Photocurable acylhydrazone covalent adaptable networks with fast dynamic exchange and tunable viscoelastic properties

Yunsheng Xu, Chonglin Liu, Yanying Zhao, Xianming Zhang and Minna Hakkarainen

Polym. Chem., 2024, 15, 2253
DOI: 10.1039/D4PY00230J

Designing dual-domain thermoplastic elastomers from ABA triblock copolymers: introducing bond-exchangeable subdomains into B-block strands

Mikihiro Hayashi and Tatsuya Mizuno

Polym. Chem., 2024, 15, 3854
DOI: 10.1039/D4PY00858H

pyRheo: an open-source Python package for complex rheology

Isaac Y. Miranda-Valdez, Aaro Niinistö, Tero Mäkinen, Juha Lejon, Juha Koivisto and Mikko J. Alava

Digital Discovery, 2025, 4, 1075
DOI: 10.1039/D5DD00021A

Thermoswitchable catalysis to inhibit and promote plastic flow in vitrimers

Filip Van Lijsebetten, Stephan Maes, Johan M. Winne and Filip E. Du Prez

Chem. Sci., 2024, 15, 7061
DOI: 10.1039/D4SC00417E

Bio-based recyclable polydithioacetal covalent adaptable networks with activation-temperature-tunable shape memory properties

Chenhui Cui, Xiejun Zhao, Xinyi Wang, Yinzhou Guo, Kexiang Chen, Jia Ma, Xueping Yan, Yilong Cheng, Zhishen Ge and Yanfeng Zhang

Polym. Chem., 2025, 16, 1595
DOI: 10.1039/D4PY01280A

Effects of crosslink density and plasticizer on thermorheological properties of dissociative guanidine-based covalent adaptable networks

Adelle L. Koenig, Kelsey M. Allis, John S. Lehr and Michael B. Larsen

Polym. Chem., 2025, 16, 52
DOI: 10.1039/D4PY01124D

Injectable biocompatible hydrogels with tunable strength based on crosslinked supramolecular polymer nanofibers

Hans F. Ulrich, Ceren C. Pihlamagi, Tobias Klein, Camille Bakkali-Hassani, Sylvain Catrouillet and Johannes C. Brendel

J. Mater. Chem. B, 2025, 13, 2003
DOI: 10.1039/D4TB01873G

Stoichiometric effects on bulk stress relaxation to enhance reprocessability in covalent adaptable networks

Jaehyun Cho, Santanu Ghosh, Mridula Nandi, Heejoon Jeon, Liang Yue, H. Jerry Qi, M. G. Finn and Blair Brettmann

Polym. Chem., 2025, 16, 1031
DOI: 10.1039/D5PY00013K

Debondable phenoxy-based structural adhesives with β-amino amide containing reversible crosslinkers

Francesca Portone, Loc Tan Nguyen, Roberta Pinalli, Alessandro Pedrini, Filip E. Du Prez and Enrico Dalcanale

RSC Appl. Polym., 2025, 3, 637
DOI: 10.1039/D4LP00369A

Poly(styrene-co-maleamic acid)-based monoamide covalent adaptable networks

Aitor Hernández, Susanne M. Fischer, Johan M. Winne and Filip E. Du Prez

J. Mater. Chem. A, 2025, 13, 24111
DOI: 10.1039/D5TA02035B

Impact of pre-crosslinks on the self-transformation performance of thermoplastic polyesters into vitrimers via intermolecular transesterification

Yuhka Shimizu and Mikihiro Hayashi

RSC Adv., 2025, 15, 524
DOI: 10.1039/D4RA08285K

Advances in cellulose-based hydrogels: tunable swelling dynamics and their versatile real-time applications

Md. Mahamudul Hasan Rumon

RSC Adv., 2025, 15, 11688
DOI: 10.1039/D5RA00521C

Impact of Cross-Link Density on Polybutadiene Permanent and Vitrimer Networks

Dana Ezzeddine, Daniel C. Barzycki and Ralm G. Ricarte

ACS Macro Lett., 2025, 14, 1011
DOI: 10.1021/acsmacrolett.5c00267

Linear Viscoelasticity of Polystyrene Vitrimers: Segmental Motions and the Slow Arrhenius Process

Daniel C. Barzycki, Dana Ezzeddine, Sachin Shanbhag and Ralm G. Ricarte

Macromolecules, 2025, 58, 3949
DOI: 10.1021/acs.macromol.4c03161

How to Characterize Covalent Adaptable Networks: A User Guide

Dimitri Berne, Sidonie Laviéville, Eric Leclerc, Sylvain Caillol, Vincent Ladmiral and Camille Bakkali-Hassani

ACS Polym. Au, 2025, 5, 214
DOI: 10.1021/acspolymersau.5c00004

Propylene–Ethylene Copolymer Covalent Adaptable Networks Synthesized by Resonance‐Stabilized, Radical‐Based Reactive Processing with Excellent Elevated‐Temperature Creep Resistance

Yen‐Wen Huang, Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan and John M. Torkelson

ChemSusChem, 2025
DOI: 10.1002/cssc.202501137

Mechanically Robust Polyvalerolactone Thermosets with Dual Recyclability

Hongyi Gu, Hao Ju, Kun Chen, Chang Sun, Lin Li, Jiayao Chen, Zhen Zhang and Peng-Fei Cao

Macromolecules, 2025
DOI: 10.1021/acs.macromol.5c00904

Molecularly Engineered Artificial Solid Electrolyte Interphase with Tailored Lithiophilicity and Solvent‐Phobicity for Stable Lithium Metal Batteries

Yeong Hun Jeong, Gwangbin Won, Seunghyeon Kim, Daun Jeong, Da‐Sol Kwon, Da Kyoung Yong, Jaehyuk Choi, Hyun Woo Ahn, Sulkyung Kim, Miso Lim and Jimin Shim

Small, 2025, 21
DOI: 10.1002/smll.202411861

Reprocessable, Lignin‐Derivable, Non‐Isocyanate Polyurethane Covalent Adaptable Networks With Complete Recovery of (Thermo)Mechanical Properties

Sampanna V. Mhatre, Thomas H. Epps, and LaShanda T. J. Korley

Macro Chemistry & Physics, 2025
DOI: 10.1002/macp.202500230

Fractional rheology as a tool for modeling viscoelasticity in cellulose-based hydrogels

Jesús G. Puente-Córdova, Flor Y. Rentería-Baltiérrez and Isaac Y. Miranda-Valdez

Cellulose, 2025, 32, 3619
DOI: 10.1007/s10570-025-06468-0

Ambient Dual Cross-Linked Interpenetrating Polymer Hydrogel Networks: Synthesis, Characterization, and Potential for Wearable Biosensing Devices

Ashwin Velraj, Audri Yasmin Dara, Abhishek Pachauri, Mia Marie Schmidt and Jeffrey Scott Bates

JOM, 2024, 76, 5654
DOI: 10.1007/s11837-024-06770-5

Highly Entangled Hydrogels by Photoiniferter‐Mediated Polymerization

Gavin Irvine, Konstantinos Myronidis, Fulvio Pinto and Maciej Kopeć

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202421970

Tailoring the Reprocessability of Thiol‐Ene Networks through Ring Size Effects

Vincent Scholiers, Susanne M. Fischer, Bram Daelman, Sandro Lehner, Sabyasachi Gaan, Johan M. Winne and Filip E. Du Prez

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420657

Food hydrogels: Experimental and theoretical aspects relating to their formulation and application

Jaekun Ryu and David Julian McClements

Trends in Food Science & Technology, 2025, 164, 105242
DOI: 10.1016/j.tifs.2025.105242

Tunable Waterborne Aspartic Acid-Based Covalent Adaptable Networks with Internal Catalysis and Incorporation in Bioinspired Nanocomposites

Sjoerd Engels and Andreas Walther

Macromolecules, 2024
DOI: 10.1021/acs.macromol.4c00666

The Multifaceted Role of Water as an Accelerator for the Preparation of Isocyanate-Free Polyurethane Thermosets

Florent Monie, Thomas Vidil, Etienne Grau, Bruno Grignard, Christophe Detrembleur and Henri Cramail

Macromolecules, 2024
DOI: 10.1021/acs.macromol.4c01672

How Does the Rate of Chain Exchange Relate to Stress Relaxation in Triblock Copolymer Networks?

Joanna M. White, Taehyoung Kim, Frank S. Bates and Timothy P. Lodge

ACS Cent. Sci., 2025, 11, 422
DOI: 10.1021/acscentsci.4c02031

Structure–property relationship and epoxy resin compatibility of poly(2‐alkyl/aryl‐2‐oxazoline)s, alongside rheological properties of their blends

Asu Ece Atespare, Taha Behroozi Kohlan, Saeed Salamatgharamaleki, Mehmet Yildiz, Yusuf Ziya Menceloglu, Serkan Unal and Bekir Dizman

Polymer Engineering & Sci, 2025, 65, 3193
DOI: 10.1002/pen.27208

Design and Continuous (Re)Processing of Thermally Resilient Poly(Styrene-co-Maleic Maleate)-Based Covalent Adaptable Networks

Aitor Hernández, Tim Maiheu, Eric Drockenmuller, Damien Montarnal, Johan M. Winne and Filip E. Du Prez

Chem. Mater., 2024, 36, 7487
DOI: 10.1021/acs.chemmater.4c01464

Recycling Polyurethane with Properties Maintained in Multiple Reprocessing Realized via Dynamic Polysulfide Bond

Xinyu Li, Bing Yu, Jing Bai, Baochun Guo, Ming Tian and Fei Chen

Macromolecules, 2025, 58, 6607
DOI: 10.1021/acs.macromol.5c00670

Structural Rheology in the Development and Study of Complex Polymer Materials

Sergey O. Ilyin

Polymers, 2024, 16, 2458
DOI: 10.3390/polym16172458

Rheological properties of C9 petroleum resin solutions

R.O. Subtelnyy, I.H. Balitskyi and B.O. Dzinyak

Vopr. Khim. Khim. Tekhnol., 2025, 17
DOI: 10.32434/0321-4095-2025-159-2-17-23

Covalent Adaptable Networks for Sustainable Soft Electronic Sensors and Actuators

Georgina E. K. K. Seah, Zhi Yuan Lee, Ai Wei Gan, Xin Jiang, Sirin Kamarulzaman, Jing Yu and Shermin S. Goh

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202421060

Does the nonuniqueness of the discrete relaxation spectrum really matter?

Sachin Shanbhag

Rheol Acta, 2025, 64, 107
DOI: 10.1007/s00397-025-01485-z

Microstructure and Viscoelasticity of Oppositely Charged Ionomer Blend Melts

Chia-Chi Tsai, Jie Xu, Cassie Duclos and Shuyi Xie

Macromolecules, 2025, 58, 1608
DOI: 10.1021/acs.macromol.4c02781

Rapidly Self‐Healable and Melt‐Extrudable Polyethylene Reprocessable Network Enabled with Dialkylamino Disulfide Dynamic Chemistry

Boran Chen, Tapas Debsharma, Logan M. Fenimore, Tong Wang, Yixuan Chen, Nathan S. Purwanto and John M. Torkelson

Macromol. Rapid Commun., 2024, 45
DOI: 10.1002/marc.202400460

Trifluoromethylated N,S-Acetal as a Chemical Platform for Covalent Adaptable Networks: Fast Thiol Exchange and Strong Hydrostability for a Highly Transparent Material

Sidonie Laviéville, Cédric Totée, Pascale Guiffrey, Sylvain Caillol, Camille Bakkali-Hassani, Vincent Ladmiral and Eric Leclerc

Macromolecules, 2024, 57, 10311
DOI: 10.1021/acs.macromol.4c01359

Tailoring the Reprocessability of Thiol‐Ene Networks through Ring Size Effects

Vincent Scholiers, Susanne M. Fischer, Bram Daelman, Sandro Lehner, Sabyasachi Gaan, Johan M. Winne and Filip E. Du Prez

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420657

Reactive Processing of Polyethylene with Azidotriazine: From Modified Thermoplastics to Injection Moldable Covalent Adaptable Networks

Huidi Sun, Thomas Vialon, Clément Guibert, Sandra Casale, Renaud Nicolaÿ and Nathan J. Van Zee

ACS Appl. Polym. Mater., 2025, 7, 2123
DOI: 10.1021/acsapm.4c04096

Viscoelastic Supramolecular Networks Based on Guanidinium‐Oxyanion Interactions

Oliver G. Venablerose, Evan B. Van Pelt, Ava L. DeKoekkoek and Michael B. Larsen

Journal of Polymer Science, 2025, 63, 2363
DOI: 10.1002/pol.20250048

Recyclable Cross-Linked Polyethylene from Self-Condensing Telechelic Polyethylene by Combining Olefin Metathesis, Hydrogenation, and Transesterification

Mara K. Kuenen and Marc A. Hillmyer

ACS Macro Lett., 2025, 14, 1068
DOI: 10.1021/acsmacrolett.5c00313

Dynamic crosslinking of thermoplastics via perfluorophenyl nitrene C–H insertion to form recyclable thermosets

Zhi Yuan Lee, Sirin Kamarulzaman, Rizqullah Rasyiddin, Sheila Y.X. Sim, Georgina E.K.K. Seah, Ai Wei Gan, Zibiao Li, Zhuang Mao Png and Shermin S. Goh

Chem, 2025, 11, 102479
DOI: 10.1016/j.chempr.2025.102479

A simulation-based comparative study on the reaction-controlled terminal relaxation of associative and dissociative CANs using a mesoscopic coarse-grained single-chain model

Tongfei Wu and Anning Cen

The Journal of Chemical Physics, 2025, 162
DOI: 10.1063/5.0256934

Understanding Non-isothermal Crystallization Behaviors of Polyethylene-Derived Vitrimers

Sara Valdez and Zhe Qiang

Macromolecules, 2025, 58, 9348
DOI: 10.1021/acs.macromol.5c01725

Assimilation of linear viscoelastic measurements by joint inference of relaxation spectrum

Sachin Shanbhag, Ralm G. Ricarte, Dana Ezzeddine and Daniel Barzycki

Journal of Rheology, 2025, 69, 1
DOI: 10.1122/8.0000869

Protorheology in practice: Avoiding misinterpretation

Mohammad Tanver Hossain, Ramdas Tiwari and Randy H. Ewoldt

Current Opinion in Colloid & Interface Science, 2024, 74, 101866
DOI: 10.1016/j.cocis.2024.101866

SBS polymer particle size impact on the characteristic time distribution of modified asphalt

Esteban Alberto González-García, Christopher Yusef Leon-Valdivieso and Rafael Herrera-Nájera

MRS Advances, 2024, 9, 1843
DOI: 10.1557/s43580-024-01001-0

Temperature-Dependent Fracture Toughness of Epoxy Vitrimers

Yuxiang Sun, Xudong Wang, Yi Zhao, Xi Chen, Qian Shi and Kun Jia

Macromolecules, 2025, 58, 942
DOI: 10.1021/acs.macromol.4c02212

Understanding the Topology Freezing Temperature of Vitrimer-Like Materials through Complementary Structural and Rheological Analyses for Phase-Separated Network

Mikihiro Hayashi, Maho Suzuki and Takumi Kito

ACS Macro Lett., 2025, 14, 182
DOI: 10.1021/acsmacrolett.4c00783

Nanoparticles reveal permanent and reversible changes to lymph node biomechanics during inflammatory response

Ann Ramirez, Vedanth Sriram, Yassmin Abbouchi, Reina Patolia, Emily Passaro, Michele Kaluzienski and Katharina Maisel

Biomaterials, 2026, 326, 123648
DOI: 10.1016/j.biomaterials.2025.123648

Pyridine Isomer Effects in the Framework of Phase‐Separated Vitrimer‐Like Materials Operated with Trans‐N‐Alkylation Bond Exchange of Quaternized Pyridines

Maho Suzuki and Mikihiro Hayashi

Macro Chemistry & Physics, 2025, 226
DOI: 10.1002/macp.202500037

Ion-Mediated Cross-Linking of Hyaluronic Acid into Hydrogels without Chemical Modification

Gayatri Prakash, Aaron J. Clasky, Kunal Gadani, Mohammad Nazeri and Frank X. Gu

Biomacromolecules, 2024, 25, 7723
DOI: 10.1021/acs.biomac.4c00985

Chain Motion and Energy Variation of Dynamic Cross-Linked Polymers

Xiaoxu Liu, Zilu Liu, Jing Bai and Fei Chen

Macromolecules, 2025, 58, 5842
DOI: 10.1021/acs.macromol.5c00132

Rheology and microstructure of graphene oxide reinforced xanthan gum suspensions

José Canazas Rodríguez, Nathália Moraes Fernandes, Lorena R. da C. Moraes, Lara S. Berghe, Hélio Ribeiro, Ricardo J. E. Andrade and Mônica F. Naccache

Journal of Rheology, 2025, 69, 475
DOI: 10.1122/8.0000963

Epoxy-Based Vitrimers for Sustainable Infrastructure: Emphasizing Recycling and Self-Healing Properties

Myung Kue Lee, Min Ook Kim, Taehwi Lee, Sanghwan Cho, Dongchan Kim, Wonghil Chang, Yongseok Kwon, Seongkwan Mark Lee, Ju Kwang Kim and Bong Cheol Son

Polymers, 2025, 17, 373
DOI: 10.3390/polym17030373

Liquid Metal‐Vitrimer Conductive Composite for Recyclable and Resilient Electronics

Dong Hae Ho, Meng Jiang, Ravi Tutika, Joshua C. Worch and Michael D. Bartlett

Advanced Materials, 2025
DOI: 10.1002/adma.202501341

Enabling the Reprocessability and Debonding of Epoxy Thermosets Using Dynamic Poly(β‐Amino Amide) Curing Agents

Loc Tan Nguyen, Stephan Maes and Filip E. Du Prez

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202419240

Gadolinium-Conjugated Lipoic Acid Hydrogels for Magnetic Resonance Imaging

Andrew R. Brotherton, Bennett Phillips-Sorich, Naedum DomNwachukwu, Matthew D. Bailey, Aarnav S. Patel, Claudio Luchinat, Giacomo Parigi and Thomas J. Meade

ACS Appl. Bio Mater., 2025, 8, 5903
DOI: 10.1021/acsabm.5c00584

Fully Recyclable and Remarkably Robust Cross-Linked Polyethylene Networks via Direct Free-Radical Copolymerization with Disulfide Dynamic Covalent Bonds

Logan M. Fenimore, Mathew J. Suazo, Sarah Mitchell, Hadi Mohammadi, Kimberly Miller McLoughlin, Cassandra Gallaschun, Patryk Sewruk, Markus Busch and John M. Torkelson

J. Am. Chem. Soc., 2025, 147, 27179
DOI: 10.1021/jacs.5c07720

Molecular Simulation of Covalent Adaptable Networks and Vitrimers: A Review

Argyrios V. Karatrantos, Olivier Couture, Channya Hesse and Daniel F. Schmidt

Polymers, 2024, 16, 1373
DOI: 10.3390/polym16101373

Extrudable and Highly Creep-Resistant Covalent Adaptable Networks Made from Polyethylene and Ethylene/1-Octene Copolymers by Reactive Processing with Aromatic Disulfide Cross-Links

Mathew J. Suazo, Logan M. Fenimore, Stephanie M. Barbon, Hayley Brown, Evelyn Auyeung, Gerardo Cespedes, Colin Li Pi Shan and John M. Torkelson

ACS Appl. Polym. Mater., 2024, 6, 14772
DOI: 10.1021/acsapm.4c02969

Highly Entangled Hydrogels by Photoiniferter‐Mediated Polymerization

Gavin Irvine, Konstantinos Myronidis, Fulvio Pinto and Maciej Kopeć

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202421970

Influence of Segmental Dynamics on Bond Exchange in Imine Vitrimers with Different Polymer Backbones and Cross-Linkers

Sirui Ge and Christopher M. Evans

Macromolecules, 2025, 58, 4043
DOI: 10.1021/acs.macromol.5c00067

Rheological Isotope Effects for Molecular Insight in Covalent Adaptable Networks

Christina M. Hemmingsen, Steven J. Chapman, Chuting Deng, Yao Xiong, Cooper J. Hanley, Vivian Zhang, Monica Olvera de la Cruz and Julia A. Kalow

Macromolecules, 2025, 58, 7957
DOI: 10.1021/acs.macromol.5c01258

Construction of dense polymer fluid networks via dual regulation of molecular weight and hydrophobic association

Di Yang, Xiaoqian Wei, Bo Yang, Xuehua Zhang and Hao Zhang

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2025, 727, 138210
DOI: 10.1016/j.colsurfa.2025.138210

Transparent Siloxane-Based Polyolefin Vitrimer and Its Use As an Encapsulant for Recyclable Photovoltaic Modules

Alexis Brastel, Margot Landa, Johannes Ast, Timea Béjat and Pierre Piluso

ACS Appl. Polym. Mater., 2025, 7, 10003
DOI: 10.1021/acsapm.5c01677

Linear viscoelasticity of physically aging soft glassy (Thixotropic) materials

Yogesh M. Joshi

Current Opinion in Colloid & Interface Science, 2025, 76, 101896
DOI: 10.1016/j.cocis.2025.101896

Impact-resistant, high-toughness, self-healable elastomers with physical-chemical dual-crosslinking networks for efficient energy absorption

Yi Yang, Ruixue Li, Chentong Gao, Ziwei Qin, Hao-Yang Mi, Binbin Dong, Xin Jing, Chuntai Liu and Changyu Shen

Applied Materials Today, 2024, 41, 102522
DOI: 10.1016/j.apmt.2024.102522