δ-Bonding modulates the electronic structure of formally divalent nd1 rare earth arene complexes

Ross E. MacKenzie, Tomáš Hajdu, John A. Seed, George F. S. Whitehead, Ralph W. Adams, Nicholas F. Chilton, David Collison, Eric J. L. McInnes and Conrad A. P. Goodwin

Chem. Sci., 2024, 15, 15160
DOI: 10.1039/D4SC03005B

The interpretation and prediction of lanthanide single-ion magnets fromab initioelectronic structure calculation: the capability and limit

Xiangxiang Wu, Jin-Feng Li and Bing Yin

Dalton Trans., 2022, 51, 14793
DOI: 10.1039/D2DT01507B

Isotopically enriched polymorphs of dysprosium single molecule magnets

Y. Kishi, F. Pointillart, B. Lefeuvre, F. Riobé, B. Le Guennic, S. Golhen, O. Cador, O. Maury, H. Fujiwara and L. Ouahab

Chem. Commun., 2017, 53, 3575
DOI: 10.1039/C7CC00317J

Construction of high-performance single-molecule magnets with a high-axiality coordination environment surrounding a lanthanide spin center based on macrocyclic ligands

Han Yan and Wen-Bin Sun

Dalton Trans., 2025, 54, 17007
DOI: 10.1039/D5DT01658D

Efficient enhancement of magnetic anisotropy by optimizing the ligand-field in a typically tetranuclear dysprosium cluster

Jiang Liu, Yan-Cong Chen, Zhong-Xia Jiang, Jun-Liang Liu, Jian-Hua Jia, Long-Fei Wang, Quan-Wen Li and Ming-Liang Tong

Dalton Trans., 2015, 44, 8150
DOI: 10.1039/C5DT00880H

Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy

Conrad A. P. Goodwin, Daniel Reta, Fabrizio Ortu, Jingjing Liu, Nicholas F. Chilton and David P. Mills

Chem. Commun., 2018, 54, 9182
DOI: 10.1039/C8CC05261A

Six-coordinated dinuclear lanthanide(iii) amide complexes: investigation of magnetization relaxation dynamics and their electronic structures

Amaleswari Rasamsetty, Sakshi Mehta, Kamal Uddin Ansari, Pardeep Kumar, Abhishake Mondal and Maheswaran Shanmugam

Dalton Trans., 2022, 51, 63
DOI: 10.1039/D1DT03708K

Coordination microenvironment perturbed single-ion magnet behavior in a β-diketone Dy(iii) complex

Peipei Cen, Meilin Wang, Xiufang Ma, Lei Chen, Yi-Quan Zhang, Yonghong Li, Danian Tian and Xiangyu Liu

CrystEngComm, 2020, 22, 6856
DOI: 10.1039/D0CE00935K

Three Dy(iii) single-ion magnets bearing the tropolone ligand: structure, magnetic properties and theoretical elucidation

Zilu Chen, Shui Yu, Rongdong Wang, Bo Li, Bing Yin, Dongcheng Liu, Yuning Liang, Di Yao and Fupei Liang

Dalton Trans., 2019, 48, 6627
DOI: 10.1039/C9DT00364A

Synthesis, characterization, magnetism and theoretical analysis of hetero-metallic [Ni2Ln2] partial di-cubane assemblies

Avik Bhanja, Radovan Herchel, Eufemio Moreno-Pineda, Anjan Khara, Wolfgang Wernsdorfer and Debashis Ray

Dalton Trans., 2021, 50, 12517
DOI: 10.1039/D1DT00510C

Construction of lanthanide single-molecule magnets with the “magnetic motif” [Dy(MQ)4]−

Deng-Ping Lyu, Jie-Yu Zheng, Quan-Wen Li, Jun-Liang Liu, Yan-Cong Chen, Jian-Hua Jia and Ming-Liang Tong

Inorg. Chem. Front., 2017, 4, 1776
DOI: 10.1039/C7QI00393E

Is a strong axial crystal-field the only essential condition for a large magnetic anisotropy barrier? The case of non-Kramers Ho(iii) versus Tb(iii )

Sandeep K. Gupta, Thayalan Rajeshkumar, Gopalan Rajaraman and Ramaswamy Murugavel

Dalton Trans., 2018, 47, 357
DOI: 10.1039/C7DT04020B

(thf)2Ln(Ge9{Si(SiMe3)3}3)2 (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides

Svetlana V. Klementyeva, Claudio Schrenk, Minghui Zhang, Marat M. Khusniyarov and Andreas Schnepf

Chem. Commun., 2021, 57, 4730
DOI: 10.1039/D1CC01151K

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

Jamie M. Frost, Katie L. M. Harriman and Muralee Murugesu

Chem. Sci., 2016, 7, 2470
DOI: 10.1039/C5SC03224E

High performance single-molecule magnets, Orbach or Raman relaxation suppression?

Alejandro Castro-Alvarez, Yolimar Gil, Leonel Llanos and Daniel Aravena

Inorg. Chem. Front., 2020, 7, 2478
DOI: 10.1039/D0QI00487A

Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry

Gautier Félix, Saad Sene, Alena Kulakova, Alexey N. Bilyachenko, Victor N. Khrustalev, Elena S. Shubina, Yannick Guari and Joulia Larionova

RSC Adv., 2023, 13, 26302
DOI: 10.1039/D3RA04901A

Single-molecule magnetism in {CoIII2DyIII2}-amine-polyalcohol-acetylacetonate complexes: effects of ligand replacement at the DyIII sites on the dynamics of magnetic relaxation

Stuart K. Langley, Nicholas F. Chilton, Boujemaa Moubaraki and Keith S. Murray

Inorg. Chem. Front., 2015, 2, 867
DOI: 10.1039/C5QI00076A

Key role of higher order symmetry and electrostatic ligand field design in the magnetic relaxation of low-coordinate Er(iii) complexes

Saurabh Kumar Singh, Bhawana Pandey, Gunasekaran Velmurugan and Gopalan Rajaraman

Dalton Trans., 2017, 46, 11913
DOI: 10.1039/C6DT03568J

Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy(CmRm)2] (where R = H, SiH3, CH3 and m = 4 to 9): a computational perspective

Ibtesham Tarannum, Shruti Moorthy and Saurabh Kumar Singh

Dalton Trans., 2023, 52, 15576
DOI: 10.1039/D3DT01646C

A stable dysprosium(iii) complex with a terminal fluoride ligand showing high resolution luminescence and slow magnetic relaxation

Bo-Kai Ling, Yuan-Qi Zhai, Junbo Han, Tian Han and Yan-Zhen Zheng

Dalton Trans., 2020, 49, 6969
DOI: 10.1039/D0DT01146K

Magnetic anisotropy in octahedral Dy(iii) and Yb(iii) complexes

Aditya Borah, Sourav Dey, Kehkasha Siddiqui, Sandeep K. Gupta, Gopalan Rajaraman and Ramaswamy Murugavel

Dalton Trans., 2024, 53, 7263
DOI: 10.1039/D3DT04352E

Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry

Octavia A. Blackburn, Robert M. Edkins, Stephen Faulkner, Alan M. Kenwright, David Parker, Nicola J. Rogers and Sergey Shuvaev

Dalton Trans., 2016, 45, 6782
DOI: 10.1039/C6DT00227G

Spin dynamics in single-molecule magnets and molecular qubits

Daniel Aravena and Eliseo Ruiz

Dalton Trans., 2020, 49, 9916
DOI: 10.1039/D0DT01414A

Phosphonate-assisted tetranuclear lanthanide assemblies: observation of the toroidic ground state in the TbIII analogue

Sourav Biswas, Pawan Kumar, Abinash Swain, Tulika Gupta, Pankaj Kalita, Subrata Kundu, Gopalan Rajaraman and Vadapalli Chandrasekhar

Dalton Trans., 2019, 48, 6421
DOI: 10.1039/C9DT00592G

The effect of the electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy(L)2(H2O)5]3+(L = phosphine oxide derivative) pentagonal bipyramidal SIMs

Ismael F. Díaz-Ortega, Juan Manuel Herrera, Sourav Dey, Hiroyuki Nojiri, Gopalan Rajaraman and Enrique Colacio

Inorg. Chem. Front., 2020, 7, 689
DOI: 10.1039/C9QI01412H

Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy(iii) complex

Pankaj Kalita, Naushad Ahmed, Shruti Moorthy, Virginie Béreau, Arun Kumar Bar, Pawan Kumar, Prakash Nayak, Jean-Pascal Sutter, Saurabh Kumar Singh and Vadapalli Chandrasekhar

Dalton Trans., 2023, 52, 2804
DOI: 10.1039/D2DT03789K

Modelling spin Hamiltonian parameters of molecular nanomagnets

Tulika Gupta and Gopalan Rajaraman

Chem. Commun., 2016, 52, 8972
DOI: 10.1039/C6CC01251E

Modulating the relaxation dynamics via structural transition from a dinuclear dysprosium cluster to a nonanuclear cluster

Peng Hu, Ling-hui Cao, Ao-gang Liu, Yi-quan Zhang, Tian-le Zhang and Bao Li

Dalton Trans., 2021, 50, 12814
DOI: 10.1039/D1DT02380B

In silico design criteria for high blocking barrier uranium (iii) SIMs

Sourav Dey and Gopalan Rajaraman

Chem. Commun., 2022, 58, 6817
DOI: 10.1039/D2CC01356H

Synthesis and magnetic studies of pentagonal bipyramidal metal complexes of Fe, Co and Ni

Yi-Fei Deng, Binling Yao, Peng-Zhi Zhan, Dexuan Gan, Yuan-Zhu Zhang and Kim R. Dunbar

Dalton Trans., 2019, 48, 3243
DOI: 10.1039/C8DT05074K

Room temperature memory device using single-molecule magnets

Hua Hao, XiaoHong Zheng, Ting Jia and Zhi Zeng

RSC Adv., 2015, 5, 54667
DOI: 10.1039/C5RA07774E

Single molecule magnet features in luminescent lanthanide coordination polymers with heptacoordinate Dy/Yb(iii) ions as nodes

Xiang-Tao Dong, Meng-Qing Yu, Yong-Bo Peng, Guo-Xing Zhou, Guo Peng and Xiao-Ming Ren

Dalton Trans., 2023, 52, 12686
DOI: 10.1039/D3DT02106H

Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands

Mikkel A. Sørensen, Høgni Weihe, Morten G. Vinum, Jesper S. Mortensen, Linda H. Doerrer and Jesper Bendix

Chem. Sci., 2017, 8, 3566
DOI: 10.1039/C7SC00135E

Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation

Thaige P. Gompa, Ningxin Jiang, John Bacsa and Henry S. La Pierre

Dalton Trans., 2019, 48, 16869
DOI: 10.1039/C9DT04230J

High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium(iii) metallocenium single-molecule magnets

K. Randall McClain, Colin A. Gould, Khetpakorn Chakarawet, Simon J. Teat, Thomas J. Groshens, Jeffrey R. Long and Benjamin G. Harvey

Chem. Sci., 2018, 9, 8492
DOI: 10.1039/C8SC03907K

An organolanthanide(iii) single-molecule magnet with an axial crystal-field: influence of the Raman process over the slow relaxation

Jérôme Long, Boris G. Shestakov, Dan Liu, Liviu F. Chibotaru, Yannick Guari, Anton V. Cherkasov, Georgy K. Fukin, Alexander A. Trifonov and Joulia Larionova

Chem. Commun., 2017, 53, 4706
DOI: 10.1039/C7CC02213A

A bis(silyldiamido) dysprosium single-molecule magnet

Tian Han and You-Song Ding

Inorg. Chem. Front., 2023, 10, 1803
DOI: 10.1039/D2QI02494B

Covalency in AnCl2 (An = Th–No)

Sophie Cooper and Nikolas Kaltsoyannis

Dalton Trans., 2022, 51, 5929
DOI: 10.1039/D2DT00315E

Lanthanide–radical single-molecule magnets: current status and future challenges

Hong-Dao Li, Si-Guo Wu and Ming-Liang Tong

Chem. Commun., 2023, 59, 6159
DOI: 10.1039/D2CC07042A

An eight-coordinate ytterbium complex with a hexagonal bipyramid geometry exhibiting field-induced single-ion magnet behaviour

Wen Zhao, Huihui Cui, Xiao-Yun Chen, Gangji Yi, Lei Chen, Aihua Yuan and Cheng-Lin Luo

Dalton Trans., 2019, 48, 5621
DOI: 10.1039/C9DT00663J

Pseudo-mono-axial ligand fields that support high energy barriers in triangular dodecahedral Dy(iii) single-ion magnets

Ben Zhang, Zhijie Cheng, Yingying Wu, Lei Chen, Rong Jing, Xingwei Cai, Chunhui Jiang, Yi-Quan Zhang, Aihua Yuan, Hui-Hui Cui and Zhao-Yang Li

Chem. Sci., 2022, 13, 13231
DOI: 10.1039/D2SC03182E

Salt metathesis routes to homoleptic near-linear Mg(ii) and Ca(ii) bulky bis(silyl)amide complexes

Ji-Dong Leng, Conrad A. P. Goodwin, Iñigo. J. Vitorica-Yrezabal and David P. Mills

Dalton Trans., 2018, 47, 12526
DOI: 10.1039/C8DT00802G

Cis–trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets

Jianfeng Wu, Julie Jung, Peng Zhang, Haixia Zhang, Jinkui Tang and Boris Le Guennic

Chem. Sci., 2016, 7, 3632
DOI: 10.1039/C5SC04510J

Lanthanoid single-ion magnets with the LnN10 coordination geometry

Zhong-Xia Jiang, Jun-Liang Liu, Yan-Cong Chen, Jiang Liu, Jian-Hua Jia and Ming-Liang Tong

Chem. Commun., 2016, 52, 6261
DOI: 10.1039/C6CC01695B

Unravelling the electronic structure, bonding, and magnetic properties of inorganic dysprosocene analogues [Dy(E4)2]− (E = N, P, As, CH)

Ibtesham Tarannum and Saurabh Kumar Singh

Phys. Chem. Chem. Phys., 2025, 27, 4109
DOI: 10.1039/D4CP03016H

Slow relaxation dynamics of a mononuclear Er(iii) complex surrounded by a ligand environment with anisotropic charge density

Kwang Soo Lim, Dong Won Kang, Jeong Hwa Song, Han Geul Lee, Mino Yang and Chang Seop Hong

Dalton Trans., 2017, 46, 739
DOI: 10.1039/C6DT04326G

Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

Lewis R. Thomas-Hargreaves, Marcus J. Giansiracusa, Matthew Gregson, Emanuele Zanda, Felix O'Donnell, Ashley J. Wooles, Nicholas F. Chilton and Stephen T. Liddle

Chem. Sci., 2021, 12, 3911
DOI: 10.1039/D1SC00238D

An air-stable Dy(iii) single-ion magnet with high anisotropy barrier and blocking temperature

Sandeep K. Gupta, Thayalan Rajeshkumar, Gopalan Rajaraman and Ramaswamy Murugavel

Chem. Sci., 2016, 7, 5181
DOI: 10.1039/C6SC00279J

Six-coordinate lanthanide complexes based on bidentate phosphine oxide ligands: synthesis, structure and magnetic properties

Xiao-Jun Wu, Hong-Yao Guo, Wei-Quan Lin, Yan Meng and Ji-Dong Leng

Dalton Trans., 2025, 54, 7819
DOI: 10.1039/D5DT00422E

Structures and magnetic properties of dysprosium complexes: the effect of crystallization temperature

Mei Guo, Yue Wang, Jianfeng Wu, Lang Zhao and Jinkui Tang

Dalton Trans., 2017, 46, 564
DOI: 10.1039/C6DT04268F

Improving f-element single molecule magnets

Stephen T. Liddle and Joris van Slageren

Chem. Soc. Rev., 2015, 44, 6655
DOI: 10.1039/C5CS00222B

Syntheses, structures and magnetic properties of a series of mono- and di-nuclear dysprosium(iii)-crown-ether complexes: effects of a weak ligand-field and flexible cyclic coordination modes

You-Song Ding, Tian Han, Yue-Qiao Hu, Minwei Xu, Sen Yang and Yan-Zhen Zheng

Inorg. Chem. Front., 2016, 3, 798
DOI: 10.1039/C5QI00308C

Diethyl ether adducts of trivalent lanthanide iodides

Thaige P. Gompa, Natalie T. Rice, Dominic R. Russo, Luis M. Aguirre Quintana, Brandon J. Yik, John Bacsa and Henry S. La Pierre

Dalton Trans., 2019, 48, 8030
DOI: 10.1039/C9DT00775J

s-Block metal complexes of superbulky (tBu3Si)2N−: a new weakly coordinating anion?

Christian Knüpfer, Lukas Klerner, Jonathan Mai, Jens Langer and Sjoerd Harder

Chem. Sci., 2024, 15, 4386
DOI: 10.1039/D3SC06896J

Relaxation dynamics in see-saw shaped Dy(iii) single-molecule magnets

Katie L. M. Harriman, Jesse Murillo, Elizaveta A. Suturina, Skye Fortier and Muralee Murugesu

Inorg. Chem. Front., 2020, 7, 4805
DOI: 10.1039/D0QI01007C

New field-induced single ion magnets based on prolate Er(iii) and Yb(iii) ions: tuning the energy barrierUeffby the choice of counterions within an N3-tridentate Schiff-base scaffold

Adam Gorczyński, Dawid Marcinkowski, Maciej Kubicki, Marta Löffler, Maria Korabik, Mirosław Karbowiak, Piotr Wiśniewski, Czesław Rudowicz and Violetta Patroniak

Inorg. Chem. Front., 2018, 5, 605
DOI: 10.1039/C7QI00727B

High local coordination symmetry around the spin center and the alignment between magnetic and symmetric axes together play a crucial role in single-molecule magnet performance

Zhao-Fu Yang, Yong-Mei Tian, Wan-Ying Zhang, Peng Chen, Hong-Feng Li, Yi-Quan Zhang and Wen-Bin Sun

Dalton Trans., 2019, 48, 4931
DOI: 10.1039/C9DT00058E

Enhancing luminescence properties of lanthanide(iii)/pyrimidine-4,6-dicarboxylato system by solvent-free approach

Javier Cepeda, Sonia Pérez-Yáñez, Garikoitz Beobide, Oscar Castillo, José Ángel García, Mónica Lanchas and Antonio Luque

Dalton Trans., 2015, 44, 6972
DOI: 10.1039/C4DT03797A

Enriching lanthanide single-ion magnetism through symmetry and axiality

Sandeep K. Gupta and Ramaswamy Murugavel

Chem. Commun., 2018, 54, 3685
DOI: 10.1039/C7CC09956H

A new breakthrough in low-coordinate Dy(iii) single-molecule magnets

Zhenhua Zhu, Xu Ying, Chen Zhao, Yi-Quan Zhang and Jinkui Tang

Inorg. Chem. Front., 2022, 9, 6061
DOI: 10.1039/D2QI01940J

Low-coordinate bis(imidazolin-2-iminato) dysprosium(iii) single-molecule magnets

Rong Sun, Chen Wang, Bing-Wu Wang, Zhe-Ming Wang, Yao-Feng Chen, Matthias Tamm and Song Gao

Inorg. Chem. Front., 2023, 10, 485
DOI: 10.1039/D2QI02180C

Blocking like it's hot: a synthetic chemists’ path to high-temperature lanthanide single molecule magnets

Conrad A. P. Goodwin

Dalton Trans., 2020, 49, 14320
DOI: 10.1039/D0DT01904F

A two-dimensional cobalt(ii) network with a remarkable positive axial anisotropy parameter exhibiting field-induced single-ion magnet behavior

Lin Sun, Sheng Zhang, Sanping Chen, Bing Yin, Yichen Sun, Zhenxing Wang, Zhongwen Ouyang, Jianlin Ren, Wenyuan Wang, Qing Wei, Gang Xie and Shengli Gao

J. Mater. Chem. C, 2016, 4, 7798
DOI: 10.1039/C6TC02234K

Synthesis, structure, and magnetic properties of diamagnetic Co(iii) ion-based heterometallic CoIII–LnIII (Ln = Dy, Tb, Ho, Er) complexes

Nandini Barman, Purbashree Halder, Subrata Mukhopadhyay, Björn Schwarz, Enrique Colacio, Rajanikanta Rana, Gopalan Rajaraman and Joydeb Goura

New J. Chem., 2024, 48, 15735
DOI: 10.1039/D4NJ02058H

Quantum tunnelling of the magnetisation in single-molecule magnet isotopologue dimers

Eufemio Moreno-Pineda, Gheorghe Taran, Wolfgang Wernsdorfer and Mario Ruben

Chem. Sci., 2019, 10, 5138
DOI: 10.1039/C9SC01062A

Record high magnetic exchange and magnetization blockade in Ln2@C79N (Ln = Gd(iii) and Dy(iii)) molecules: a theoretical perspective

Mukesh Kumar Singh, Neeraj Yadav and Gopalan Rajaraman

Chem. Commun., 2015, 51, 17732
DOI: 10.1039/C5CC06642E

Spin-state energetics and magnetic anisotropy in penta-coordinated Fe(iii) complexes with different axial and equatorial ligand environments

Shalini Joshi, Sabyasachi Roy Chowdhury and Sabyashachi Mishra

Phys. Chem. Chem. Phys., 2023, 25, 17680
DOI: 10.1039/D3CP02182C

Five Co(ii) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl)benzoato]− ligand: directed synthesis, structures and magnetic properties

Wen-Hong Jiang, Han-Zhong Zhang, Guang-Feng Hou, Dong-Sheng Ma, Bin Liu and Ying-Hui Yu

RSC Adv., 2017, 7, 45641
DOI: 10.1039/C7RA07089F

A fluorobenzene-bound dysprosium half-sandwich dication single-molecule magnet

Sophie C. Corner, William J. A. Blackmore, Gemma K. Gransbury, Andrea Mattioni, George F. S. Whitehead, Nicholas F. Chilton and David P. Mills

Chem. Sci., 2025, 16, 610
DOI: 10.1039/D4SC06661H

Synthesis, structures and magnetic properties of four dysprosium-based complexes with a multidentate ligand with steric constraint

Wen-Qiang Li, Meng-Xia Ma, Qing-Ling Ni, Shi-Ming Li, Liu-Cheng Gui and Xiu-Jian Wang

CrystEngComm, 2023, 25, 614
DOI: 10.1039/D2CE01201D

Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation

Sophie C. Corner, Gemma K. Gransbury and David P. Mills

Dalton Trans., 2025, 54, 198
DOI: 10.1039/D4DT02713B

Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets

Katie L. M. Harriman, Jennifer J. Le Roy, Liviu Ungur, Rebecca J. Holmberg, Ilia Korobkov and Muralee Murugesu

Chem. Sci., 2017, 8, 231
DOI: 10.1039/C6SC01224H

Equatorial coordination optimization for enhanced axiality of mononuclear Dy(iii) single-molecule magnets

Ke-Xin Yu, You-Song Ding, Yuan-Qi Zhai, Tian Han and Yan-Zhen Zheng

Dalton Trans., 2020, 49, 3222
DOI: 10.1039/D0DT00011F

Magnetic anisotropy in YbIII complex candidates for molecular qubits: a theoretical analysis

Martín Amoza, Silvia Gómez-Coca and Eliseo Ruiz

Phys. Chem. Chem. Phys., 2021, 23, 1976
DOI: 10.1039/D0CP05422D

Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes

Conrad A. P. Goodwin, Alex Smith, Fabrizio Ortu, Iñigo. J. Vitorica-Yrezabal and David P. Mills

Dalton Trans., 2016, 45, 6004
DOI: 10.1039/C5DT02535D

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L3-edge X-ray absorption spectroscopy

Conrad A. P. Goodwin, Benjamin L. L. Réant, Jon G. C. Kragskow, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills and Stephen Sproules

Dalton Trans., 2018, 47, 10613
DOI: 10.1039/C8DT01452C

Ab initioprediction of key parameters and magneto-structural correlation of tetracoordinated lanthanide single-ion magnets

Qi-Qi Yang, Yu-Fei Wang, Yu-Xi Wang, Ming-Jing Tang and Bing Yin

Phys. Chem. Chem. Phys., 2023, 25, 18387
DOI: 10.1039/D3CP01766D

Determining the zero-field cooling/field cooling blocking temperature from AC susceptibility data for single-molecule magnets

Yolimar Gil, María Mar Quesada-Moreno, María A. Palacios, Silvia Gómez-Coca, Enrique Colacio, Eliseo Ruiz and Daniel Aravena

Inorg. Chem. Front., 2025, 12, 2856
DOI: 10.1039/D4QI03259D

Electronic structures of bent lanthanide(III) complexes with two N-donor ligands

Hannah M. Nicholas, Michele Vonci, Conrad A. P. Goodwin, Song Wei Loo, Siobhan R. Murphy, Daniel Cassim, Richard E. P. Winpenny, Eric J. L. McInnes, Nicholas F. Chilton and David P. Mills

Chem. Sci., 2019, 10, 10493
DOI: 10.1039/C9SC03431E

Investigation of magneto-structural correlation based on a series of seven-coordinated β-diketone Dy(iii) single-ion magnets with C2v and C3v local symmetry

Xu Yao, Pengfei Yan, Guanghui An, Yuxin Li, Weizuo Li and Guangming Li

Dalton Trans., 2018, 47, 3976
DOI: 10.1039/C7DT04764A

Magnetic relaxations in four-coordinate Dy(iii) complexes: effects of anionic surroundings and short Dy–O bonds

Ke-Xin Yu, You-Song Ding, Tian Han, Ji-Dong Leng and Yan-Zhen Zheng

Inorg. Chem. Front., 2016, 3, 1028
DOI: 10.1039/C6QI00117C

The coexistence of longτQTMand highUeffas a concise criterion for a good single-molecule magnet: a theoretical case study of square antiprism dysprosium single-ion magnets

Hong Liu, Jin-Feng Li and Bing Yin

Phys. Chem. Chem. Phys., 2022, 24, 11729
DOI: 10.1039/D2CP00776B

Redox transmetallation approaches to the synthesis of extremely bulky amido-lanthanoid(ii) and -calcium(ii) complexes

Caspar N. de Bruin-Dickason, Aaron J. Boutland, Deepak Dange, Glen B. Deacon and Cameron Jones

Dalton Trans., 2018, 47, 9512
DOI: 10.1039/C8DT02138D

Isomeric ligands enhance the anisotropy barrier within nine-coordinated {Dy2} compounds

Lin Sun, Shilong Wei, Jun Zhang, Wenyuan Wang, Sanping Chen, Yiquan Zhang, Qing Wei, Gang Xie and Shengli Gao

J. Mater. Chem. C, 2017, 5, 9488
DOI: 10.1039/C7TC02786A

Modulating the slow magnetic relaxation of a mononuclear Dy(iii) single-molecule magnet via a magnetic field and dilution effects

Peipei Cen, Zixin He, Runmei Ding, Huifang Yang, Li Li, Yi-Quan Zhang, Yonghong Li, Danian Tian and Xiangyu Liu

CrystEngComm, 2021, 23, 5443
DOI: 10.1039/D1CE00682G

Constraining the coordination geometries of lanthanide centers and magnetic building blocks in frameworks: a new strategy for molecular nanomagnets

Ke Liu, Xuejing Zhang, Xixi Meng, Wei Shi, Peng Cheng and Annie K. Powell

Chem. Soc. Rev., 2016, 45, 2423
DOI: 10.1039/C5CS00770D

A monometallic lanthanide bis(methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour

Matthew Gregson, Nicholas F. Chilton, Ana-Maria Ariciu, Floriana Tuna, Iain F. Crowe, William Lewis, Alexander J. Blake, David Collison, Eric J. L. McInnes, Richard E. P. Winpenny and Stephen T. Liddle

Chem. Sci., 2016, 7, 155
DOI: 10.1039/C5SC03111G

Reversible temperature-induced polymorphic phase transitions of [Y(OAr)3] and [Ce(OAr)3] (Ar = 2,6-tBu2-4-MeC6H2): interconversions between pyramidal and planar geometries

Mairi F. Haddow, Robert J. Newland, Bengt E. Tegner and Stephen M. Mansell

CrystEngComm, 2019, 21, 2884
DOI: 10.1039/C9CE00184K

Interchange between coordinated and lattice solvents generates the highest energy barrier within nine-coordinated DyIII single molecule magnets

Lin Sun, Sheng Zhang, Zhijie Jiang, Qi Yang, Sanping Chen, Yiquan Zhang, Wenyuan Wang, Qing Wei and Gang Xie

Dalton Trans., 2017, 46, 11159
DOI: 10.1039/C7DT02382K

A new air- and moisture-stable pentagonal-bipyramidal DyIII single-ion magnet based on the HMPA ligand

Lei-Lei Li, Hong-Dan Su, Shuang Liu, Ya-Chao Xu and Wen-Zhen Wang

Dalton Trans., 2019, 48, 2213
DOI: 10.1039/C8DT03565B

Advancements in mononuclear dysprosium-based single-molecule magnets via synthetic and molecular engineering

Jarrod R. Thomas and Scott A. Sulway

CrystEngComm, 2025, 27, 4055
DOI: 10.1039/D5CE00181A

Luminescent Er3+ based single molecule magnets with fluorinated alkoxide or aryloxide ligands

Alexander N. Selikhov, Gautier Félix, Dmitry M. Lyubov, Yulia V. Nelyubina, Anton V. Cherkasov, Saad Sene, Ilya V. Taydakov, Mikhail T. Metlin, Andrey A. Tyutyunov, Yannick Guari, Joulia Larionova and Alexander A. Trifonov

Dalton Trans., 2024, 53, 6352
DOI: 10.1039/D3DT04375D

Experimental and theoretical interpretation of the magnetic behavior of two Dy(iii) single-ion magnets constructed through β-diketonate ligands with different substituent groups (–Cl/–OCH3)

Sheng Zhang, Wenjiao Mo, Jiangwei Zhang, Haipeng Wu, Min Li, Xingqiang Lü, Bing Yin and Desuo Yang

RSC Adv., 2018, 8, 29513
DOI: 10.1039/C8RA06240D

Construction and theoretical study of a new Dy-β-diketone chain featuring slow magnetic relaxation

Yan-Chun Hui, Yin-Shan Meng, Zongsheng Li, Qi Chen, Hao-Ling Sun, Yi-Quan Zhang and Song Gao

CrystEngComm, 2015, 17, 5620
DOI: 10.1039/C5CE00971E

4f-Orbital mixing increases the magnetic susceptibility of Cp′3Eu

S. Olivia Gunther, Yusen Qiao, Patrick W. Smith, Sierra R. Ciccone, Alexander S. Ditter, Daniel N. Huh, Liane M. Moreau, David K. Shuh, Taoxiang Sun, Polly L. Arnold, Corwin H. Booth, Wibe A. de Jong, William J. Evans, Wayne W. Lukens and Stefan G. Minasian

Chem. Sci., 2024, 15, 12667
DOI: 10.1039/D4SC01300J

Research Progresses of Lanthanide Single-Ion Magnets

玲黄

JAPC, 2022, 11, 196
DOI: 10.12677/JAPC.2022.114022

Switching of Slow Magnetic Relaxation Dynamics in Mononuclear Dysprosium(III) Compounds with Charge Density

Kwang Soo Lim, José J. Baldoví, Woo Ram Lee, Jeong Hwa Song, Sung Won Yoon, Byoung Jin Suh, Eugenio Coronado, Alejandro Gaita-Ariño and Chang Seop Hong

Inorg. Chem., 2016, 55, 5398
DOI: 10.1021/acs.inorgchem.6b00410

Luminescence and Single‐Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near‐Planar Tricoordinate Ytterbium(III) Amide

Nimisha Jain, Félix Houard, Rémi Marchal, Marie Cordier, Boris Le Guennic, Yan Suffren, Yann Sarazin and Kevin Bernot

ChemistryEurope, 2024, 2
DOI: 10.1002/ceur.202400062

Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

Veacheslav Vieru, Silvia Gómez‐Coca, Eliseo Ruiz and Liviu F. Chibotaru

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202303146

Large Magnetic Anisotropy in Linear CoII Complexes – Ab Initio Investigation of the Roles of Ligand Field, Structural Distortion, and Conformational Dynamics

Sabyasachi Roy Chowdhury and Sabyashachi Mishra

Eur J Inorg Chem, 2017, 2017, 659
DOI: 10.1002/ejic.201601192

Unravelling the Reason for Transition from the Field-Induced Single-Molecule Magnet to Zero-Field One in a Group of Dysprosium Complexes via Ab Initio Calculation

Xuan Wang, Yan-Ling Hu, Hao Liu, Yu-Xi Wang and Bing Yin

J. Phys. Chem. A, 2025, 129, 5737
DOI: 10.1021/acs.jpca.5c01099

Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown

Jin Wang, Quan‐Wen Li, Si‐Guo Wu, Yan‐Cong Chen, Rui‐Chen Wan, Guo‐Zhang Huang, Yang Liu, Jun‐Liang Liu, Daniel Reta, Marcus J. Giansiracusa, Zhen‐Xing Wang, Nicholas F. Chilton and Ming‐Liang Tong

Angewandte Chemie, 2021, 133, 5359
DOI: 10.1002/ange.202014993

Rare Earth Starting Materials and Methodologies for Synthetic Chemistry

Fabrizio Ortu

Chem. Rev., 2022, 122, 6040
DOI: 10.1021/acs.chemrev.1c00842

High-Frequency and -Field Electron Paramagnetic Resonance Spectroscopic Analysis of Metal–Ligand Covalency in a 4f7 Valence Series (Eu2+, Gd3+, and Tb4+)

Thaige P. Gompa, Samuel M. Greer, Natalie T. Rice, Ningxin Jiang, Joshua Telser, Andrew Ozarowski, Benjamin W. Stein and Henry S. La Pierre

Inorg. Chem., 2021, 60, 9064
DOI: 10.1021/acs.inorgchem.1c01062

Effect of Ligands on Quantum Tunneling of Magnetization for Dysprosium C4v Single-Molecule Magnets with Theoretical Insights

Jiyuan Du, Botan Li, Jiale Tian, Lin Sun, Bing Yin and Pengtao Ma

Crystal Growth & Design, 2024, 24, 3309
DOI: 10.1021/acs.cgd.4c00037

Magnetic relaxation in two 1D Tb-nitronyl nitroxide complexes

Feng-Ping Xiao, Peng Hu, Xiang-Ying Hao, Jiang-Fei Cao and Li-Li Zhu

Inorganica Chimica Acta, 2018, 471, 608
DOI: 10.1016/j.ica.2017.11.026

Electronic Structure of Ytterbium(III) Solvates—a Combined Spectroscopic and Theoretical Study

Nicolaj Kofod, Patrick Nawrocki, Carlos Platas-Iglesias and Thomas Just Sørensen

Inorg. Chem., 2021, 60, 7453
DOI: 10.1021/acs.inorgchem.1c00743

Determining molecular structure, coordination geometry, and molecular symmetry using a continuous symmetry operation measure software

Villads R. M. Nielsen and Thomas Just Sørensen

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-66054-7

Cyclic Single‐Molecule Magnets: From Even‐Numbered Hexanuclear to Odd‐Numbered Heptanuclear Dysprosium Clusters

Haiquan Tian, Song‐Song Bao and Li‐Min Zheng

Eur J Inorg Chem, 2016, 2016, 3184
DOI: 10.1002/ejic.201600392

A trivalent 4f complex with two bis-silylamide ligands displaying slow magnetic relaxation

Dylan Errulat, Katie L. M. Harriman, Diogo A. Gálico, Alexandros A. Kitos, Akseli Mansikkamäki and Muralee Murugesu

Nat. Chem., 2023, 15, 1100
DOI: 10.1038/s41557-023-01208-y

Enantiopure Benzamidinate/Cyclooctatetraene Complexes of the Rare-Earth Elements: Synthesis, Structure, and Magnetism

Meng He, Xiao Chen, Tilmann Bodenstein, Andreas Nyvang, Sebastian F. M. Schmidt, Yan Peng, Eufemio Moreno-Pineda, Mario Ruben, Karin Fink, Michael T. Gamer, Annie K. Powell and Peter W. Roesky

Organometallics, 2018, 37, 3708
DOI: 10.1021/acs.organomet.8b00412

A Low‐Symmetry Dysprosium Metallocene Single‐Molecule Magnet with a High Anisotropy Barrier

Thomas Pugh, Nicholas F. Chilton and Richard A. Layfield

Angew Chem Int Ed, 2016, 55, 11082
DOI: 10.1002/anie.201604346

A Tetra-amido-Protected Ge5-Spiropentadiene

Yan Guo, Zhengqiang Xia, Jingjing Liu, Jiaxiu Yu, Shenglai Yao, Weiqun Shi, Kongqiu Hu, Sanping Chen, Yaoyu Wang, Anyang Li, Matthias Driess and Wenyuan Wang

J. Am. Chem. Soc., 2019, 141, 19252
DOI: 10.1021/jacs.9b10946

Dynamical Simulations of Polaron Spin-Filtering and Rectification in an Organic Magnetic–Nonmagnetic Co-oligomer: The Interfacial Effect

Hui Wang, Hong-yan Shi, Jing-fen Zhao, Xiao-juan Yuan, Wen-jing Wang, Zai-fa Yang, Hong-xia Bu, Yuan-xun Yu, Wen-li Guan, Chang-jian Ji, Kun Gao, Yuan Li and De-Sheng Liu

J. Phys. Chem. C, 2019, 123, 14432
DOI: 10.1021/acs.jpcc.9b01819

Magnetic relaxation in single-ion magnets formed by less-studied lanthanide ions Ce(III), Nd(III), Gd(III), Ho(III), Tm(II/III) and Yb(III)

Aditya Borah and Ramaswamy Murugavel

Coordination Chemistry Reviews, 2022, 453, 214288
DOI: 10.1016/j.ccr.2021.214288

Comparison of the Magnetic Anisotropy and Spin Relaxation Phenomenon of Dinuclear Terbium(III) Phthalocyaninato Single-Molecule Magnets Using the Geometric Spin Arrangement

Takaumi Morita, Marko Damjanović, Keiichi Katoh, Yasutaka Kitagawa, Nobuhiro Yasuda, Yanhua Lan, Wolfgang Wernsdorfer, Brian K. Breedlove, Markus Enders and Masahiro Yamashita

J. Am. Chem. Soc., 2018, 140, 2995
DOI: 10.1021/jacs.7b12667

Regulating Lanthanide Single-Molecule Magnets with Coordination Geometry and Organometallic Chemistry

Peng-Bo Jin, Qian-Cheng Luo and Yan-Zhen Zheng

Acc. Chem. Res., 2026, 59, 221
DOI: 10.1021/acs.accounts.5c00668

Synthesis, characterization and reactivity of a series of alkaline earth and rare earth iminophosphoranomethanide complexes

Matthew P. Stevens, Yu Liu, Elias Alexopoulos, Shifaa S. A. Xec Daudo, Rebecca R. Hawker, Adam Khan, Luis Lezama, Daniel Reta and Fabrizio Ortu

Commun Chem, 2025, 8
DOI: 10.1038/s42004-025-01572-5

Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets

Arun Kumar Bar, Pankaj Kalita, Mukesh Kumar Singh, Gopalan Rajaraman and Vadapalli Chandrasekhar

Coordination Chemistry Reviews, 2018, 367, 163
DOI: 10.1016/j.ccr.2018.03.022

Synthesis of the Bulky Phosphanide [P(SiiPr3)2]− and Its Stabilization of Low-Coordinate Group 12 Complexes

Olivia P. Churchill, Antonia Dase, Laurence J. Taylor, Stephen P. Argent, Nathan T. Coles, Gavin S. Walker and Deborah L. Kays

Inorg. Chem., 2024, 63, 20286
DOI: 10.1021/acs.inorgchem.4c03134

Magnetic Anisotropy in Divalent Lanthanide Compounds

Weibing Zhang, Almas Muhtadi, Naoya Iwahara, Liviu Ungur and Liviu F. Chibotaru

Angew Chem Int Ed, 2020, 59, 12720
DOI: 10.1002/anie.202003399

Theoretical Study of Pentacoordinated Lanthanide Single-Ion Magnets via Ab Initio Electronic Structure Calculation

Yu-Xi Wang, Yu-Fei Wang and Bing Yin

Magnetochemistry, 2025, 11, 3
DOI: 10.3390/magnetochemistry11010003

Enhancing Steric Hindrance via Ligand Design in Dysprosium Complexes: From Induced Slow Relaxation to Zero-Field Single-Molecule Magnet Properties

Christina M. Legendre, Regine Herbst-Irmer and Dietmar Stalke

Inorg. Chem., 2021, 60, 13982
DOI: 10.1021/acs.inorgchem.1c00973

An Inconspicuous Six-Coordinate Neutral DyIII Single-Ion Magnet with Remarkable Magnetic Anisotropy and Stability

Min Li, Haipeng Wu, Zhengqiang Xia, Liviu Ungur, Dan Liu, Liviu F. Chibotaru, Hongshan Ke, Sanping Chen and Shengli Gao

Inorg. Chem., 2020, 59, 7158
DOI: 10.1021/acs.inorgchem.0c00616

Triangular dodecahedral Dy(III) single-ion magnets with pseudo-mono-axial ligand field

Yawen Wang, Hong Li, Shaojun Zheng, Lei Chen, Shu-Chang Luo, Peipei Cen and Ulli Englert

Journal of Molecular Structure, 2026, 1351, 144203
DOI: 10.1016/j.molstruc.2025.144203

Regulating the slow magnetic relaxation behavior of two different shapes Dy4clusters with in situ formed penta‐ and heptadentate Schiff base ligands

Zhong‐Hong Zhu, Hai‐Ling Wang, Xiao‐Xiao Fu, Hua‐Hong Zou and Fu‐Pei Liang

Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5808

Understanding the Magnetic Anisotropy toward Single-Ion Magnets

Yin-Shan Meng, Shang-Da Jiang, Bing-Wu Wang and Song Gao

Acc. Chem. Res., 2016, 49, 2381
DOI: 10.1021/acs.accounts.6b00222

Development of Single‐Molecule Magnets†

Dong Shao and Xin‐Yi Wang

Chin. J. Chem., 2020, 38, 1005
DOI: 10.1002/cjoc.202000090

Rare Earth and Main Group Metal Poly(hydrosilyl) Compounds

Nicole L. Lampland, Aradhana Pindwal, KaKing Yan, Arkady Ellern and Aaron D. Sadow

Organometallics, 2017, 36, 4546
DOI: 10.1021/acs.organomet.7b00383

Four-coordinate dysprosium single-molecule magnets based on amido ligands

Rong Sun, Chen Wang, Bing-Wu Wang, Zhe-Ming Wang and Song Gao

Chin. Sci. Bull., 2025, 70, 5880
DOI: 10.1360/TB-2024-1125

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

Conrad A. P. Goodwin, Nicholas F. Chilton, Gianni F. Vettese, Eufemio Moreno Pineda, Iain F. Crowe, Joseph W. Ziller, Richard E. P. Winpenny, William J. Evans and David P. Mills

Inorg. Chem., 2016, 55, 10057
DOI: 10.1021/acs.inorgchem.6b00808

Adaptability to Crystal Fields in a Series of COT/Monodentate Ligand-Based Dy and Er Single Ion Magnets

Feng Pan, Rong Sun, Bing-Wu Wang and Song Gao

Inorg. Chem., 2023, 62, 8010
DOI: 10.1021/acs.inorgchem.3c00922

A Cost-Effective Semi-Ab Initio Approach to Model Relaxation in Rare-Earth Single-Molecule Magnets

Elena Garlatti, Alessandro Chiesa, Pietro Bonfà, Emilio Macaluso, Ifeanyi J. Onuorah, Vijay S. Parmar, You-Song Ding, Yan-Zhen Zheng, Marcus J. Giansiracusa, Daniel Reta, Eva Pavarini, Tatiana Guidi, David P. Mills, Nicholas F. Chilton, Richard E. P. Winpenny, Paolo Santini and Stefano Carretta

J. Phys. Chem. Lett., 2021, 12, 8826
DOI: 10.1021/acs.jpclett.1c02367

η²-Acetylene Sm^II and Sm^III complexes: mirage or reality?

Hamza Zakaria, Dmitry Mikhailovich Lyubov, Rinat Ravil'evich Aysin, Yulia Vladimirovna Nelyubina, Sergei Sergeevich Bukalov and Aleksandr Anatol'evich Trifonov

Mendeleev Communications, 2025, 35, 310
DOI: 10.71267/mencom.7667

Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes

Tener F. Jenkins, David H. Woen, Luke N. Mohanam, Joseph W. Ziller, Filipp Furche and William J. Evans

Organometallics, 2018, 37, 3863
DOI: 10.1021/acs.organomet.8b00557

Quantifying magnetic anisotropy using X-ray and neutron diffraction

Emil Andreasen Klahn, Emil Damgaard-Møller, Lennard Krause, Iurii Kibalin, Arsen Gukasov, Shalini Tripathi, Abinash Swain, Maheswaran Shanmugam and Jacob Overgaard

IUCrJ, 2021, 8, 833
DOI: 10.1107/S2052252521008290

Experimental and Theoretical Interpretation on the Magnetic Behavior in a Series of Pentagonal‐Bipyramidal DyIII Single‐Ion Magnets

Min Li, Haipeng Wu, Qi Yang, Hongshan Ke, Bing Yin, Quan Shi, Wenyuan Wang, Qing Wei, Gang Xie and Sanping Chen

Chemistry A European J, 2017, 23, 17775
DOI: 10.1002/chem.201703755

Molecular nanomagnets: a viable path toward quantum information processing?

A Chiesa, P Santini, E Garlatti, F Luis and S Carretta

Rep. Prog. Phys., 2024, 87, 034501
DOI: 10.1088/1361-6633/ad1f81

Seven-Coordinate Lanthanide Bis-Halide Bis-Tetrathiometallate Complexes: A Compelling Platform for Luminescent and Magnetic Properties

Marie A. Perrin, Salauat R. Kiraev, Julia Specht, Liam Grunwald, Fabrice Pointillart, Olivier Cador, Boris Le Guennic, Olivier Maury and Victor Mougel

Inorg. Chem., 2026, 65, 360
DOI: 10.1021/acs.inorgchem.5c04468

Air‐Stable Hexagonal Bipyramidal Dysprosium(III) Single‐Ion Magnets with Nearly Perfect D6h Local Symmetry

Zi‐Han Li, Yuan‐Qi Zhai, Wei‐Peng Chen, You‐Song Ding and Yan‐Zhen Zheng

Chemistry A European J, 2019, 25, 16219
DOI: 10.1002/chem.201904325

On Approaching the Limit of Molecular Magnetic Anisotropy: A Near‐Perfect Pentagonal Bipyramidal Dysprosium(III) Single‐Molecule Magnet

You‐Song Ding, Nicholas F. Chilton, Richard E. P. Winpenny and Yan‐Zhen Zheng

Angewandte Chemie, 2016, 128, 16305
DOI: 10.1002/ange.201609685

Synergy of Magnetic Anisotropy and Ferromagnetic Interaction Triggering a Dimeric Cr(II) Zero-Field Single-Molecule Magnet

Yuzhu Li, Zhaopeng Zeng, Yan Guo, Xingman Liu, Yi-Quan Zhang, Zhongwen Ouyang, Zhenxing Wang, Xiangyu Liu and Yan-Zhen Zheng

Inorg. Chem., 2023, 62, 6297
DOI: 10.1021/acs.inorgchem.2c04359

Molecular magnetism of lanthanide: Advances and perspectives

Zhenhua Zhu, Mei Guo, Xiao-Lei Li and Jinkui Tang

Coordination Chemistry Reviews, 2019, 378, 350
DOI: 10.1016/j.ccr.2017.10.030

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Vijay S. Parmar, David P. Mills and Richard E. P. Winpenny

Chemistry A European J, 2021, 27, 7625
DOI: 10.1002/chem.202100085

Magnetic Anisotropy in Divalent Lanthanide Compounds

Weibing Zhang, Almas Muhtadi, Naoya Iwahara, Liviu Ungur and Liviu F. Chibotaru

Angewandte Chemie, 2020, 132, 12820
DOI: 10.1002/ange.202003399

A Combined Synthetic, Magnetic, and Theoretical Study on Enhancing Ligand-Field Axiality for Dy(III) Single-Molecule Magnets Supported by Ferrocene Diamide Ligands

Kexin Yang, Rong Sun, Jingliang Zhao, Chong Deng, Bingwu Wang, Song Gao and Wenliang Huang

Inorg. Chem., 2023, 62, 9892
DOI: 10.1021/acs.inorgchem.3c00896

Synthesis of a Heteroleptic Pentamethylcyclopentadienyl Yttrium(II) Complex, [K(2.2.2-Cryptand)]{(C5Me5)2YII[N(SiMe3)2]}, and Its C–H Bond Activated Y(III) Derivative

Tener F. Jenkins, Samuel Bekoe, Joseph W. Ziller, Filipp Furche and William J. Evans

Organometallics, 2021, 40, 3917
DOI: 10.1021/acs.organomet.1c00482

Comprehensive Spectroscopic Determination of the Crystal Field Splitting in an Erbium Single-Ion Magnet

Yvonne Rechkemmer, Julia E. Fischer, Raphael Marx, María Dörfel, Petr Neugebauer, Sebastian Horvath, Maren Gysler, Theis Brock-Nannestad, Wolfgang Frey, Michael F. Reid and Joris van Slageren

J. Am. Chem. Soc., 2015, 137, 13114
DOI: 10.1021/jacs.5b08344

Enhancing the Magnetic Anisotropy in Low-Symmetry Dy-Based Complexes by Tuning the Bond Length

Yan Li, Ya You, Pu Zhao, Zhong-Yi Liu, Yi-Quan Zhang, En-Cui Yang and Xiao-Jun Zhao

Inorg. Chem., 2021, 60, 11419
DOI: 10.1021/acs.inorgchem.1c01437

Local Geometry Symmetry and Electrostatic Distribution Dominated Eight‐Coordinate β‐Diketone DyIII SIMs

Xu Yao, Pengfei Yan, Guanghui An, Yuxin Li, Weizuo Li and Guangming Li

Eur J Inorg Chem, 2019, 2019, 1413
DOI: 10.1002/ejic.201900006

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills and Stephen Sproules

Inorg. Chem., 2020, 59, 7571
DOI: 10.1021/acs.inorgchem.0c00470

Exploring Synthetic Routes to Heteroleptic UIII, UIV, and ThIV Bulky Bis(silyl)amide Complexes

Conrad A. P. Goodwin, Floriana Tuna, Eric J. L. McInnes and David P. Mills

Eur J Inorg Chem, 2018, 2018, 2356
DOI: 10.1002/ejic.201800036

Approaching the uniaxiality of magnetic anisotropy in single-molecule magnets

Chen Wang, Yin-Shan Meng, Shang-Da Jiang, Bing-Wu Wang and Song Gao

Sci. China Chem., 2023
DOI: 10.1007/s11426-022-1423-4

Strangely attractive: Collaboration and feedback in the field of molecular magnetism

Conrad A. P. Goodwin, Fabrizio Ortu and Daniel Reta

Int J of Quantum Chemistry, 2020, 120
DOI: 10.1002/qua.26248

Characterization of a Monomeric, Homoleptic, Solvent-Free Samarium Bis(aryloxide)

Pei Zhao, Qihao Zhu, James C. Fettinger and Philip Power

Inorg. Chem., 2018, 57, 14044
DOI: 10.1021/acs.inorgchem.8b02677

Yttrium Methanide and Methanediide Bis(silyl)amide Complexes

Fabrizio Ortu, Matthew Gregson, Ashley J. Wooles, David P. Mills and Stephen T. Liddle

Organometallics, 2017, 36, 4584
DOI: 10.1021/acs.organomet.7b00394

Two dysprosium single molecule magnets with planar skeleton built from edge-shared Dy3 triangles

Lan Liu, Zhihui Qiu, Shui Yu, Yuning Liang, Huancheng Hu, HuaHong Zou, Dongcheng Liu, Bing Yin, Fupei Liang and Zilu Chen

Journal of Molecular Structure, 2024, 1308, 138038
DOI: 10.1016/j.molstruc.2024.138038

Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

Conrad A. P. Goodwin, Nicholas F. Chilton, Louise S. Natrajan, Marie-Emmanuelle Boulon, Joseph W. Ziller, William J. Evans and David P. Mills

Inorg. Chem., 2017, 56, 5959
DOI: 10.1021/acs.inorgchem.7b00664

Engineering Mononuclear Ln(III) Complexes with a Pseudo-Macrocyclic Hexadentate N4O2 Schiff Base Ligand Exhibiting Slow Magnetic Relaxation

Ismael Francisco Diaz-Ortega, Yating Ye, Jesus Jover, Eliseo Ruiz, Enrique Colacio and Juan Manuel Herrera

Magnetochemistry, 2024, 10, 104
DOI: 10.3390/magnetochemistry10120104

Magnetostructural Correlation in Trigonal Bipyramidal Fe(III) Complexes: Tuning Spin-State Stability and Magnetic Anisotropy via Second Coordination Sphere Substitution

Shalini Joshi, Sabyasachi Roy Chowdhury and Sabyashachi Mishra

Crystal Growth & Design, 2025, 25, 2602
DOI: 10.1021/acs.cgd.5c00110

A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands

Ariel S. Hyre and Linda H. Doerrer

Coordination Chemistry Reviews, 2020, 404, 213098
DOI: 10.1016/j.ccr.2019.213098

Molecular Magnetism

Nicholas F. Chilton

Annu. Rev. Mater. Res., 2022, 52, 79
DOI: 10.1146/annurev-matsci-081420-042553

Bis(tert-butoxydiphenylsilyl)amide Divalent Lanthanide Complexes

Grant R. Wilkinson, Sarah J. Schultz, Kaitlyn S. Otte, Maximilian G. Bernbeck and Henry S. La Pierre

Inorg. Chem., 2025, 64, 10751
DOI: 10.1021/acs.inorgchem.5c00277

Electronic Energy Levels of Dysprosium(III) ions in Solution. Assigning the Emitting State and the Intraconfigurational 4f–4f Transitions in the Vis–NIR Region and Photophysical Characterization of Dy(III) in Water, Methanol, and Dimethyl Sulfoxide

Nicolaj Kofod, Riikka Arppe-Tabbara and Thomas Just Sørensen

J. Phys. Chem. A, 2019, 123, 2734
DOI: 10.1021/acs.jpca.8b12034

Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings

Johannes Martin, Christian Knüpfer, Jonathan Eyselein, Christian Färber, Samuel Grams, Jens Langer, Katharina Thum, Michael Wiesinger and Sjoerd Harder

Angewandte Chemie, 2020, 132, 9187
DOI: 10.1002/ange.202001160

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

Alessandro Lunghi and Stefano Sanvito

Nat Rev Chem, 2022, 6, 761
DOI: 10.1038/s41570-022-00424-3

Monoanionic Anilidophosphine Ligand in Lanthanide Chemistry: Scope, Reactivity, and Electrochemistry

Fabian A. Watt, Athul Krishna, Grigoriy Golovanov, Holger Ott, Roland Schoch, Christoph Wölper, Adam G. Neuba and Stephan Hohloch

Inorg. Chem., 2020, 59, 2719
DOI: 10.1021/acs.inorgchem.9b03071

Reductive Reactivity of the 4f75d1 Gd(II) Ion in {GdII[N(SiMe3)2]3}−: Structural Characterization of Products of Coupling, Bond Cleavage, Insertion, and Radical Reactions

Amanda B. Chung, Austin J. Ryan, Ming Fang, Joseph W. Ziller and William J. Evans

Inorg. Chem., 2021, 60, 15635
DOI: 10.1021/acs.inorgchem.1c02241

Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions

Gemma K. Gransbury, Hannah M. Nicholas, Siobhan R. Murphy, Jack Emerson-King, Michele Vonci, Conrad A. P. Goodwin, Richard E. P. Winpenny, Nicholas F. Chilton, Marcus J. Giansiracusa and David P. Mills

Inorg. Chem., 2024, 63, 22422
DOI: 10.1021/acs.inorgchem.4c03281

Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding

Colin A. Gould, K. Randall McClain, Daniel Reta, Jon G. C. Kragskow, David A. Marchiori, Ella Lachman, Eun-Sang Choi, James G. Analytis, R. David Britt, Nicholas F. Chilton, Benjamin G. Harvey and Jeffrey R. Long

Science, 2022, 375, 198
DOI: 10.1126/science.abl5470

The Exploration and Analysis of the Magnetic Relaxation Behavior in Three Isostructural Cyano-Bridged 3d–4f Linear Heterotrinuclear Compounds

Xia Xiong, Yangyu Liu, Shan Li, Anqi Xue, Juan Wang, Chi Zhang, Wenhua Zhu and Haoling Sun

Inorganics, 2018, 6, 36
DOI: 10.3390/inorganics6020036

Molecular Design for Single-molecule Magnetism of Lanthanide Complexes

Sunri Lee and Takuji Ogawa

Chem. Lett., 2017, 46, 10
DOI: 10.1246/cl.160800

Crystal structure details of La- and Bi-substituted hydroxyapatites: Evidence for LaO+ and BiO+ with a very short metal–oxygen bond

Pavel E. Kazin, Mariam A. Pogosova, Lev A. Trusov, Irina V. Kolesnik, Oxana V. Magdysyuk and Robert E. Dinnebier

Journal of Solid State Chemistry, 2016, 237, 349
DOI: 10.1016/j.jssc.2016.03.004

Rare‐Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2‐cryptand)][Sc(OC6H2tBu2‐2,6‐Me‐4)3]

Samuel A. Moehring, María J. Beltrán‐Leiva, Dayán Páez‐Hernández, Ramiro Arratia‐Pérez, Joseph W. Ziller and William J. Evans

Chemistry A European J, 2018, 24, 18059
DOI: 10.1002/chem.201803807

Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)

Colin A. Gould, K. Randall McClain, Jason M. Yu, Thomas J. Groshens, Filipp Furche, Benjamin G. Harvey and Jeffrey R. Long

J. Am. Chem. Soc., 2019, 141, 12967
DOI: 10.1021/jacs.9b05816

Main Group Chemistry at the Interface with Molecular Magnetism

Fu-Sheng Guo, Arun Kumar Bar and Richard A. Layfield

Chem. Rev., 2019, 119, 8479
DOI: 10.1021/acs.chemrev.9b00103

Tuning the Equatorial Crystal-Field in Mononuclear DyIII Complexes to Improve Single-Molecule Magnetic Properties

Li Zhu, Bing Yin, Pengtao Ma and Dongfeng Li

Inorg. Chem., 2020, 59, 16117
DOI: 10.1021/acs.inorgchem.0c01716

Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings

Johannes Martin, Christian Knüpfer, Jonathan Eyselein, Christian Färber, Samuel Grams, Jens Langer, Katharina Thum, Michael Wiesinger and Sjoerd Harder

Angew Chem Int Ed, 2020, 59, 9102
DOI: 10.1002/anie.202001160

Substituent Effects on Exchange Coupling and Magnetic Relaxation in 2,2′-Bipyrimidine Radical-Bridged Dilanthanide Complexes

Colin A. Gould, Edward Mu, Veacheslav Vieru, Lucy E. Darago, Khetpakorn Chakarawet, Miguel I. Gonzalez, Selvan Demir and Jeffrey R. Long

J. Am. Chem. Soc., 2020, 142, 21197
DOI: 10.1021/jacs.0c10612

Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown

Jin Wang, Quan‐Wen Li, Si‐Guo Wu, Yan‐Cong Chen, Rui‐Chen Wan, Guo‐Zhang Huang, Yang Liu, Jun‐Liang Liu, Daniel Reta, Marcus J. Giansiracusa, Zhen‐Xing Wang, Nicholas F. Chilton and Ming‐Liang Tong

Angew Chem Int Ed, 2021, 60, 5299
DOI: 10.1002/anie.202014993

Ab initio investigation of magnetic anisotropy in intermediate spin iron(iii) complexes

Sabyasachi Roy Chowdhury and Sabyashachi Mishra

The Journal of Chemical Physics, 2018, 149
DOI: 10.1063/1.5050037

Rare-earth complexes of the asymmetric amide ligands, N(SiMe3)Ph and N(SiMe3)Cy

Samuel A. Moehring, Joseph W. Ziller and William J. Evans

Polyhedron, 2019, 168, 72
DOI: 10.1016/j.poly.2019.04.026

Magnetic Hysteresis in a Dysprosium Bis(amide) Complex

Florian Benner, Rashmi Jena, Aaron L. Odom and Selvan Demir

J. Am. Chem. Soc., 2025, 147, 8156
DOI: 10.1021/jacs.4c08137

Unravelling the Role of Sterically Encumbered Ligands in Tuning the Magnetic Properties of Lanthanide‐Based D5h Single‐Ion Magnets

Aheli Ghatak, Gargi Bhatt, Rajanikanta Rana, Sandeep K. Gupta, Franc Meyer, Gopalan Rajaraman and Ramaswamy Murugavel

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401477

Deciphering the Role of Anions and Secondary Coordination Sphere in Tuning Anisotropy in Dy(III) Air‐Stable D5h SIMs**

Sandeep K. Gupta, Sourav Dey, Thayalan Rajeshkumar, Gopalan Rajaraman and Ramaswamy Murugavel

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202103585

Facile Solvent-Free Mechanochemical Synthesis of UI3 and Lanthanoid Iodides

Daniel Werner, Désirée Badea, Jasmin Schönzart, Sophia Eimermacher, Philipp Bätz, Mathias S. Wickleder and Markus Zegke

Chemistry, 2022, 4, 1672
DOI: 10.3390/chemistry4040108

Two Types of Hexanuclear Partial Tetracubane [Ni4Ln2] (Ln = Dy, Tb, Ho) Complexes of Thioether-Based Schiff Base Ligands: Synthesis, Structure, and Comparison of Magnetic Properties

Avik Bhanja, Radovan Herchel, Zdeněk Trávníček and Debashis Ray

Inorg. Chem., 2019, 58, 12184
DOI: 10.1021/acs.inorgchem.9b01517

Magnetic Hysteresis up to 73 K in a Dysprosium Cyclopentadienyl-Amide Single-Molecule Magnet

Jack Emerson-King, Jack Baldwin, Sophie C. Corner, William J. A. Blackmore, Nicholas F. Chilton and David P. Mills

J. Am. Chem. Soc., 2025, 147, 35555
DOI: 10.1021/jacs.5c10400

Record High Single-Ion Magnetic Moments Through 4fn5d1 Electron Configurations in the Divalent Lanthanide Complexes [(C5H4SiMe3)3Ln]−

Katie R. Meihaus, Megan E. Fieser, Jordan F. Corbey, William J. Evans and Jeffrey R. Long

J. Am. Chem. Soc., 2015, 137, 9855
DOI: 10.1021/jacs.5b03710

Large magnetic anisotropy in mononuclear metal complexes

Silvia Gómez-Coca, Daniel Aravena, Roser Morales and Eliseo Ruiz

Coordination Chemistry Reviews, 2015, 289-290, 379
DOI: 10.1016/j.ccr.2015.01.021

Lanthanide(III)-Based Single-Ion Magnets

Atanu Dey, Pankaj Kalita and Vadapalli Chandrasekhar

ACS Omega, 2018, 3, 9462
DOI: 10.1021/acsomega.8b01204

A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes

Samuel A. Moehring, Matthias Miehlich, Christopher J. Hoerger, Karsten Meyer, Joseph W. Ziller and William J. Evans

Inorg. Chem., 2020, 59, 3207
DOI: 10.1021/acs.inorgchem.9b03587

A Local D4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K**

Xia‐Li Ding, Yuan‐Qi Zhai, Tian Han, Wei‐Peng Chen, You‐Song Ding and Yan‐Zhen Zheng

Chemistry A European J, 2021, 27, 2623
DOI: 10.1002/chem.202003931

Experimental and Theoretical Studies on the Magnetic Anisotropy in Lanthanide(III)‐Centered Fe3Ln Propellers

Luca Rigamonti, Andrea Nava, Marie‐Emmanuelle Boulon, Javier Luzon, Roberta Sessoli and Andrea Cornia

Chemistry A European J, 2015, 21, 12171
DOI: 10.1002/chem.201501400

Hard Single-Molecule Magnet Behavior by a Linear Trinuclear Lanthanide–[1]Metallocenophane Complex

Trevor P. Latendresse, Nattamai S. Bhuvanesh and Michael Nippe

J. Am. Chem. Soc., 2017, 139, 14877
DOI: 10.1021/jacs.7b08690

Relaxation Dynamics and Magnetic Anisotropy in a Low‐Symmetry DyIII Complex

Eva Lucaccini, Matteo Briganti, Mauro Perfetti, Laure Vendier, Jean‐Pierre Costes, Federico Totti, Roberta Sessoli and Lorenzo Sorace

Chemistry A European J, 2016, 22, 5552
DOI: 10.1002/chem.201505211

Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

Simon G. McAdams, Ana-Maria Ariciu, Andreas K. Kostopoulos, James P.S. Walsh and Floriana Tuna

Coordination Chemistry Reviews, 2017, 346, 216
DOI: 10.1016/j.ccr.2017.03.015

Alumanyl-Samarium(II): Synthesis, Characterization, and Reactivity Studies

Genfeng Feng, Ka Lok Chan, Zhenyang Lin and Makoto Yamashita

J. Am. Chem. Soc., 2024, 146, 7204
DOI: 10.1021/jacs.4c01193

Electrostatic Potential Determined Magnetic Dynamics Observed in Two Mononuclear β-Diketone Dysprosium(III) Single-Molecule Magnets

Pei-Pei Cen, Sheng Zhang, Xiang-Yu Liu, Wei-Ming Song, Yi-Quan Zhang, Gang Xie and San-Ping Chen

Inorg. Chem., 2017, 56, 3644
DOI: 10.1021/acs.inorgchem.7b00057

Theoretical analyses of actinide single-atom magnetic behavior: Spin-vibration coupling and spin relaxation dynamics of single uranium atom on MgO/Ag(100)

Jie Liu, Ninghan Qiao, Hong Chen, Ruizhi Qiu and Hongkuan Yuan

Phys. Rev. B, 2025, 111
DOI: 10.1103/PhysRevB.111.184430

High-Pressure Crystallography as a Guide in the Design of Single-Molecule Magnets

Andreas M. Thiel, Emil Damgaard-Møller and Jacob Overgaard

Inorg. Chem., 2020, 59, 1682
DOI: 10.1021/acs.inorgchem.9b02794

Investigating Steric and Electronic Effects in the Synthesis of Square Planar 6d1 Th(III) Complexes

Joseph Q. Nguyen, Justin C. Wedal, Joseph W. Ziller, Filipp Furche and William J. Evans

Inorg. Chem., 2024, 63, 6217
DOI: 10.1021/acs.inorgchem.3c04462

Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

Veacheslav Vieru, Silvia Gómez‐Coca, Eliseo Ruiz and Liviu F. Chibotaru

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202303146

Magnetocaloric effect and slow magnetic relaxation behavior in binuclear rare earth based RE2(L)2(DMF)4 (RE = Gd, Tb, and Dy) complexes

Zhenqian Zhang, Yuwei Wu, Haifeng Wang and Lingwei Li

Journal of Rare Earths, 2022, 40, 916
DOI: 10.1016/j.jre.2021.04.009

Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII]

Daniel N. Huh, Sierra R. Ciccone, William N.G. Moore, Joseph W. Ziller and William J. Evans

Polyhedron, 2021, 210, 115493
DOI: 10.1016/j.poly.2021.115493

Pentagonal-Bipyramid Ln(III) Complexes Exhibiting Single-Ion-Magnet Behavior: A Rational Synthetic Approach for a Rigid Equatorial Plane

Arun Kumar Bar, Pankaj Kalita, Jean-Pascal Sutter and Vadapalli Chandrasekhar

Inorg. Chem., 2018, 57, 2398
DOI: 10.1021/acs.inorgchem.8b00059

Observation of the asphericity of 4f-electron density and its relation to the magnetic anisotropy axis in single-molecule magnets

Chen Gao, Alessandro Genoni, Song Gao, Shangda Jiang, Alessandro Soncini and Jacob Overgaard

Nat. Chem., 2020, 12, 213
DOI: 10.1038/s41557-019-0387-6

Multifunctional Dy3+ Complexes with Triphenylmethanolates: Structural Diversity, Luminescence, and Magnetic Relaxation

Gautier Félix, Aleksei O. Tolpygin, Aurore Larquey, Ilia A. Gogolev, Yulia V. Nelyubina, Yannick Guari, Joulia Larionova and Alexander A. Trifonov

Molecules, 2024, 29, 5343
DOI: 10.3390/molecules29225343

Isolation of a Bent Dysprosium Bis(amide) Single-Molecule Magnet

Jack Emerson-King, Gemma K. Gransbury, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, Mathieu Rouzières, Rodolphe Clérac, Nicholas F. Chilton and David P. Mills

J. Am. Chem. Soc., 2024, 146, 3331
DOI: 10.1021/jacs.3c12427

Role of Lanthanide-Ligand bonding in the magnetization relaxation of mononuclear single-ion magnets: A case study on Pyrazole and Carbene ligated Ln I I I (Ln=Tb, Dy, Ho, Er) complexes

TULIKA GUPTA, GUNASEKARAN VELMURUGAN, THAYALAN RAJESHKUMAR and GOPALAN RAJARAMAN

J Chem Sci, 2016, 128, 1615
DOI: 10.1007/s12039-016-1147-4

Anion Effects on Lanthanide(III) Tetrazole-1-acetate Dinuclear Complexes Showing Slow Magnetic Relaxation and Photofluorescent Emission

Ying-Bing Lu, Xiao-Ming Jiang, Shui-Dong Zhu, Zi-Yi Du, Cai-Ming Liu, Yong-Rong Xie and Liang-Xian Liu

Inorg. Chem., 2016, 55, 3738
DOI: 10.1021/acs.inorgchem.5b02432

Structural Characterization of Lithium and Sodium Bulky Bis(silyl)amide Complexes

Hannah M. Nicholas, Conrad A. P. Goodwin, Jon G. C. Kragskow, Selena J. Lockyer and David P. Mills

Molecules, 2018, 23, 1138
DOI: 10.3390/molecules23051138

Emerging Trends on Designing High-Performance Dysprosium(III) Single-Molecule Magnets

Tesfay G. Ashebr, Hui Li, Xu Ying, Xiao-Lei Li, Chen Zhao, Shuting Liu and Jinkui Tang

ACS Materials Lett., 2022, 4, 307
DOI: 10.1021/acsmaterialslett.1c00765

Single Ion Magnets from 3d to 5f: Developments and Strategies

Min Feng and Ming‐Liang Tong

Chemistry A European J, 2018, 24, 7574
DOI: 10.1002/chem.201705761

Single-molecule magnet behavior in heteroleptic dysprosium complexes supported by carboranyl and bidentate dianionic ligands

Yu-Xin Li, Ye-Ye Liu, Qian-Cheng Luo, Peng-Bo Jin and Yan-Zhen Zheng

Chinese Chemical Letters, 2026, 112761
DOI: 10.1016/j.cclet.2026.112761

Design of a Family of Ln3 Triangles with the HAT Ligand (1,4,5,8,9,12-Hexaazatriphenylene): Single-Molecule Magnetism

Ismael F. Díaz-Ortega, Juan Manuel Herrera, Tulika Gupta, Gopalan Rajaraman, Hiroyuki Nojiri and Enrique Colacio

Inorg. Chem., 2017, 56, 5594
DOI: 10.1021/acs.inorgchem.6b03031

tert-Butyl(cyclopentadienyl) Ligands Will Stabilize Nontraditional +2 Rare-Earth Metal Ions

Mary A. Angadol, David H. Woen, Cory J. Windorff, Joseph W. Ziller and William J. Evans

Organometallics, 2019, 38, 1151
DOI: 10.1021/acs.organomet.8b00941

Optimizing Alkali Metal (M) and Chelate (L) Combinations for the Synthesis and Stability of [M(L)][(C5H4SiMe3)3Y] Yttrium(II) Complexes

William N. G. Moore, Joseph W. Ziller and William J. Evans

Organometallics, 2021, 40, 3170
DOI: 10.1021/acs.organomet.1c00379

On Approaching the Limit of Molecular Magnetic Anisotropy: A Near‐Perfect Pentagonal Bipyramidal Dysprosium(III) Single‐Molecule Magnet

You‐Song Ding, Nicholas F. Chilton, Richard E. P. Winpenny and Yan‐Zhen Zheng

Angew Chem Int Ed, 2016, 55, 16071
DOI: 10.1002/anie.201609685

Understanding the Magnetic Relaxation Mechanism in Mixed-Valence Dilanthanide Complexes with Metal–Metal Bonding: A Theoretical Investigation

Tao Shang, Fang Lu, Jin Tao and Yi-Quan Zhang

J. Phys. Chem. A, 2023, 127, 3088
DOI: 10.1021/acs.jpca.2c08526

Designing Ligands to Isolate ZnLn and Zn2Ln Complexes: Field-Induced Single-Ion Magnet Behavior of the ZnDy, Zn2Dy, and Zn2Er Analogues

Matilde Fondo, Julio Corredoira-Vázquez, Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Juan Manuel Herrera and Enrique Colacio

Inorg. Chem., 2017, 56, 5646
DOI: 10.1021/acs.inorgchem.7b00165

Strategies toward High-Temperature Lanthanide-Based Single-Molecule Magnets

Liviu Ungur and Liviu F. Chibotaru

Inorg. Chem., 2016, 55, 10043
DOI: 10.1021/acs.inorgchem.6b01353

Low‐Coordinate Single‐Ion Magnets by Intercalation of Lanthanides into a Phenol Matrix

Yin‐Shan Meng, Ling Xu, Jin Xiong, Qiong Yuan, Tao Liu, Bing‐Wu Wang and Song Gao

Angew Chem Int Ed, 2018, 57, 4673
DOI: 10.1002/anie.201801223

Two 1,8-naphthalenediol-based dysprosium complexes: syntheses, structures, and magnetic properties

Yue Wang, Mei Guo, Jianfeng Wu, Xiao-Lei Li, Yun-Hui Li, Ying Gao and Jinkui Tang

Journal of Coordination Chemistry, 2016, 69, 1864
DOI: 10.1080/00958972.2016.1190837

Molcas 8: New capabilities for multiconfigurational quantum chemical calculations across the periodic table

Francesco Aquilante, Jochen Autschbach, Rebecca K. Carlson, Liviu F. Chibotaru, Mickaël G. Delcey, Luca De Vico, Ignacio Fdez. Galván, Nicolas Ferré, Luis Manuel Frutos, Laura Gagliardi, Marco Garavelli, Angelo Giussani, Chad E. Hoyer, Giovanni Li Manni, Hans Lischka, Dongxia Ma, Per Åke Malmqvist, Thomas Müller, Artur Nenov, Massimo Olivucci, Thomas Bondo Pedersen, Daoling Peng, Felix Plasser, Ben Pritchard, Markus Reiher, Ivan Rivalta, Igor Schapiro, Javier Segarra‐Martí, Michael Stenrup, Donald G. Truhlar, Liviu Ungur, Alessio Valentini, Steven Vancoillie, Valera Veryazov, Victor P. Vysotskiy, Oliver Weingart, Felipe Zapata and Roland Lindh

J Comput Chem, 2016, 37, 506
DOI: 10.1002/jcc.24221

Slow Relaxation of Magnetization in an Isostructural Series of Zinc–Lanthanide Complexes: An Integrated EPR and AC Susceptibility Study

Asma Amjad, Augustin M. Madalan, Marius Andruh, Andrea Caneschi and Lorenzo Sorace

Chemistry A European J, 2016, 22, 12849
DOI: 10.1002/chem.201601996

Understanding magnetic relaxation in single-ion magnets with high blocking temperature

A. Chiesa, F. Cugini, R. Hussain, E. Macaluso, G. Allodi, E. Garlatti, M. Giansiracusa, C. A. P. Goodwin, F. Ortu, D. Reta, J. M. Skelton, T. Guidi, P. Santini, M. Solzi, R. De Renzi, D. P. Mills, N. F. Chilton and S. Carretta

Phys. Rev. B, 2020, 101
DOI: 10.1103/PhysRevB.101.174402

Synthesis, structures and magnetic properties of [(η9-C9H9)Ln(η8-C8H8)] super sandwich complexes

L. Münzfeld, C. Schoo, S. Bestgen, E. Moreno-Pineda, R. Köppe, M. Ruben and P. W. Roesky

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-10976-6

Single-Molecule Magnet Properties in 3d4f Heterobimetallic Iron and Dysprosium Complexes Involving Hydrazone Ligand

Bertrand Lefeuvre, Thierry Guizouarn, Vincent Dorcet, Marie Cordier and Fabrice Pointillart

Molecules, 2023, 28, 6359
DOI: 10.3390/molecules28176359

A Low‐Symmetry Dysprosium Metallocene Single‐Molecule Magnet with a High Anisotropy Barrier

Thomas Pugh, Nicholas F. Chilton and Richard A. Layfield

Angewandte Chemie, 2016, 128, 11248
DOI: 10.1002/ange.201604346

Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5

David H. Woen, Jessica R.K. White, Joseph W. Ziller and William J. Evans

Journal of Organometallic Chemistry, 2019, 899, 120885
DOI: 10.1016/j.jorganchem.2019.120885

Elucidating the Magnetic Anisotropy and Relaxation Dynamics of Low-Coordinate Lanthanide Compounds

Peng Zhang, Julie Jung, Li Zhang, Jinkui Tang and Boris Le Guennic

Inorg. Chem., 2016, 55, 1905
DOI: 10.1021/acs.inorgchem.5b02792

Magnetic Anisotropy, Magneto–Structural Correlations and Mechanism of Magnetic Relaxation in {DyIIIN8} Complexes: A Theoretical Perspective

Tulika Gupta and Gopalan Rajaraman

Eur J Inorg Chem, 2018, 2018, 3402
DOI: 10.1002/ejic.201800350

Synthesis of Superbulky Amide Ligands by Addition of Polar Reagents to Sila–Imine

Christian Knüpfer, Lukas Klerner, Michael Raucheisen, Jens Langer and Sjoerd Harder

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400715

Soft magnetic hysteresis in a dysprosium amide–alkene complex up to 100 kelvin

Jack Emerson-King, Gemma K. Gransbury, Benjamin E. Atkinson, William J. A. Blackmore, George F. S. Whitehead, Nicholas F. Chilton and David P. Mills

Nature, 2025, 643, 125
DOI: 10.1038/s41586-025-09138-0

Phenalenyl-based mononuclear dysprosium complexes

Yanhua Lan, Andrea Magri, Olaf Fuhr and Mario Ruben

Beilstein J. Nanotechnol., 2016, 7, 995
DOI: 10.3762/bjnano.7.92

High-Pressure Crystallographic and Magnetic Studies of Pseudo-D5h Symmetric Dy(III) and Ho(III) Single-Molecule Magnets

Marie S. Norre, Chen Gao, Sourav Dey, Sandeep K. Gupta, Aditya Borah, Ramaswamy Murugavel, Gopalan Rajaraman and Jacob Overgaard

Inorg. Chem., 2020, 59, 717
DOI: 10.1021/acs.inorgchem.9b02962

Tetramethylcyclopentadienyl Samarium(II) Metallocene Chemistry: Isolation of a Bimetallic Sm(II)/Sm(II) Complex

Joseph Q. Nguyen, Joseph W. Ziller and William J. Evans

Inorganics, 2022, 11, 4
DOI: 10.3390/inorganics11010004

Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes

Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jesús Ferrando-Soria, Gang Xie, Sanping Chen and Emilio Pardo

Inorg. Chem., 2018, 57, 14843
DOI: 10.1021/acs.inorgchem.8b02602

Magnetic Interaction Affecting the Zero-Field Single-Molecule Magnet Behaviors in Isomorphic {NiII2DyIII2} and {CoII2DyIII2} Tetranuclear Complexes

Haipeng Wu, Min Li, Sheng Zhang, Hongshan Ke, Yiquan Zhang, Guilin Zhuang, Wenyuan Wang, Qing Wei, Gang Xie and Sanping Chen

Inorg. Chem., 2017, 56, 11387
DOI: 10.1021/acs.inorgchem.7b01840

AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets

Gemma K. Gransbury, Sophie C. Corner, Jon G. C. Kragskow, Peter Evans, Hing Man Yeung, William J. A. Blackmore, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, Meagan S. Oakley, Nicholas F. Chilton and David P. Mills

J. Am. Chem. Soc., 2023, 145, 22814
DOI: 10.1021/jacs.3c08841

Magnetic Hysteresis at 31 K in a Four-Coordinate Dysprosium(III) Amide Complex

Benjamin L. L. Réant, William J. A. Blackmore, Nicolaj Kofod, John A. Seed, Meagan S. Oakley and Conrad A. P. Goodwin

J. Am. Chem. Soc., 2026, 148, 2942
DOI: 10.1021/jacs.5c13255

Design Criteria for High-Temperature Single-Molecule Magnets

Nicholas F. Chilton

Inorg. Chem., 2015, 54, 2097
DOI: 10.1021/acs.inorgchem.5b00089

Synthesis and Structure of Silyl-Substituted Bis(cyclopentadienyl) Scandium(III) Halide Complexes

Joseph Q. Nguyen, Lauren M. Anderson-Sanchez, Joseph W. Ziller and William J. Evans

Organometallics, 2025, 44, 137
DOI: 10.1021/acs.organomet.4c00412

Low‐Coordinate Single‐Ion Magnets by Intercalation of Lanthanides into a Phenol Matrix

Yin‐Shan Meng, Ling Xu, Jin Xiong, Qiong Yuan, Tao Liu, Bing‐Wu Wang and Song Gao

Angewandte Chemie, 2018, 130, 4763
DOI: 10.1002/ange.201801223

A Dy2 Dimer Embedded in One Salen‐type Ligand with Different Local Symmetries Behaves as Zero‐field Single‐Molecule Magnet

Jing‐Wei Yang, Zhao‐Fu Yang, Peng Chen, Yong‐Mei Tian and Wen‐Bin Sun

Zeitschrift anorg allge chemie, 2018, 644, 443
DOI: 10.1002/zaac.201800001

Synthesis and Structure of Heteroleptic [C5Me4(SiMe2tBu)]1– Uranium(III) Complexes

Joseph Q. Nguyen, Olaf Nachtigall, Austin J. Ryan, Brynn N. Turpin, Joseph W. Ziller and William J. Evans

Organometallics, 2024, 43, 2767
DOI: 10.1021/acs.organomet.4c00325

Two Dy(III) Single-Molecule Magnets with Their Performance Tuned by Schiff Base Ligands

Shui Yu, Zhaobo Hu, Zilu Chen, Bo Li, Yi-Quan Zhang, Yuning Liang, Dongcheng Liu, Di Yao and Fupei Liang

Inorg. Chem., 2019, 58, 1191
DOI: 10.1021/acs.inorgchem.8b02637

Single molecular magnet behavior for a copper(II)–terbium(III) 15-metallacrown-5 complex based on pyrazinehydroxamic acid

Honggang Zhang, Hua Yang, Jie Yang, Dacheng Li and Jianmin Dou

Inorganica Chimica Acta, 2019, 495, 119014
DOI: 10.1016/j.ica.2019.119014

Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs

Daniel N. Huh, Joseph W. Ziller and William J. Evans

Inorg. Chem., 2018, 57, 11809
DOI: 10.1021/acs.inorgchem.8b01966

Synthesis, Redox Chemistry, and Electronic Structures of Bis-di(silylamido)silane f-Element Complexes

Benjamin L. L. Réant, S. Genevieve Duggan, John A. Seed, Pere Miró and Conrad A. P. Goodwin

Inorg. Chem., 2025, 64, 21465
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