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Synthesis of C-acyl furanosides via the cross-coupling of glycosyl esters with carboxylic acids

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A protecting group–free approach for synthesizing C-glycosides through glycosyl dithiocarbamates

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A novel bis-phosphonyl C-glycoside: the first synthesis of C-(1,6-deoxy-β-d-glucopyranosyl)dimethylphosphonate, a stable bisphosphonate to probe the mechanism of β-phosphoglucomutase

Ramprasad Ghosh and David L. Jakeman

Org. Biomol. Chem., 2025, 23, 1129
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Preparing glycosyl benzothiazoles from 2-isocyanoaryl thioethers and glycosyl radicals under thermal conditions

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Generation and Use of Glycosyl Radicals under Acidic Conditions: Glycosyl Sulfinates as Precursors

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Angew Chem Int Ed, 2023, 62
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Modular assembly of complex C-alkyl glycoside enabled via cooperative NHC and photoredox catalysis

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Glycosyl Radical-Based Synthesis of C-Alkyl Glycosides Bearing a Cyclopropane via a Deoxygenative Giese Addition–Reduction–Cyclization Cascade

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β-Glycosyl Trifluoroborates as Precursors for Direct α-C-Glycosylation: Synthesis of 2-Deoxy-α-C-glycosides

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Org. Lett., 2021, 23, 1940
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Stereoselective Synthesis of C-Aryl-α-Glycosides by Reductive C(sp2)–C(sp3) Cross-Coupling Reaction

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1,2-trans-Stereoselective Synthesis of C-Glycosides of 2-Deoxy-2-amino-sugars Involving Glycosyl Radicals

Wen-Ze Shi, Hai Li, Gui-Cai Mu, Ji-Liang Lu, Yuan-Hong Tu and Xiang-Guo Hu

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Linkage-Editing of β-Glucosylceramide and β-Glucosylcholesterol: Development of β-Selective C-Glucosylation and Potent Mincle Ligands

Suzuka Chiba, Wakana Kusuhara, Eri Ishikawa, Makoto Yoritate, Taishi Miura, Kazushi Maeda, Haruto Takamura, Hiroaki Matoba, Sho Yamasaki and Go Hirai

J. Am. Chem. Soc., 2026, 148, 3316
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Recent development of stereoselective C-glycosylation via generation of glycosyl radical

Titli Ghosh and Toshiki Nokami

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Glycosyl-Radical-Based Synthesis of C-Alkyl Glycosides via Photomediated Defluorinative gem-Difluoroallylation

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Generation and Use of Glycosyl Radicals under Acidic Conditions: Glycosyl Sulfinates as Precursors

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Angewandte Chemie, 2023, 135
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Visible-Light-Mediated Synthesis of C-Alkyl Glycosides via Glycosyl Radical Addition and Aryl Migration

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Post‐Modification of Amino Acids and Peptides for the Rapid Synthesis of C‐Glycoamino Acids and C‐Glycopeptides

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Eur J Org Chem, 2022, 2022
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Diversification of Glycosyl Compounds via Glycosyl Radicals

Yi Jiang, Yijun Zhang, Boon Chong Lee and Ming Joo Koh

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Pseudo-Glycoconjugates: Synthesis and Biological Function of C-Glycoside Analogues of Glycoconjugates

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Catalytic Multicomponent Synthesis ofC‐Acyl Glycosides by Consecutive Cross‐Electrophile Couplings

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Angew Chem Int Ed, 2022, 61
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A Radical Activation Strategy for Versatile and Stereoselective N‐Glycosylation

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Angew Chem Int Ed, 2024, 63
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Diversification of Glycosyl Compounds via Glycosyl Radicals

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Linkage-Editing of Melibiosamine: Synthesis and Biological Evaluation of CH2- and CHF-Linked Analogs

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J. Org. Chem., 2024, 89, 11909
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Radicals and Carbohydrates: A Grand Alliance

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Convenient Synthesis of β‐C‐Acyl Glycosides and its Application in the Synthesis of Scleropentaside A, Scleropentaside B and the Derivatives of Dapagliflozin

Ya Fang, Wei Ma, Zhaobo Zhou, Xuanjia Wang, Xi Chen, Jiaxiang Wang and Xiaolei Wang

Chemistry A European J, 2025, 31
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Linkage-Editing Pseudo-Glycans: A Reductive α-Fluorovinyl-C-Glycosylation Strategy to Create Glycan Analogs with Altered Biological Activities

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J. Am. Chem. Soc., 2024, 146, 2237
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Radical C‐Glycosylation Using Photoexcitable Unprotected Glycosyl Borate

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Chemistry A European J, 2024, 30
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A Radical Activation Strategy for Versatile and Stereoselective N‐Glycosylation

Wenyan Ding, Xinyu Chen, Zuyao Sun, Jiaxin Luo, Shiping Wang, Qingqing Lu, Jialu Ma, Chongxin Zhao, Fen‐Er Chen and Chunfa Xu

Angewandte Chemie, 2024, 136
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Catalytic Multicomponent Synthesis ofC‐Acyl Glycosides by Consecutive Cross‐Electrophile Couplings

Yi Jiang, Kai Yang, Yi Wei, Quanquan Wang, Shi‐Jun Li, Yu Lan and Ming Joo Koh

Angewandte Chemie, 2022, 134
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Chemical Biology of αGalCer: A Chemist's Toolbox for the Stimulation of Invariant Natural Killer T (iNKT) Cells

Cecilia Romanò and Mads H. Clausen

Eur J Org Chem, 2022, 2022
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Synthesis of C-glycosides by Ti-catalyzed stereoselective glycosyl radical functionalization

Yi Jiang, Quanquan Wang, Xinglong Zhang and Ming Joo Koh

Chem, 2021, 7, 3377
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