain, Totan Roy, Dilip Gorai and Debasish Kundu

COS, 2024, 21, 764
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Double ortho-C–H Activation/Annulation of Benzamides with Aryl Alkynes: A Route to Double-Helical Polycyclic Heteroaromatics

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Palladium-Catalyzed Synthesis of 2,3-Disubstituted Benzothiophenes via the Annulation of Aryl Sulfides with Alkynes

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Cobalt‐Catalyzed Enantio‐ and Regioselective C(sp3)−H Alkenylation of Thioamides

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Ru(II)-Catalyzed [3 + 3] Annulation of Benzamides with Iodonium Ylides via Redox-Neutral C–H Bond Functionalization

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Functionalized Cyclopentadienyl Ligands and Their Substituent Effects on a Rhodium(III)‐Catalyzed Oxidative [4+2] Annulation of Indole‐ and Pyrrole‐1‐Carboxamides with Alkynes

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Directed Cp*RhIII-Catalyzed Fluorosulfonylvinylation of Arenes

Gqwetha Ncube and Malcolm P. Huestis

Organometallics, 2019, 38, 76
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Red and Orange‐Light‐Accelerated Rhodium‐Catalyzed Oxidative Olefination of Arenes

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Chemistry A European J, 2025, 31
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Rhodium‐Catalyzed Dual C−H Activation for Regioselective Triple Annulation of Enaminones: Access to Polycyclic Naphthopyran Derivatives

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Rhodium-Catalyzed Direct Vinylene Annulation of 2-Aryloxazolines and Cascade Ring-Opening Using a Vinyl Selenone

Junya Kitano, Yuji Nishii, Koji Hirano and Masahiro Miura

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Sodium chlorate as a viable substoichiometric oxidant for cobalt-catalyzed oxidative annulation of aryl sulfonamides with alkynes

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Rhodium(III)‐Catalyzed Annulation of 2‐Arylimidazo[1,2‐a]pyridines with Maleimides: Synthesis of 1H‐Benzo[e]pyrido[1′,2′:1,2]imidazo[4,5‐g]isoindole‐1,3(2H)‐Diones and their Photophysical Studies

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Rhodium(III)‐Catalyzed Regioselective C−H Annulation and Alkenylation of 2‐Pyridones with Terminal Alkynes

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Pyridinium Salt Forming Rh(III)-Catalyzed Annulation Reaction of Secondary Allylamines with Internal Alkynes and Its Application to Surface Modification of a Mesoporous Material

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Rhodium-Catalyzed Relay Carbenoid Functionalization of Aromatic C–H Bonds toward Fused Heteroarenes

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Rhodiumkatalysierte sp2‐ und sp3‐C‐H‐Funktionalisierungen mit entfernbaren dirigierenden Gruppen

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Ni‐Catalyzed/mediated C−X (X=N, O, S) Bond Formation Chelation‐Assisted by Bidentate Directing Groups

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Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills

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Ni–Al Bimetal-Catalyzed Dual C–H Annulation of Formamides with Alkynes for Synthesis of Seven-Membered Lactams

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Palladium-Catalyzed Direct C(sp2)–H ortho-Arylation of Anilides Using 2-Aminophenylpyrazole as the Directing Group

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Diastereoselective and Reversed Regioselective Annulations of N-Alkyl Anilines to Julolidines and Lilolidines

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The application of chiral amide directing group in asymmetric C–H activation

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Arylative Cyclization of Indole‐1‐carboxamides with 1,6‐Enynes for the Synthesis of Polycyclic Indole Scaffolds

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Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration

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I2/TBHP Mediated C–N and C–H Bond Cleavage of Tertiary Amines toward Selective Synthesis of Sulfonamides and β-Arylsulfonyl Enamines: The Solvent Effect on Reaction

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Highly Efficient Catalytic Oxidation of Inert C(sp3)–H Bonds by the Synergistic Effect of Copper Nanoparticles/N‐Doped Graphene

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Substrate‐ and Catalyst‐Controlled C−H Bond Activation/Annulation for Construction of Pyrido[2,3,4‐de]quinazolinones and Indolo[1,2‐c]quinazolinones

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Rhodium(III)‐catalyzed Construction of D‐A Type Polyheteroaromatics with Fluorinated Benzothiadiazole as a Modifiable Acceptor Block

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Introducing the Chiral Transient Directing Group Strategy to Rhodium(III)‐Catalyzed Asymmetric C−H Activation

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Theoretical Exploration of Rh/Cu Cooperative Catalysis in C–H Allylation of Benzamide with 1,3-Diene

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One-Pot Preparation of 9,10-Dihydrophenanthrenes Initiated by Rhodium(III)-Catalyzed C–H Activation and Relay Diels–Alder Reaction

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Transition Metal‐Catalyzed Intermolecular Cascade C−H Activation/Annulation Processes for the Synthesis of Polycycles

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Metal–Organic Cooperative Catalysis in C–H and C–C Bond Activation

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One‐Pot Sequential N‐Heterocyclic Carbene/Rhodium(III) Catalysis: Synthesis of Fused Polycyclic Isocoumarins

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Tandem Rh-Catalyzed [4 + 2] Vinylic C–H O-Annulation of Exocyclic Enones with Alkynes and 1,5-H Shift

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Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O-Pivaloyl Oximes with Ketenes

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Rhodium‐Catalyzed ortho‐Olefination of Sterically Demanding Benzamides: Application to the Asymmetric Synthesis of Axially Chiral Benzamides

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Rhodium‐Catalyzed Synthesis of Isoquinolino[1,2‐b]Quinazolines via C−H Annulation in Biomass‐Derived γ‐Valerolactone

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Recent Advances in the Synthesis of 5‐Membered N‐Heterocycles via Rhodium Catalysed Cascade Reactions

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