Intersystem crossing of perylene bisimide neutral, radical anion, and dianion derivatives compared via ultrafast spectroelectrochemistry

Julia Heitmüller, Rebecca Fröhlich, Rebecca Renner, Frank Würthner and Tobias Brixner

Phys. Chem. Chem. Phys., 2023, 25, 17214
DOI: 10.1039/D2CP05602J

Electron diffraction tomography and X-ray powder diffraction on photoredox catalyst PDI

Alexander Bodach, Haishuang Zhao, Nai-Wei Liu, Edith Alig, Georg Manolikakes, Ute Kolb and Lothar Fink

CrystEngComm, 2019, 21, 2571
DOI: 10.1039/C8CE02026D

Molecular engineering based on four-arm perylene diimide chromophores toward hypoxia-induced specific photothermal therapy

Kecheng Huang, Xiangkun Cui, Miaomiao Zhen, Xueying Zhang, Fei Yang, Wei Wei and Yanqing Xu

J. Mater. Chem. B, 2025, 13, 12124
DOI: 10.1039/D5TB01583A

Designing a highly stable coordination-driven metallacycle for imaging-guided photodynamic cancer theranostics

Lizhen He, Li-Xuan Cai, Meng-Hua Li, Guang-Lu Zhang, Li-Peng Zhou, Tianfeng Chen, Mei-Jin Lin and Qing-Fu Sun

Chem. Sci., 2020, 11, 7940
DOI: 10.1039/D0SC02236E

Rescuing the solid-state fluorescence of perylene diimide dyes by host–guest isolation

Yanfeng He, Caihong Mao, Mingwan Duan, Linmeng Fan, Xiaohan Wang, Yan Cai, Min Du, Minli Hu, Ping Hu, Qiuyu Cheng and Xiaobo Hu

Org. Chem. Front., 2022, 9, 6466
DOI: 10.1039/D2QO01358D

Green hydrothermal synthesis yields perylenebisimide–SiO2 hybrid materials with solution-like fluorescence and photoredox activity

Hipassia M. Moura, Herwig Peterlik and Miriam M. Unterlass

J. Mater. Chem. A, 2022, 10, 12817
DOI: 10.1039/D1TA03214C

Merging of the photocatalyst decatungstate and naphthalene diimide in a hybrid structure for the oxidative coupling of amines

Zhengfen Liu, Xiaobo Li, Jian Chen, Chao Li, Fumang Luo, Fei-Xiang Cheng and Jian-Jun Liu

Dalton Trans., 2022, 51, 8472
DOI: 10.1039/D2DT01003H

Emerging perylene diimide-based photocatalysts: status and trends in organic synthesis

Tianyi Shang, Gonghong Qiu, Yunkui Li, Qiyan Lv, Yan Liu and Bing Yu

Chem. Commun., 2025, 61, 18208
DOI: 10.1039/D5CC05653E

Strong electron affinity PDI supramolecules form anion radicals for the degradation of organic pollutants via direct electrophilic attack

Xiaojuan Bai, Cong Wang, Xuyu Wang, Tianqi Jia, Boxuan Sun, Shengqi Yang, Di Li, Junqi Li and Haiyan Li

Catal. Sci. Technol., 2021, 11, 1899
DOI: 10.1039/D0CY01982H

Wavelength dependence and wavelength selectivity in photochemical reactions

Stefano Protti, Davide Ravelli and Maurizio Fagnoni

Photochem Photobiol Sci, 2019, 18, 2094
DOI: 10.1039/c8pp00512e

A persistent radical anion derived from a propeller-shaped perylene bisimide-carbazole pentad

Zhaolong Wang, Xinyu Gou, Gang Wang, Xingmao Chang, Ke Liu, Taihong Liu, Gang He and Yu Fang

Chem. Commun., 2022, 58, 7082
DOI: 10.1039/D2CC02042D

A coronene diimide based radical anion for detection of picomolar H2O2: a biochemical assay for detection of picomolar glucose in aqueous medium

Navdeep Kaur and Prabhpreet Singh

J. Mater. Chem. B, 2024, 12, 1043
DOI: 10.1039/D3TB02473C

Steering photoinduced multi-electron accumulation via high-concentration sacrificial electron donors

Rui Jing, Yuhang Yang, Junji Zhao, Yang Li, Di Song, Hongwei Song, Yan Wan, Andong Xia and Zhuoran Kuang

Chem. Commun., 2026, 62, 3378
DOI: 10.1039/D5CC06583F

Photoactive perylenediimide metal–organic framework for boosting iodoperfluoroalkylation of alkenes and oxidative coupling of amines

Zhengfen Liu, Chao Li, Jian Chen, Xiaobo Li, Fumang Luo, Feixiang Cheng and Jian-Jun Liu

Inorg. Chem. Front., 2022, 9, 111
DOI: 10.1039/D1QI01206A

Substituent-dependent absorption and fluorescence properties of perylene bisimide radical anions and dianions

Rebecca Renner, Matthias Stolte, Julia Heitmüller, Tobias Brixner, Christoph Lambert and Frank Würthner

Mater. Horiz., 2022, 9, 350
DOI: 10.1039/D1MH01019K

1,1′-Bi(2-naphthol-4,5-dicarboximide)s: blue emissive axially chiral scaffolds with aggregation-enhanced emission properties

Meng-Ting Chen, Yang Zhang, Myroslav O. Vysotsky, Joachim O. Lindner, Meng-Hua Li, Mei-Jin Lin and Frank Würthner

Org. Chem. Front., 2019, 6, 3731
DOI: 10.1039/C9QO01090D

Reactivity control of a photocatalytic system by changing the light intensity

Christoph Kerzig and Oliver S. Wenger

Chem. Sci., 2019, 10, 11023
DOI: 10.1039/C9SC04584H

Photo-substitution reactions of perylene red dyes

Johan Lub, Paul A. van Hal, Erica M.G. Custers, Hugo H. Knobel and Rifat A.M. Hikmet

Journal of Luminescence, 2020, 218, 116845
DOI: 10.1016/j.jlumin.2019.116845

Excitation of Radical Anions of Naphthalene Diimides in Consecutive‐ and Electro‐Photocatalysis**

Sofia Caby, Lydia M. Bouchet, Juan E. Argüello, Roberto A. Rossi and Javier I. Bardagi

ChemCatChem, 2021, 13, 3001
DOI: 10.1002/cctc.202100359

Photochromic Polyoxometalate/Perylenediimide Donor–Acceptor Hybrid Crystals with Interesting Luminescent Properties

Ming-Hua You, Meng-Hua Li, Yi-Ming Di, Shu-Quan Zhang and Mei-Jin Lin

Inorg. Chem., 2022, 61, 105
DOI: 10.1021/acs.inorgchem.1c02361

Photochemical Dehalogenation of Aryl Halides: Importance of Halogen Bonding

Ayda Elhage, Paolo Costa, Amrah Nasim, Anabel E. Lanterna and Juan C. Scaiano

J. Phys. Chem. A, 2019, 123, 10224
DOI: 10.1021/acs.jpca.9b06716

Photoinduced C–N Coupling of 6‐Aminouracil With Aryl Iodide: Aryl Iodide as a Source of Aryl Radical

Shikha Pandey, Divya Singh and Sundaram Singh

Asian J Org Chem, 2026, 15
DOI: 10.1002/ajoc.70373

Understanding the Light-Triggered Process of a Photo-Rechargeable Battery via Fluorescence Studies of Its Constitutional Photo- and Electroactive Components

Elsa Briqueleur, Mickael Dollé and W. G. Skene

J. Phys. Chem. C, 2022, 126, 2634
DOI: 10.1021/acs.jpcc.1c09127

Consecutive Charging of a Perylene Bisimide Dye by Multistep Low‐Energy Solar‐Light‐Induced Electron Transfer Towards H2 Evolution

Yucheng Xu, Jiaxin Zheng, Joachim O. Lindner, Xinbo Wen, Nianqiang Jiang, Zhicheng Hu, Linlin Liu, Fei Huang, Frank Würthner and Zengqi Xie

Angewandte Chemie, 2020, 132, 10449
DOI: 10.1002/ange.202001231

Continuous-Flow Photobromination/Debromination Cascade for Synthesis of the Trifloxystrobin Intermediate

Fujun Li, Peihao Cheng, Xinghai Li, Yun Zou and Shengyang Tao

Ind. Eng. Chem. Res., 2024, 63, 17734
DOI: 10.1021/acs.iecr.4c02202

Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations

Toshifumi Dohi, Elghareeb E. Elboray, Kotaro Kikushima, Koji Morimoto and Yasuyuki Kita

Chem. Rev., 2025, 125, 3440
DOI: 10.1021/acs.chemrev.4c00808

Dictating Packing and Interactions of Perylene Bisimides within Cyclophane Structures in the Solid State

Iris Solymosi, Christian Neiß, Harald Maid, Frank Hampel, Thomas Solymosi, Andreas Görling, Andreas Hirsch and M. Eugenia Pérez‐Ojeda

ChemistrySelect, 2023, 8
DOI: 10.1002/slct.202300523

Slow charge transfer from pentacene triplet states at the Marcus optimum

Natalie A. Pace, Nadezhda V. Korovina, Tyler T. Clikeman, Sarah Holliday, Devin B. Granger, Gerard M. Carroll, Sanjini U. Nanayakkara, John E. Anthony, Iain McCulloch, Steven H. Strauss, Olga V. Boltalina, Justin C. Johnson, Garry Rumbles and Obadiah G. Reid

Nat. Chem., 2020, 12, 63
DOI: 10.1038/s41557-019-0367-x

Asymmetric anionic [O⋯H⋯N]−1 -type strong H-bond constructed new near-infrared organic photothermal materials with high molar absorptivity and high amount of temperature rise

Yuanyuan Li, Longgang Wang, Mengming Sun, Jianping Zhang, Wenlong Hou, Lu Liu, Bo Liang, Hongliang Liu and Haiquan Zhang

Dyes and Pigments, 2022, 206, 110649
DOI: 10.1016/j.dyepig.2022.110649

Perylenediimide-Based Hybrid Materials for the Iodoperfluoroalkylation of Alkenes and Oxidative Coupling of Amines: Bay-Substituent-Mediated Photocatalytic Activity

Zhengfen Liu, Xiaobo Li, Wenxiu Yin, Jian Chen, Chao Li, Feixiang Cheng and Jian-Jun Liu

ACS Appl. Mater. Interfaces, 2022, 14, 53090
DOI: 10.1021/acsami.2c17197

Supramolecular Engineering and Self-Assembly Strategies in Photoredox Catalysis

Ayan Bhattacharyya, Suman De Sarkar and Anindita Das

ACS Catal., 2021, 11, 710
DOI: 10.1021/acscatal.0c04952

Tubular Perylene Bisimide Macrocycles for the Recognition of Geometrical Isomers of Azobenzenes

Tankut Türel, Samarth Bhargava and Suresh Valiyaveettil

J. Org. Chem., 2020, 85, 3092
DOI: 10.1021/acs.joc.9b02972

7, 8-Dichlorobenzo[ghi]perylenetriimide: A versatile synthon for bay-substituted π-extended perylene dyes

Lei Li, Jun-Yang Zhu, Yu-Jian Hong, Meng-Hua Li, Wang-Chuan Xiao and Mei-Jin Lin

Dyes and Pigments, 2019, 167, 83
DOI: 10.1016/j.dyepig.2019.04.019

Highly reductive photocatalytic systems in organic synthesis

Li-Li Liao, Lei Song, Si-Shun Yan, Jian-Heng Ye and Da-Gang Yu

Trends in Chemistry, 2022, 4, 512
DOI: 10.1016/j.trechm.2022.03.008

From structural stability to electronic flexibility: Unveiling strain-induced effects in a MoS2/perylene orange hybrid system

Mohammed El Amine Miloudi and Oliver Kühn

Phys. Rev. B, 2024, 110
DOI: 10.1103/PhysRevB.110.245307

1-Mono- and 1,7-Disubstituted Perylene Bisimide Dyes with Voluminous Groups at Bay Positions: In Search for Highly Effective Solid-State Fluorescence Materials

Matthias Stolte, Tim Schembri, Jasmin Süß, David Schmidt, Ana-Maria Krause, Myroslav O. Vysotsky and Frank Würthner

Chem. Mater., 2020, 32, 6222
DOI: 10.1021/acs.chemmater.0c02115

Control of triplet energy transfer driving forces between perylene diimide ligands and PbS quantum dots by size tuning

S. Hou, Y. Li, J. Yang, Y. Wang, H. Lin, S. Chen, J. Zhou, S. Zhuo, Y. Liu and Y. Wu

Materials Today Chemistry, 2023, 31, 101611
DOI: 10.1016/j.mtchem.2023.101611

Polyoxometalate‐dependent Photocatalytic Activity of Radical‐doped Perylenediimide‐based Hybrid Materials

Weijun Dai, Xiaobo Li, Chixian He, Xiang Li, Ci Kong, Feixiang Cheng and Jian‐Jun Liu

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303996

Ultrafast Dynamics of Photoinduced Electron Transfer in Bay-Aryl-Substituted Perylene Diimide Derivatives

Swati J. N. Dixit, Sajeev Chacko, Biswajit Manna and Neeraj Agarwal

J. Phys. Chem. B, 2022, 126, 5908
DOI: 10.1021/acs.jpcb.2c03952

Photoredox catalysis harvesting multiple photon or electrochemical energies

Mattia Lepori, Simon Schmid and Joshua P Barham

Beilstein J. Org. Chem., 2023, 19, 1055
DOI: 10.3762/bjoc.19.81

Reactor Technology Concepts for Flow Photochemistry

Thomas H. Rehm

ChemPhotoChem, 2020, 4, 235
DOI: 10.1002/cptc.201900247

Dynamic Self‐Assembly of Photo‐Reduced Perylene Diimide: Single‐Component White Light Emission from Organic Radicals

Oendrila Chatterjee, Rupam Roy, Anup Pramanik, Tanoy Dutta, Vikas Sharma, Pranab Sarkar and Apurba Lal Koner

Advanced Optical Materials, 2022, 10
DOI: 10.1002/adom.202201187

Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis

Han Li and Oliver S. Wenger

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202110491

Quantifying Förster Resonance Energy Transfer from Single Perovskite Quantum Dots to Organic Dyes

Leon G. Feld, Simon C. Boehme, Viktoriia Morad, Yesim Sahin, Christoph J. Kaul, Dmitry N. Dirin, Gabriele Rainò and Maksym V. Kovalenko

ACS Nano, 2024, 18, 9997
DOI: 10.1021/acsnano.3c11359

Synthesis and Isolation of a Stable Perylenediimide Radical Anion and Its Exceptionally Electron-Deficient Precursor

Yogendra Kumar, Sharvan Kumar, Deepak Bansal and Pritam Mukhopadhyay

Org. Lett., 2019, 21, 2185
DOI: 10.1021/acs.orglett.9b00490

Excited Organic Radicals in Photoredox Catalysis

Björn Pfund and Oliver S. Wenger

JACS Au, 2025, 5, 426
DOI: 10.1021/jacsau.4c00974

Unexpected Hydrated Electron Source for Preparative Visible-Light Driven Photoredox Catalysis

Christoph Kerzig, Xingwei Guo and Oliver S. Wenger

J. Am. Chem. Soc., 2019, 141, 2122
DOI: 10.1021/jacs.8b12223

Development of Novel Catalytic and Photocatalytic Reactions Toward the Production of Valuable Organic Molecules

Marco Manni and Giacomo Filippini

Synlett, 2025
DOI: 10.1055/a-2764-1035

New 1,4-divinylbenzene conjugated truxene dyes possessing D-π-D structure: Synthesis, linear photophysics and two-photon absorption

Yi Wang, Xiyuan Kang, Fangjian Cai, Lei Sun, Yinjie Yu, Claude P. Gros, Frédéric Bolze and Haijun Xu

Journal of Luminescence, 2022, 242, 118579
DOI: 10.1016/j.jlumin.2021.118579

Making Charge Recombination Spin-Forbidden for Efficient Generation and Excitation of Perylene Diimide Radical Anion by Pump–Pump–Probe Spectroscopy

Daniel H. Cruz Neto, Estefanía Sucre-Rosales and Eric Vauthey

J. Phys. Chem. Lett., 2025, 16, 13241
DOI: 10.1021/acs.jpclett.5c03240

Complete defluorination of PFASs via photocatalytic reduction in water

MeiChi Chong, Qixin Zhou, Jingyi Xu, Zhaohui Wu, Enwei Zhu, Wenlu Li, Ling Zhang, Yan Guo and Yongfa Zhu

Nat Commun, 2026, 17
DOI: 10.1038/s41467-026-69933-9

Flow Photochemistry as a Tool in Organic Synthesis

Thomas H. Rehm

Chemistry A European J, 2020, 26, 16952
DOI: 10.1002/chem.202000381

Consecutive Charging of a Perylene Bisimide Dye by Multistep Low‐Energy Solar‐Light‐Induced Electron Transfer Towards H2 Evolution

Yucheng Xu, Jiaxin Zheng, Joachim O. Lindner, Xinbo Wen, Nianqiang Jiang, Zhicheng Hu, Linlin Liu, Fei Huang, Frank Würthner and Zengqi Xie

Angew Chem Int Ed, 2020, 59, 10363
DOI: 10.1002/anie.202001231

Donor–Acceptor Hybrid Heterostructures: An Emerging Class of Photoactive Materials with Inorganic and Organic Semiconductive Components

Yi‐Ming Di, Jing‐Yan Liu, Meng‐Hua Li, Shu‐Quan Zhang, Ming‐Hua You and Mei‐Jin Lin

Small, 2022, 18
DOI: 10.1002/smll.202201159

p‐Benzoyl‐l‐phenylalanine as a Multifunctional Noncanonical Amino Acid in Synthetic Biology: Photoprobing, Photocatalysis, and Structural Programming for Biocontainment

Surendar R. Jakka and Govindasamy Mugesh

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202525502

Excited radical anions and excited anions in visible light photoredox catalysis

Indrajit Ghosh

Physical Sciences Reviews, 2019, 4
DOI: 10.1515/psr-2017-0185

Chemical doping of unsubstituted perylene diimide to create radical anions with enhanced stability and tunable photothermal conversion efficiency

Canyan Che, Shaohua Tong, Yanhua Jia, Jiaji Yang, Xiandong He, Shaobo Han, Qinglin Jiang and Yuguang Ma

Front. Chem., 2023, 11
DOI: 10.3389/fchem.2023.1187378

Electrosynthesis and characterizations of a multielectrochromic copolymer based on aniline and o‐nitroaniline in visible‐infrared region

Bo Zhang, Chen Xu, Guoyue Xu, Chuyang Liu, Jianchao Zhang, Tengchao Guo and Honghan Bu

J of Applied Polymer Sci, 2019, 136
DOI: 10.1002/app.47290

Incorporation of Core‐Twisted Perylene Bisimide Ligands into a Discrete Cp*Rh‐Based Molecular‐Rectangle via Coordination‐Driven Self‐Assembly

Le Zhang, Rajorshi Das and Ying‐Feng Han

Israel Journal of Chemistry, 2019, 59, 311
DOI: 10.1002/ijch.201900003

Naphthalene diimides with improved solubility for visible light photoredox catalysis

Barbara Reiß and Hans-Achim Wagenknecht

Beilstein J. Org. Chem., 2019, 15, 2043
DOI: 10.3762/bjoc.15.201

Organic Halogenation of Alkynes with Inorganic Halides Using Perylenediimide as Visible‐Light Photocatalyst

Pravat Nayek, Chidananda Biswal, Sandeepan Maity and Prasenjit Mal

Adv Synth Catal, 2026, 368
DOI: 10.1002/adsc.70245

Use of Perylene Diimides in Synthetic Photochemistry

Cristian Rosso, Giacomo Filippini and Maurizio Prato

Eur J Org Chem, 2021, 2021, 1193
DOI: 10.1002/ejoc.202001616

Dynamics of reduced perylene bisimide cyclophane redox species by ultrafast spectroelectrochemistry

Rebecca Fröhlich, Jessica Rühe, Michael Moos, Laura Kontschak, Patrik Ehrmann, Frank Würthner, Christoph Lambert and Tobias Brixner

The Journal of Chemical Physics, 2024, 160
DOI: 10.1063/5.0210490

Transition-Metal-Free and Visible-Light-Mediated Desulfonylation and Dehalogenation Reactions: Hantzsch Ester Anion as Electron and Hydrogen Atom Donor

Micaela D. Heredia, Walter D. Guerra, Silvia M. Barolo, Santiago J. Fornasier, Roberto A. Rossi and María E. Budén

J. Org. Chem., 2020, 85, 13481
DOI: 10.1021/acs.joc.0c01523

Unraveling the Interfacial Electron Transfer in Various Photocathode Architectures for Advancing a Photobattery

Elsa Briqueleur, Fatemeh Shoghi, Mickael Dollé and W. G. Skene

ACS Appl. Energy Mater., 2023, 6, 2768
DOI: 10.1021/acsaem.2c03577

Tailoring Dynamic Chiral Supramolecular Assembly with Phototriggered Radical Anions of C3-Symmetric Triphenylene Triimides

Namhee Kim, Jun Su Kang, Taesuk Jun, Jong-Min Suh, Deok-Ho Roh, Won-Woo Park, Oh-Hoon Kwon, Tae-Hyuk Kwon, Mi Hee Lim, Du Yeol Ryu, Myungeun Seo and Byeong-Su Kim

Macromolecules, 2024, 57, 21
DOI: 10.1021/acs.macromol.3c01189

The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle

Luca Capaldo and Davide Ravelli

Eur J Org Chem, 2020, 2020, 2783
DOI: 10.1002/ejoc.202000144

p‐Benzoyl‐l‐phenylalanine as a Multifunctional Noncanonical Amino Acid in Synthetic Biology: Photoprobing, Photocatalysis, and Structural Programming for Biocontainment

Surendar R. Jakka and Govindasamy Mugesh

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202525502

Silanediol-Bay-Bridge Rigidified Axially Chiral Perylene Bisimide

Oliver Nagler, Rajeev K. Dubey and Frank Würthner

J. Org. Chem., 2025, 90, 1006
DOI: 10.1021/acs.joc.4c02175

Review on application of perylene diimide (PDI)-based materials in environment: Pollutant detection and degradation

Wenwu Zhou, Guo Liu, Bing Yang, Qiuyi Ji, Weiming Xiang, Huan He, Zhe Xu, Chengdu Qi, Shiyin Li, Shaogui Yang and Chenmin Xu

Science of The Total Environment, 2021, 780, 146483
DOI: 10.1016/j.scitotenv.2021.146483

Persistent radical anions in panchromatic D-A hybrid heterostructures induced by anion-π interactions

Ming-Hua You, Yi-Ming Di, Meng-Hua Li, Hao-Hong Li and Mei-Jin Lin

Dyes and Pigments, 2020, 180, 108468
DOI: 10.1016/j.dyepig.2020.108468

Pyrazole and Triazole Fused Perylene Bisimides: Synthesis and Photophysical Properties

Wenshu Feng, Andrey A. Sukhanov, Xue Zhang, Greta Sambucari, Jianzhang Zhao, Lunxiang Yin, Violeta K. Voronkova and Mariangela Di Donato

Chemistry A European J, 2026
DOI: 10.1002/chem.70788

Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis

Han Li and Oliver S. Wenger

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202110491

Enhancing Electron Donor–Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal–Organic Framework

Xia Wu, Ming Cui, Kun Wu, Jun Guo, Tianyu Liu, Dongyi Liu, Zekun Li, Puxin Weng, Ri-Qin Xia, Xiao Xiong, Yong-Liang Huang, Dan Li and Jian He

J. Am. Chem. Soc., 2025, 147, 8350
DOI: 10.1021/jacs.4c16021