Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst

Debabrata Mukherjee, Satoru Shirase, Thomas P. Spaniol, Kazushi Mashima and Jun Okuda

Chem. Commun., 2016, 52, 13155
DOI: 10.1039/C6CC06805G

Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated CO bond cleavage

Yan Yang, Mathew D. Anker, Jian Fang, Mary F. Mahon, Laurent Maron, Catherine Weetman and Michael S. Hill

Chem. Sci., 2017, 8, 3529
DOI: 10.1039/C7SC00117G

Organoaluminum hydrides catalyzed hydroboration of carbonates, esters, carboxylic acids, and carbon dioxide

Ben Yan, Sayan Dutta, Xiaoli Ma, Congjian Ni, Debasis Koley, Zhi Yang and Herbert W. Roesky

Dalton Trans., 2022, 51, 6756
DOI: 10.1039/D2DT00785A

Extremely efficient hydroboration of ketones and aldehydes by copper carbene catalysis

Sharareh Bagherzadeh and Neal P. Mankad

Chem. Commun., 2016, 52, 3844
DOI: 10.1039/C5CC09162D

NaHBEt3-catalyzed HBpin hydroboration and deoxygenation of primary, secondary, and tertiary amides

Ben Yan, Xiaoli Ma, Ziyuan Pang and Zhi Yang

New J. Chem., 2023, 47, 3202
DOI: 10.1039/D2NJ05849A

Synthesis and characterization of rare-earth metallate amido complexes bearing the 2-amidate-functionalized indolyl ligand and their application in the hydroboration of esters with pinacolborane

Yun Wei, Qin Bao, Lulu Song, Dongjing Hong, Jianjian Gao, Shaowu Wang, Xiancui Zhu, Shuangliu Zhou and Xiaolong Mu

Dalton Trans., 2022, 51, 2953
DOI: 10.1039/D1DT03384K

Magnesium amide catalyzed selective hydroboration of esters

Milan Kr. Barman, Ashim Baishya and Sharanappa Nembenna

Dalton Trans., 2017, 46, 4152
DOI: 10.1039/C7DT00556C

Magnesium-catalysed nitrile hydroboration

Catherine Weetman, Mathew D. Anker, Merle Arrowsmith, Michael S. Hill, Gabriele Kociok-Köhn, David J. Liptrot and Mary F. Mahon

Chem. Sci., 2016, 7, 628
DOI: 10.1039/C5SC03114A

Rhenium-catalysed hydroboration of aldehydes and aldimines

Rebeca Arévalo, Christopher M. Vogels, Gregory A. MacNeil, Lucía Riera, Julio Pérez and Stephen A. Westcott

Dalton Trans., 2017, 46, 7750
DOI: 10.1039/C7DT01549F

The transition metal-catalysed hydroboration reaction

Stephen J. Geier, Christopher M. Vogels, Jennifer A. Melanson and Stephen A. Westcott

Chem. Soc. Rev., 2022, 51, 8877
DOI: 10.1039/D2CS00344A

Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane

Mirco Fleige, Juri Möbus, Thorsten vom Stein, Frank Glorius and Douglas W. Stephan

Chem. Commun., 2016, 52, 10830
DOI: 10.1039/C6CC05360B

Hydrosilylation and hydroboration in a sustainable manner: from Earth-abundant catalysts to catalyst-free solutions

Krzysztof Kuciński and Grzegorz Hreczycho

Green Chem., 2020, 22, 5210
DOI: 10.1039/D0GC01430C

Catalytic bond forming reactions promoted by amidinate, guanidinate and phosphaguanidinate compounds of magnesium

Ryan J. Schwamm, Benjamin M. Day, Natalie E. Mansfield, William Knowelden, Peter B. Hitchcock and Martyn P. Coles

Dalton Trans., 2014, 43, 14302
DOI: 10.1039/C4DT01097C

An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

Congjian Ni, Hailong Yu, Ling Liu, Ben Yan, Bingyi Zhang, Xiaoli Ma, Xiuhui Zhang and Zhi Yang

New J. Chem., 2022, 46, 14635
DOI: 10.1039/D2NJ03136A

Catalytic hydroboration of carbonyl derivatives by using phosphinimino amide ligated magnesium complexes

Min Li, Xinli Liu and Dongmei Cui

Dalton Trans., 2021, 50, 13037
DOI: 10.1039/D1DT00143D

Tri-coordinated zinc alkyl complexes with N^S/Se coordination of imino-phosphanamidinate chalcogenide ligands as precursors for efficient hydroboration of nitriles and esters

Himadri Karmakar, Gobbilla Sai Kumar, Kuntal Pal, Vadapalli Chandrasekhar and Tarun K. Panda

Dalton Trans., 2024, 53, 10592
DOI: 10.1039/D4DT00840E

Alkaline earths as main group reagents in molecular catalysis

Michael S. Hill, David J. Liptrot and Catherine Weetman

Chem. Soc. Rev., 2016, 45, 972
DOI: 10.1039/C5CS00880H

Low-valent-tungsten catalysis enables hydroboration of esters and nitriles

Heng Song, Yuting Xiao, Jingjing Wei, Yuzan Liu, Liqing Yang, Pengtao Bai, Fu Yang, Kai Yu, Chen Xu and Xingwei Cai

Chem. Commun., 2024, 60, 5026
DOI: 10.1039/D4CC00041B

Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters

Xu Cao, Weifan Wang, Kai Lu, Weiwei Yao, Fei Xue and Mengtao Ma

Dalton Trans., 2020, 49, 2776
DOI: 10.1039/D0DT00465K

Main group metal–ligand cooperation of N-heterocyclic germylene: an efficient catalyst for hydroboration of carbonyl compounds

Yile Wu, Changkai Shan, Ying Sun, Peng Chen, Jianxi Ying, Jun Zhu, Liu Leo Liu and Yufen Zhao

Chem. Commun., 2016, 52, 13799
DOI: 10.1039/C6CC08147A

N^Nvs.N^E (E = S or Se) coordination behavior of imino-phosphanamidinate chalcogenide ligands towards aluminum alkyls: efficient hydroboration catalysis of nitriles, alkynes, and alkenes

Himadri Karmakar, Ravi Kumar, Jyoti Sharma, Jayanta Bag, Kuntal Pal, Tarun K. Panda and Vadapalli Chandrasekhar

Dalton Trans., 2023, 52, 4481
DOI: 10.1039/D3DT00038A

Hydroborative reduction of amides to amines mediated by La(CH2C6H4NMe2-o)3

Fangcao Zhang, Chenjun Guo, Mingliang Gong, Hongzhen Xie and Yunjie Luo

New J. Chem., 2022, 46, 779
DOI: 10.1039/D1NJ04996H

Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

Sandeep Yadav, Sanjukta Pahar and Sakya S. Sen

Chem. Commun., 2017, 53, 4562
DOI: 10.1039/C7CC02311A

Iron(ii) coordination polymer catalysed hydroboration of ketones

Li Li, E Liu, Jessica Cheng and Guoqi Zhang

Dalton Trans., 2018, 47, 9579
DOI: 10.1039/C8DT02134A

Zinc hydride catalyzed hydroboration of esters

A. Ganesh Patro, Rajata Kumar Sahoo and Sharanappa Nembenna

Dalton Trans., 2024, 53, 3621
DOI: 10.1039/D3DT04084D

Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

Lara E. Lemmerz, Debabrata Mukherjee, Thomas P. Spaniol, Anthony Wong, Gabriel Ménard, Laurent Maron and Jun Okuda

Chem. Commun., 2019, 55, 3199
DOI: 10.1039/C9CC00490D

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

Go Nakamura, Yumiko Nakajima, Kazuhiro Matsumoto, Venu Srinivas and Shigeru Shimada

Catal. Sci. Technol., 2017, 7, 3196
DOI: 10.1039/C7CY00944E

Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones

Milan Kumar Bisai, Tamal Das, Kumar Vanka and Sakya S. Sen

Chem. Commun., 2018, 54, 6843
DOI: 10.1039/C8CC02314J

Sterically bulky amido magnesium methyl complexes: syntheses, structures and catalysis

Mengtao Ma, Jia Li, Xingchao Shen, Zhijuan Yu, Weiwei Yao and Sumod A. Pullarkat

RSC Adv., 2017, 7, 45401
DOI: 10.1039/C7RA08836A

A bis-dianionic β-ketoiminato octalithium complex as a universal catalyst for hydroboration with broad scope

Yu Zheng, Xu Zhu, Xiaojuan Xu, Shuai Zhou, Wenguang Lu and Mingqiang Xue

New J. Chem., 2023, 47, 19367
DOI: 10.1039/D3NJ03524G

Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

Darren Willcox, Jamie L. Carden, Adam J. Ruddy, Paul D. Newman and Rebecca L. Melen

Dalton Trans., 2020, 49, 2417
DOI: 10.1039/D0DT00232A

CeO2–nanocubes as efficient and selective catalysts for the hydroboration of carbonyl groups

Ramesh Bhawar, Kiran S. Patil and Shubhankar Kumar Bose

New J. Chem., 2021, 45, 15028
DOI: 10.1039/D1NJ00065A

Efficient hydroboration of carbonyls by an iron(ii) amide catalyst

Ashim Baishya, Swavalina Baruah and K. Geetharani

Dalton Trans., 2018, 47, 9231
DOI: 10.1039/C8DT01998C

La(CH2C6H4NMe2-o)3-catalyzed reduction of esters to alcohols with pinacolborane

Fangcao Zhang, Mingliang Gong, Hongzhen Xie and Yunjie Luo

New J. Chem., 2021, 45, 17654
DOI: 10.1039/D1NJ03732C

Catalytic hydroboration of aldehydes, ketones, alkynes and alkenes initiated by NaOH

Yile Wu, Changkai Shan, Jianxi Ying, Jue Su, Jun Zhu, Liu Leo Liu and Yufen Zhao

Green Chem., 2017, 19, 4169
DOI: 10.1039/C7GC01632H

Possible B–C bonding in the hydroboration of benzonitrile by an external electric field

Ming-Xia Zhang and Hong-Liang Xu

Phys. Chem. Chem. Phys., 2019, 21, 18
DOI: 10.1039/C8CP06704J

Magnesium-catalysed hydroboration of isonitriles

Catherine Weetman, Michael S. Hill and Mary F. Mahon

Chem. Commun., 2015, 51, 14477
DOI: 10.1039/C5CC05708F

Lithium triethylborohydride as catalyst for solvent-free hydroboration of aldehydes and ketones

Krzysztof Kuciński and Grzegorz Hreczycho

Green Chem., 2019, 21, 1912
DOI: 10.1039/C9GC00216B

Snapshots of magnesium-centred diborane heterolysis by an outer sphere SN2 process

Anne-Frédérique Pécharman, Michael S. Hill, Grace McMullon, Claire L. McMullin and Mary F. Mahon

Chem. Sci., 2019, 10, 6672
DOI: 10.1039/C9SC02087J

Lithium compounds as single site catalysts for hydroboration of alkenes and alkynes

Milan Kumar Bisai, Sandeep Yadav, Tamal Das, Kumar Vanka and Sakya S. Sen

Chem. Commun., 2019, 55, 11711
DOI: 10.1039/C9CC05783H

Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis

Mathew D. Anker, Merle Arrowsmith, Peter Bellham, Michael S. Hill, Gabriele Kociok-Köhn, David J. Liptrot, Mary F. Mahon and Catherine Weetman

Chem. Sci., 2014, 5, 2826
DOI: 10.1039/C4SC00885E

Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation

Jamie L. Carden, Lukas J. Gierlichs, Duncan F. Wass, Duncan L. Browne and Rebecca L. Melen

Chem. Commun., 2019, 55, 318
DOI: 10.1039/C8CC09459D

A highly efficient Ti-catalyst for the deoxygenative reduction of esters under ambient conditions: experimental and mechanistic insights from DFT studies

Jayeeta Bhattacharjee, Parveen Rawal, Suman Das, Adimulam Harinath, Puneet Gupta and Tarun K. Panda

Dalton Trans., 2022, 51, 5859
DOI: 10.1039/D2DT00076H

Main group catalysed reduction of unsaturated bonds

K. Revunova and G. I. Nikonov

Dalton Trans., 2015, 44, 840
DOI: 10.1039/C4DT02024C

The borylamino-diborata-allyl anion

Henry T. W. Shere, Han-Ying Liu, Samuel E. Neale, Michael S. Hill, Mary F. Mahon and Claire L. McMullin

Chem. Sci., 2024, 15, 7999
DOI: 10.1039/D4SC01953A

1-D manganese(ii)-terpyridine coordination polymers as precatalysts for hydrofunctionalisation of carbonyl compounds

Guoqi Zhang, Haisu Zeng, Sihan Li, Jahvon Johnson, Zixuan Mo, Michelle C. Neary and Shengping Zheng

Dalton Trans., 2020, 49, 2610
DOI: 10.1039/C9DT04637B

Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study

Dongdong Xu, Chunhui Shan, Yingzi Li, Xiaotian Qi, Xiaoling Luo, Ruopeng Bai and Yu Lan

Inorg. Chem. Front., 2017, 4, 1813
DOI: 10.1039/C7QI00459A

A cationic aluminium complex: an efficient mononuclear main-group catalyst for the cyanosilylation of carbonyl compounds

Mahendra Kumar Sharma, Soumen Sinhababu, Goutam Mukherjee, Gopalan Rajaraman and Selvarajan Nagendran

Dalton Trans., 2017, 46, 7672
DOI: 10.1039/C7DT01760J

Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane

Milan Kumar Bisai, Sanjukta Pahar, Tamal Das, Kumar Vanka and Sakya S. Sen

Dalton Trans., 2017, 46, 2420
DOI: 10.1039/C6DT04893E

Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters

Nicole L. Lampland, Aradhana Pindwal, Steven R. Neal, Shealyn Schlauderaff, Arkady Ellern and Aaron D. Sadow

Chem. Sci., 2015, 6, 6901
DOI: 10.1039/C5SC02435H

Practical and selective hydroboration of aldehydes and ketones in air catalysed by an iron(ii) coordination polymer

Guoqi Zhang, Jessica Cheng, Kezia Davis, Mary Grace Bonifacio and Cynthia Zajaczkowski

Green Chem., 2019, 21, 1114
DOI: 10.1039/C9GC00078J

Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

Mahadev L. Shegavi, Ashim Baishya, K. Geetharani and Shubhankar Kumar Bose

Org. Chem. Front., 2018, 5, 3520
DOI: 10.1039/C8QO00912K

Alkali metal complexes as efficient catalysts for hydroboration and cyanosilylation of carbonyl compounds

Adimulam Harinath, Jayeeta Bhattacharjee, Hari Pada Nayek and Tarun K. Panda

Dalton Trans., 2018, 47, 12613
DOI: 10.1039/C8DT02032A

Borohydride intermediates pave the way for magnesium-catalysed enantioselective ketone reduction

Vladislav Vasilenko, Clemens K. Blasius, Hubert Wadepohl and Lutz H. Gade

Chem. Commun., 2020, 56, 1203
DOI: 10.1039/C9CC09111D

Mechanistic insights into neosilyllithium-catalyzed hydroboration of nitriles, aldehydes, and esters: a DLPNO-CCSD(T) study

Mridula Choudhary, Tarun K. Panda and Saurabh Kumar Singh

Phys. Chem. Chem. Phys., 2025, 27, 20237
DOI: 10.1039/D5CP02589C

Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

Soumen Sinhababu, Dharmendra Singh, Mahendra Kumar Sharma, Rahul Kumar Siwatch, Pritam Mahawar and Selvarajan Nagendran

Dalton Trans., 2019, 48, 4094
DOI: 10.1039/C8DT05121F

Regioselective Ring Opening Reactions of Pyridine N-Oxide Analogues by Magnesium Hydride Complexes

Hongyan Xie, Xinli Liu and Dongmei Cui

Organometallics, 2017, 36, 3597
DOI: 10.1021/acs.organomet.7b00517

Tris(cyclopentadienyl)lanthanide Complexes as Catalysts for Hydroboration Reaction toward Aldehydes and Ketones

Sufang Chen, Dandan Yan, Mingqiang Xue, Yubiao Hong, Yingming Yao and Qi Shen

Org. Lett., 2017, 19, 3382
DOI: 10.1021/acs.orglett.7b01335

Dehydrogenative borylation: the dark horse in metal-catalyzed hydroborations and diborations?

Stephen J. Geier and Stephen A. Westcott

Reviews in Inorganic Chemistry, 2015, 35, 69
DOI: 10.1515/revic-2014-0008

Beyond Hydrofunctionalisation: A Well‐Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation

Sandeep Yadav, Ruchi Dixit, Kumar Vanka and Sakya S. Sen

Chemistry A European J, 2018, 24, 1269
DOI: 10.1002/chem.201705795

Manganese‐Catalyzed Hydroborations with Broad Scope

Pradip Ghosh and Axel Jacobi von Wangelin

Angew Chem Int Ed, 2021, 60, 16035
DOI: 10.1002/anie.202103550

Molecular Main Group Metal Hydrides

Matthew M. D. Roy, Alvaro A. Omaña, Andrew S. S. Wilson, Michael S. Hill, Simon Aldridge and Eric Rivard

Chem. Rev., 2021, 121, 12784
DOI: 10.1021/acs.chemrev.1c00278

Selective Depolymerization of Polyurethanes into Borylated N,N′-Dimethyldiamines Mediated by Supported Lanthanum Complex La(CH2C6H4NMe2-o)3@SBA-15

Zheyu Zhao, Yansong Ma, Jue Chen, Binfeng Jiang and Yunjie Luo

Inorg. Chem., 2026, 65, 4658
DOI: 10.1021/acs.inorgchem.5c05893

Aluminum-Catalyzed Hydroboration of Alkenes

Alessandro Bismuto, Michael J. Cowley and Stephen P. Thomas

ACS Catal., 2018, 8, 2001
DOI: 10.1021/acscatal.7b04279

Magnesium complexes in hydroelementation and reduction catalysis: Opportunities and challenges

Marc Magre, Marcin Szewczyk and Magnus Rueping

Current Opinion in Green and Sustainable Chemistry, 2021, 32, 100526
DOI: 10.1016/j.cogsc.2021.100526

Polynuclear lanthanide–diketonato clusters for the catalytic hydroboration of carboxamides and esters

Sem Raj Tamang, Arpita Singh, Deepika Bedi, Adineh Rezaei Bazkiaei, Audrey A. Warner, Keeley Glogau, Corey McDonald, Daniel K. Unruh and Michael Findlater

Nat Catal, 2020, 3, 154
DOI: 10.1038/s41929-019-0405-5

Hydrophosphanylation of Alkynes via Magnesium Complexes: Evidence for Ligand Dependency in Structure–Activity Relationships

Darakshan Parveen, Sneha Mittal, Radhika Shrivas, Biswarup Pathak and Dipak Kumar Roy

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500002

Ring‐Shaped Phosphinoamido‐Magnesium‐Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis

Lea Fohlmeister and Andreas Stasch

Chemistry A European J, 2016, 22, 10235
DOI: 10.1002/chem.201601623

Magnesium-Promoted Selectively Reduction of Unprotected Indoles and Quinoxalines

Nana Wei, Wanzhen Guo, Xing Lu, Zhiqiang Ren, Haojie Ma, Yuqi Zhang, Jijiang Wang and Bo Han

Chinese Journal of Organic Chemistry, 2026, 46, 1027
DOI: 10.6023/cjoc202508021

Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

Gajanan M. Pawar, John B. Sheridan and Frieder Jäkle

Eur J Inorg Chem, 2016, 2016, 2227
DOI: 10.1002/ejic.201501373

Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications

Lixing Zhao, Chenyang Hu, Xuefeng Cong, Gongda Deng, Liu Leo Liu, Meiming Luo and Xiaoming Zeng

J. Am. Chem. Soc., 2021, 143, 1618
DOI: 10.1021/jacs.0c12318

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well‐Defined Manganese Complex

Guoqi Zhang, Haisu Zeng, Jing Wu, Zhiwei Yin, Shengping Zheng and James C. Fettinger

Angewandte Chemie, 2016, 128, 14581
DOI: 10.1002/ange.201607579

La[N(SiMe3)2]3‐Catalyzed Hydroboration of Esters and Other Challenging Unsaturated Groups

Xiaojuan Xu, Zihan Kang, Dandan Yan and Mingqiang Xue

Chin. J. Chem., 2019, 37, 1142
DOI: 10.1002/cjoc.201900344

Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe2)2 by Amine‐Exchange Reaction

Koichi Shinohara, Hayato Tsurugi, Reiner Anwander and Kazushi Mashima

Chemistry A European J, 2020, 26, 14130
DOI: 10.1002/chem.202002011

Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations

Naresh Eedugurala, Megan Hovey, Hung-An Ho, Barun Jana, Nicole L. Lampland, Arkady Ellern and Aaron D. Sadow

Organometallics, 2015, 34, 5566
DOI: 10.1021/acs.organomet.5b00771

Magnesium-Catalyzed CO2 Reduction to Formic Acid or Methanol: Solvent or No Solvent Settles the Selectivity

Biplab Mahata, Nripen Khilari, Debasis Koley and Sakya S. Sen

Inorg. Chem., 2026, 65, 8793
DOI: 10.1021/acs.inorgchem.6c01255

Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds

Yuanyuan Li, Haohua Chen, Lingbo Qu, Ruopeng Bai and Yu Lan

Chinese Chemical Letters, 2019, 30, 2249
DOI: 10.1016/j.cclet.2019.06.001

1,2-Hydroboration of Pyridines by Organomagnesium

Xinli Liu, Bingwen Li, Xiufang Hua and Dongmei Cui

Org. Lett., 2020, 22, 4960
DOI: 10.1021/acs.orglett.0c01388

Magnesium Catalysis for the Hydroboration of Carbodiimides

Catherine Weetman, Michael S. Hill and Mary F. Mahon

Chemistry A European J, 2016, 22, 7158
DOI: 10.1002/chem.201600681

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes

Yumeng Xi and John F. Hartwig

J. Am. Chem. Soc., 2017, 139, 12758
DOI: 10.1021/jacs.7b07124

Nucleophilic Magnesium Silanide and Silaamidinate Derivatives

Bibian Okokhere-Edeghoghon, Maximilian Dehmel, Michael S. Hill, Robert Kretschmer, Mary F. Mahon, Claire L. McMullin, Louis J. Morris and Nasir A. Rajabi

Inorg. Chem., 2020, 59, 13679
DOI: 10.1021/acs.inorgchem.0c02034

A N‐Heterocyclic Carbene‐Supported Zinc Catalyst for the 1,2‐Regioselective Hydroboration of N‐Heteroarenes

Sumana Mondal, Tejender Singh, Sudip Baguli, Soumya Ghosh and Debabrata Mukherjee

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300508

Cobalt(II) Coordination Polymer as a Precatalyst for Selective Hydroboration of Aldehydes, Ketones, and Imines

Jing Wu, Haisu Zeng, Jessica Cheng, Shengping Zheng, James A. Golen, David R. Manke and Guoqi Zhang

J. Org. Chem., 2018, 83, 9442
DOI: 10.1021/acs.joc.8b01094

Reduction of Cyclic and Linear Organic Carbonates Using a Readily Available Magnesium Catalyst

Marcin Szewczyk, Marc Magre, Viktoriia Zubar and Magnus Rueping

ACS Catal., 2019, 9, 11634
DOI: 10.1021/acscatal.9b04086

s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds

Marc Magre, Marcin Szewczyk and Magnus Rueping

Chem. Rev., 2022, 122, 8261
DOI: 10.1021/acs.chemrev.1c00641

Aluminum Hydrides Stabilized by N‐Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane

Daniel Franz, Lorenz Sirtl, Alexander Pöthig and Shigeyoshi Inoue

Zeitschrift anorg allge chemie, 2016, 642, 1245
DOI: 10.1002/zaac.201600313

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis

Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping

Angew Chem Int Ed, 2019, 58, 17567
DOI: 10.1002/anie.201908012

[(Me6TREN)MgOCHPh2][B(C6F5)4]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

Ankur, Ramkumar Kannan, Raju Chambenahalli, Sumanta Banerjee, Yan Yang, Laurent Maron and Ajay Venugopal

Eur J Inorg Chem, 2021, 2021, 4632
DOI: 10.1002/ejic.202100651

On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides

Alexa Caise, Barnabé Berger, Aidan Murray, Eugene Kolychev, Jamie Hicks, M. Ángeles Fuentes, Job J. C. Struijs, Jose M. Goicoechea and Simon Aldridge

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202517007

Manganese‐Catalyzed Hydroborations with Broad Scope

Pradip Ghosh and Axel Jacobi von Wangelin

Angewandte Chemie, 2021, 133, 16171
DOI: 10.1002/ange.202103550

Reactivity of [TismPriBenz]MgH and [TismPriBenz]MgMe towards Carbonyl Compounds: Access to Terminal Alkoxide and Enolate Complexes

David A. Vaccaro, Ran Yan and Gerard Parkin

Organometallics, 2024, 43, 746
DOI: 10.1021/acs.organomet.3c00541

Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation

Yaoyu Liang, Uttam Kumar Das, Jie Luo, Yael Diskin-Posner, Liat Avram and David Milstein

J. Am. Chem. Soc., 2022, 144, 19115
DOI: 10.1021/jacs.2c08491

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis

Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping

Angewandte Chemie, 2019, 131, 17731
DOI: 10.1002/ange.201908012

Reactivity of [TismPriBenz]MgH and [TismPriBenz]MgMe Towards Esters: Alkoxide Elimination and C–C Bond Formation

David A. Vaccaro, Ran Yan and Gerard Parkin

Organometallics, 2025, 44, 1893
DOI: 10.1021/acs.organomet.5c00190

Lithium diisobutyl‐tert‐butoxyaluminum hydride promoted ester hydroboration: An efficient protocol under solvent‐free conditions at room temperature

Hwan Hwi Kim, Hyun Ji Han, Ashok Kumar Jaladi and Duk Keun An

Bulletin Korean Chem Soc, 2025, 46, 516
DOI: 10.1002/bkcs.70017

Catalytic hydrogenation of acetone to isopropyl alcohol with CAl3MgH2¯ containing planar tetracoordinate carbon

Abdul Hamid Malhan and Krishnan Thirumoorthy

Front. Chem., 2026, 13
DOI: 10.3389/fchem.2025.1750798

N-Methylation and Trideuteromethylation of Amines via Magnesium-Catalyzed Reduction of Cyclic and Linear Carbamates

Marc Magre, Marcin Szewczyk and Magnus Rueping

Org. Lett., 2020, 22, 3209
DOI: 10.1021/acs.orglett.0c00988

An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

Zhi Yang, Mingdong Zhong, Xiaoli Ma, Karikkeeriyil Nijesh, Susmita De, Pattiyil Parameswaran and Herbert W. Roesky

J. Am. Chem. Soc., 2016, 138, 2548
DOI: 10.1021/jacs.6b00032

Efficient and Selective Iron-Complex-Catalyzed Hydroboration of Aldehydes

Uttam K. Das, Carolyn S. Higman, Bulat Gabidullin, Jason E. Hein and R. Tom Baker

ACS Catal., 2018, 8, 1076
DOI: 10.1021/acscatal.7b03785

Catalytic hydrogenation of alkyne with planar tetracoordinate carbon in CAl3MgH2¯ system

Abdul Hamid Malhan and Krishnan Thirumoorthy

Front. Chem., 2025, 13
DOI: 10.3389/fchem.2025.1672968

Ruthenium-Catalyzed Selective Hydroboration of Nitriles and Imines

Akash Kaithal, Basujit Chatterjee and Chidambaram Gunanathan

J. Org. Chem., 2016, 81, 11153
DOI: 10.1021/acs.joc.6b02122

Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation

Marc Magre, Eva Paffenholz, Bholanath Maity, Luigi Cavallo and Magnus Rueping

J. Am. Chem. Soc., 2020, 142, 14286
DOI: 10.1021/jacs.0c05917

A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration

Jacob B. Geri and Nathaniel K. Szymczak

J. Am. Chem. Soc., 2015, 137, 12808
DOI: 10.1021/jacs.5b08406

n‐Butyllithium (1 mol %)‐catalyzed Hydroboration of Aldehydes and Ketones with Pinacolborane

Su Jin Yang, Ashok Kumar Jaladi, Jea Ho Kim, Shankaraiah Gundeti and Duk Keun An

Bulletin Korean Chem Soc, 2019, 40, 34
DOI: 10.1002/bkcs.11635

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes

Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping

Angewandte Chemie, 2019, 131, 7099
DOI: 10.1002/ange.201902188

Story of Hydroboration: Experimentally Generated Mechanistic Insights

Siyuan Zhai, Milena Petković and Dragoslav Vidović

Organometallics, 2023, 42, 1573
DOI: 10.1021/acs.organomet.3c00151

La[N(SiMe3)2]3-Catalyzed Deoxygenative Reduction of Amides with Pinacolborane. Scope and Mechanism

Christopher J. Barger, Rachel D. Dicken, Victoria L. Weidner, Alessandro Motta, Tracy L. Lohr and Tobin J. Marks

J. Am. Chem. Soc., 2020, 142, 8019
DOI: 10.1021/jacs.0c02446

Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds

Che Chang Chong, Hajime Hirao and Rei Kinjo

Angew Chem Int Ed, 2015, 54, 190
DOI: 10.1002/anie.201408760

Organoactinide‐Catalyzed Monohydroboration of Carbodiimides

Heng Liu, Kseniya Kulbitski, Matthias Tamm and Moris S. Eisen

Chemistry A European J, 2018, 24, 5738
DOI: 10.1002/chem.201705987

Bulky guanidinate stabilized homoleptic magnesium, calcium and zinc complexes and their catalytic activity in the Tishchenko reaction

Milan Kr Barman, Ashim Baishya and Sharanappa Nembenna

Journal of Organometallic Chemistry, 2015, 785, 52
DOI: 10.1016/j.jorganchem.2015.02.044

Recent developments in the reduction of unsaturated bonds by magnesium precursors

Indrani Banerjee and Tarun K. Panda

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6333

Potassium Fluoride‐Catalyzed Hydroboration of Aldehydes and Ketones: Facile Reduction to Primary and Secondary Alcohols

Krzysztof Kuciński and Grzegorz Hreczycho

Eur J Org Chem, 2020, 2020, 552
DOI: 10.1002/ejoc.201901514

Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds

Che Chang Chong, Hajime Hirao and Rei Kinjo

Angewandte Chemie, 2015, 127, 192
DOI: 10.1002/ange.201408760

Copper(II)-Catalyzed Selective Hydroboration of Ketones and Aldehydes

Haisu Zeng, Jing Wu, Sihan Li, Christina Hui, Anita Ta, Shu-Yuan Cheng, Shengping Zheng and Guoqi Zhang

Org. Lett., 2019, 21, 401
DOI: 10.1021/acs.orglett.8b03583

Homoleptic Lanthanide Amide Catalysts for Organic Synthesis: Experiment and Theory

Rachel D. Dicken, Alessandro Motta and Tobin J. Marks

ACS Catal., 2021, 11, 2715
DOI: 10.1021/acscatal.0c04882

Recent Developments in Homogeneous Organomagnesium Catalysis

Raphaël Rochat, Michael J. Lopez, Hayato Tsurugi and Kazushi Mashima

ChemCatChem, 2016, 8, 10
DOI: 10.1002/cctc.201500853

Lithium tert‐Butoxide‐catalyzed Hydroboration of Carbonyl Compounds

Jea Ho Kim, Ashok Kumar Jaladi, Hyun Tae Kim and Duk Keun An

Bulletin Korean Chem Soc, 2019, 40, 971
DOI: 10.1002/bkcs.11855

N-Heterocyclic Carbene-Phosphinidenide Complexes as Hydroboration Catalysts

Jayeeta Bhattacharjee, Dirk Bockfeld and Matthias Tamm

J. Org. Chem., 2022, 87, 1098
DOI: 10.1021/acs.joc.1c02377

Magnesium-Catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines

Nicole L. Lampland, Megan Hovey, Debabrata Mukherjee and Aaron D. Sadow

ACS Catal., 2015, 5, 4219
DOI: 10.1021/acscatal.5b01038

Advancing Propylene Epoxidation: the Role of Ethyl Acetate Autoxidation via Cobalt‐Nickel Catalyzed C(acyl)─O Bond Scission

Yaorong He, Chao Xiong, Luotian Lv, Dongpo Li, Sixuan Shi, Can Xue and Hongbing Ji

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500384

Hydroboration, Cyanosilylation, and Sequential Cyanosilylation and Hydroboration of Carbonyl Compounds in the Presence of a TiIV Amido Complex as an Efficient Catalyst

Adimulam Harinath, Jayeeta Bhattcharjee, Koteswar Rao Gorantla, Bhabani S. Mallik and Tarun K. Panda

Eur J Org Chem, 2018, 2018, 3180
DOI: 10.1002/ejoc.201800547

Aluminium‐Catalyzed Selective Hydroboration of Esters and Epoxides to Alcohols: C−O Bond Activation

Nabin Sarkar, Rajata Kumar Sahoo and Sharanappa Nembenna

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203023

Catalytic Hydroboration of Esters by Versatile Thorium and Uranium Amide Complexes

Konstantin Makarov, Alexander Kaushansky and Moris S. Eisen

ACS Catal., 2022, 12, 273
DOI: 10.1021/acscatal.1c04799

Dinuclear Magnesium-Catalyzed Hydroboration: Unveiling Metal–Ligand Cooperative Activation of Polar Unsaturated Bonds

Hengxu Li, Mingjie Fan and Qiang Liu

J. Am. Chem. Soc., 2025, 147, 37708
DOI: 10.1021/jacs.5c13113

tBuOLi-Promoted Hydroboration of Esters and Epoxides

Yinyin Shi, Yue Wang, Zhefan Huang, Fangjun Zhang and Yinlin Shao

ACS Omega, 2022, 7, 18876
DOI: 10.1021/acsomega.2c01866

Reduction of Carboxamides Into Amines Catalyzed by La[NH‐2,6‐iPr2‐4‐FcC6H2]3/HBpin

Qiujin Ye, Yukun Wang, Jue Chen and Yunjie Luo

Applied Organom Chemis, 2024, 38
DOI: 10.1002/aoc.7739

Catalytic hydroboration of aldehydes and ketones with sodium hydride: Application to chemoselective reduction of aldehydes over ketones

Won Kyu Shin, Hanbi Kim, Ashok Kumar Jaladi and Duk Keun An

Tetrahedron, 2018, 74, 6310
DOI: 10.1016/j.tet.2018.09.031

Redox-Noninnocent Ligand-Supported Vanadium Catalysts for the Chemoselective Reduction of C═X (X = O, N) Functionalities

Guoqi Zhang, Jing Wu, Shengping Zheng, Michelle C. Neary, Jincheng Mao, Marco Flores, Ryan J. Trovitch and Pavel A. Dub

J. Am. Chem. Soc., 2019, 141, 15230
DOI: 10.1021/jacs.9b07062

Heteroleptic Magnesium n-Butyl on a Chemically Non-innocent 2-Anilidomethylpyridine Ligand Leading to Diverse Magnesium Hydrides

Chhotan Mandal, Shalini Joshi, Sabyashachi Mishra and Debabrata Mukherjee

Inorg. Chem., 2024, 63, 15692
DOI: 10.1021/acs.inorgchem.4c01612

Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration

Naresh Eedugurala, Zhuoran Wang, Umesh Chaudhary, Nicholas Nelson, Kapil Kandel, Takeshi Kobayashi, Igor I. Slowing, Marek Pruski and Aaron D. Sadow

ACS Catal., 2015, 5, 7399
DOI: 10.1021/acscatal.5b01671

Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)2

Chong Yu, Chenjun Guo, Linhong Jiang, Mingliang Gong and Yunjie Luo

Organometallics, 2021, 40, 1201
DOI: 10.1021/acs.organomet.1c00120

Metal-Free Catalytic Reduction of α,β-Unsaturated Esters by 1,3,2-Diazaphospholene and Subsequent C–C Coupling with Nitriles

Che Chang Chong, Bin Rao and Rei Kinjo

ACS Catal., 2017, 7, 5814
DOI: 10.1021/acscatal.7b01338

Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

Yoon Kyung Jang, Marc Magre and Magnus Rueping

Org. Lett., 2019, 21, 8349
DOI: 10.1021/acs.orglett.9b03131

Magnesium‐Catalyzed Tandem Dehydrogenation‐Dehydrocoupling: An Atom Economical Access to Alkynylboranes

Mélodie Birepinte, Virginie Liautard, Laurent Chabaud and Mathieu Pucheault

Chemistry A European J, 2020, 26, 3236
DOI: 10.1002/chem.201905772

The Hidden Role of Boranes and Borohydrides in Hydroboration Catalysis

Andrew D. Bage, Kieran Nicholson, Thomas A. Hunt, Thomas Langer and Stephen P. Thomas

ACS Catal., 2020, 10, 13479
DOI: 10.1021/acscatal.0c04051

Iron-borane catalyzed carbonyl hydroboration and isolation of an iron(I)-ketyl radical

Laura A. Grose, Ryan J. Schwamm, Adam Brookfield, David Robinson and Darren Willcox

Nat Commun, 2026, 17
DOI: 10.1038/s41467-026-69500-2

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

Ross McLellan, Alan R. Kennedy, Robert E. Mulvey, Samantha A. Orr and Stuart D. Robertson

Chemistry A European J, 2017, 23, 16853
DOI: 10.1002/chem.201703609

Reduction of Amides to Amines with Pinacolborane Catalyzed by Heterogeneous Lanthanum Catalyst La(CH2C6H4NMe2-o)3@SBA-15

Chenjun Guo, Fangcao Zhang, Chong Yu and Yunjie Luo

Inorg. Chem., 2021, 60, 13122
DOI: 10.1021/acs.inorgchem.1c01531

N-Heterocyclic Carbene–Carbodiimide (“NHC–CDI”) Adduct or Zwitterionic-Type Neutral Amidinate-Supported Magnesium(II) and Zinc(II) Complexes

Ashim Baishya, Lokesh Kumar, Milan Kr. Barman, Himansu S. Biswal and Sharanappa Nembenna

Inorg. Chem., 2017, 56, 9535
DOI: 10.1021/acs.inorgchem.7b00879

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage

Smita Patnaik and Aaron D. Sadow

Angew Chem Int Ed, 2019, 58, 2505
DOI: 10.1002/anie.201813305

Magnesium-Catalyzed Primary, Secondary, and Tertiary Amide Hydroboration

Biplab Mahata, V. Devaraj, Soumya Ranjan Dash, Rajesh G. Gonnade, Kumar Vanka and Sakya S. Sen

Inorg. Chem., 2025, 64, 13405
DOI: 10.1021/acs.inorgchem.5c01787

Readily available lithium compounds as catalysts for the hydroboration of carbodiimides and esters

Milan Kumar Bisai, Kritika Gour, Tamal Das, Kumar Vanka and Sakya S. Sen

Journal of Organometallic Chemistry, 2021, 949, 121924
DOI: 10.1016/j.jorganchem.2021.121924

Novel aluminium compounds derived from Schiff bases: Synthesis, characterization and catalytic performance in hydroboration

Da Jin, Xiaoli Ma, Yashuai Liu, Jiong Peng and Zhi Yang

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.4637

Transforming Hydroxide-Containing Metal–Organic Framework Nodes for Transition Metal Catalysis

Xuanyu Feng, Yang Song and Wenbin Lin

Trends in Chemistry, 2020, 2, 965
DOI: 10.1016/j.trechm.2020.08.009

Selective Hydroboration of Carboxylic Acids with a Homogeneous Manganese Catalyst

Milan K. Barman, Kuhali Das and Biplab Maji

J. Org. Chem., 2019, 84, 1570
DOI: 10.1021/acs.joc.8b03108

Modification of Yttrium Silyl‐Bridged Amide Alkyl Complexes through Si−H/C−H Cross‐Dehydrocoupling of Silanes with a Silylamino Ligand: Synthesis, Reactivity, and Mechanism

Qing You, Jie Zhang and Xigeng Zhou

Chemistry A European J, 2020, 26, 7702
DOI: 10.1002/chem.202001207

Advancing Propylene Epoxidation: the Role of Ethyl Acetate Autoxidation via Cobalt‐Nickel Catalyzed C(acyl)─O Bond Scission

Yaorong He, Chao Xiong, Luotian Lv, Dongpo Li, Sixuan Shi, Can Xue and Hongbing Ji

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500384

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

Lara E. Lemmerz, Ross McLellan, Neil R. Judge, Alan R. Kennedy, Samantha A. Orr, Marina Uzelac, Eva Hevia, Stuart D. Robertson, Jun Okuda and Robert E. Mulvey

Chemistry A European J, 2018, 24, 9940
DOI: 10.1002/chem.201801541

Hydroboration of nitriles, esters, and amides catalyzed by simple neosilyllithium

Gobbilla Sai Kumar, Jayeeta Bhattacharjee, Kusum Kumari, Shruti Moorthy, Ayan Bandyopadhyay, Saurabh Kumar Singh and Tarun K. Panda

Polyhedron, 2022, 219, 115784
DOI: 10.1016/j.poly.2022.115784

A review of thermal homogeneous catalytic deoxygenation reactions for valuable products

Zhaoni Kong, Liang He, Yuzheng Shi, Qingqing Guan and Ping Ning

Heliyon, 2020, 6, e03446
DOI: 10.1016/j.heliyon.2020.e03446

Magnesium-Catalyzed Regioselective Hydrophosphinylation of Alkenes with Diarylphosphine Oxides

Lei Zhang, Shaokun Bai and Lijiao Zheng

Organometallics, 2023, 42
DOI: 10.1021/acs.organomet.3c00247

Lithium Bromide/HBpin: A Mild and Effective Catalytic System for the Selective Hydroboration of Aldehydes and Ketones

Hanbi Kim, Hye Lim Shin, Jaeeun Yi, Hyeon Seong Choi, Ji Hye Lee, Hyonseok Hwang and Duk Keun An

Bulletin Korean Chem Soc, 2020, 41, 1009
DOI: 10.1002/bkcs.12103

Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N–H Activation by Metal–Ligand Cooperation as Key Steps

Yaoyu Liang, Jie Luo, Yael Diskin-Posner and David Milstein

J. Am. Chem. Soc., 2023, 145, 9164
DOI: 10.1021/jacs.3c01091

Bimetallic Bis-anion Cascade Complexes of Magnesium in Nonaqueous Solution

David Van Craen, Ian G. Flynn, Veronica Carta and Amar H. Flood

Inorg. Chem., 2020, 59, 5939
DOI: 10.1021/acs.inorgchem.9b03710

La[N(SiMe3)2]3-Catalyzed Ester Reductions with Pinacolborane: Scope and Mechanism of Ester Cleavage

Christopher J. Barger, Alessandro Motta, Victoria L. Weidner, Tracy L. Lohr and Tobin J. Marks

ACS Catal., 2019, 9, 9015
DOI: 10.1021/acscatal.9b02605

Fluorenyl-tethered N-heterocyclic carbene: An effective ancillary support for heteroleptic magnesium organometallics

Sumana Mondal, Subham Sarkar, Dibyendu Mallick and Debabrata Mukherjee

Polyhedron, 2024, 251, 116849
DOI: 10.1016/j.poly.2024.116849

Lanthanide Mimicking by Magnesium for Oxazolidinone Synthesis

Rohit Kumar, Biplab Mahata, S. Gayathridevi, K. Vipin Raj, Kumar Vanka and Sakya S. Sen

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303478

Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis

Bhupendra Goswami, Thomas J. Feuerstein, Ravi Yadav, Ralf Köppe, Sergei Lebedkin, Manfred M. Kappes and Peter W. Roesky

Chemistry A European J, 2021, 27, 4401
DOI: 10.1002/chem.202004833

Monomeric Magnesium Catalyzed Alkene and Alkyne Hydroboration

Rohit Kumar, Sayan Dutta, Vishal Sharma, Praval P. Singh, Rajesh G. Gonnade, Debasis Koley and Sakya S. Sen

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201896

Catalytic ester hydroboration promoted by actinide complexes featuring six-membered N-heterocyclic imine ligands and actinide-alkoxides activation

Konstantin Makarov, Natalia Fridman and Moris S. Eisen

Commun Chem, 2025, 8
DOI: 10.1038/s42004-025-01711-y

n-Butyllithium Catalyzed Selective Hydroboration of Aldehydes and Ketones

Zhangye Zhu, Xueli Wu, Xiaojuan Xu, Zhenjie Wu, Mingqiang Xue, Yingming Yao, Qi Shen and Xiaoguang Bao

J. Org. Chem., 2018, 83, 10677
DOI: 10.1021/acs.joc.8b01495

Group 2 Catalysis for the Atom‐Efficient Synthesis of Imidazolidine and Thiazolidine Derivatives

Merle Arrowsmith, Michael S. Hill and Gabriele Kociok‐Köhn

Chemistry A European J, 2015, 21, 10548
DOI: 10.1002/chem.201501328

ChemInform Abstract: Magnesium‐Catalyzed Hydroboration of Esters: Evidence for a New Zwitterionic Mechanism.

Debabrata Mukherjee, Arkady Ellern and Aaron D. Sadow

ChemInform, 2014, 45
DOI: 10.1002/chin.201429202

Magnesium-mediated hydroboration under ambient condition: A reduction of esters, aldehydes, and ketones

Hyun Ji Han, Hyun Tae Kim, Jaeho Kim, Ashok Kumar Jaladi and Duk Keun An

Tetrahedron, 2023, 142, 133500
DOI: 10.1016/j.tet.2023.133500

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

Marc Magre, Marcin Szewczyk and Magnus Rueping

Org. Lett., 2020, 22, 1594
DOI: 10.1021/acs.orglett.0c00184

Super hydride catalyzed ester and isocyanate hydroboration

Zonggang Du, Bedabyas Behera, Arun Kumar and Yi Ding

Journal of Organometallic Chemistry, 2021, 950, 121982
DOI: 10.1016/j.jorganchem.2021.121982

Amidophosphine Boranes as Hydroboration Reagents for Nitriles, Alkynes, and Carboxylic Acids

Ravi Kumar, Rohan Kumar Meher, Jyoti Sharma, Abhijit Sau and Tarun K. Panda

Org. Lett., 2023, 25, 7923
DOI: 10.1021/acs.orglett.3c03194

Metal‐Free Ammonia Borane‐Catalyzed Hydroboration of Lactones and Esters to Alcohols

Azamat Yessengazin, Bakdaulet Seisenkul, Samat Tussupbayev, Tolganay Andizhanova and Andrey Y. Khalimon

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400876

Determination of the Mechanism and True Catalyst in CO2 Hydroboration Catalyzed by the Low-Valent Magnesium(I) Dimer: A Computational Study

Lin Yang, Zhendong Li and Xiaoyan Li

J. Phys. Chem. A, 2026, 130, 2061
DOI: 10.1021/acs.jpca.5c07854

Green Synthesis of Electrophilic Alkenes Using a Magnesium Catalyst under Aqueous Conditions and Mechanistic Insights by Density Functional Theory

Pankaj Lal Kalar, Kavita Jain, Swatantra Agrawal, Siddique Khan, Rampal Vishwakarma, Ayush Shivhare, Milind M. Deshmukh and Kalpataru Das

J. Org. Chem., 2023, 88, 16829
DOI: 10.1021/acs.joc.3c01540

Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines

Hyun Ji Han, Suh Youn Park, So Eun Jeon, Jae Seok Kwak, Ji Hye Lee, Ashok Kumar Jaladi, Hyonseok Hwang and Duk Keun An

Molecules, 2023, 28, 7090
DOI: 10.3390/molecules28207090

Hydroboration of Nitriles, Esters, and Carbonates Catalyzed by Simple Earth‐Abundant Metal Triflate Salts

Ranjeesh Thenarukandiyil, Vanaparthi Satheesh, Linda J. W. Shimon and Graham de Ruiter

Chemistry An Asian Journal, 2021, 16, 999
DOI: 10.1002/asia.202100003

On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides

Alexa Caise, Barnabé Berger, Aidan Murray, Eugene Kolychev, Jamie Hicks, M. Ángeles Fuentes, Job J. C. Struijs, Jose M. Goicoechea and Simon Aldridge

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202517007

Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations

Teng Zhang, Kuntal Manna and Wenbin Lin

J. Am. Chem. Soc., 2016, 138, 3241
DOI: 10.1021/jacs.6b00849

Heteroleptic Four-Coordinate Tris(oxazolinyl)borato Iron(II) Compounds

Regina R. Reinig, Arkady Ellern and Aaron D. Sadow

Inorg. Chem., 2019, 58, 6044
DOI: 10.1021/acs.inorgchem.9b00359

Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide

Che Chang Chong and Rei Kinjo

ACS Catal., 2015, 5, 3238
DOI: 10.1021/acscatal.5b00428

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well‐Defined Manganese Complex

Guoqi Zhang, Haisu Zeng, Jing Wu, Zhiwei Yin, Shengping Zheng and James C. Fettinger

Angew Chem Int Ed, 2016, 55, 14369
DOI: 10.1002/anie.201607579

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage

Smita Patnaik and Aaron D. Sadow

Angewandte Chemie, 2019, 131, 2527
DOI: 10.1002/ange.201813305

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes

Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping

Angew Chem Int Ed, 2019, 58, 7025
DOI: 10.1002/anie.201902188

Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application

Bo Han, Jiong Zhang, Haijun Jiao and Lipeng Wu

Chinese Journal of Catalysis, 2021, 42, 2059
DOI: 10.1016/S1872-2067(21)63853-6

Supported Single-Site Ti(IV) on a Metal–Organic Framework for the Hydroboration of Carbonyl Compounds

Zhiyuan Huang, Dong Liu, Jeffrey Camacho-Bunquin, Guanghui Zhang, Dali Yang, Juan M. López-Encarnación, Yunjie Xu, Magali S. Ferrandon, Jens Niklas, Oleg G. Poluektov, Julius Jellinek, Aiwen Lei, Emilio E. Bunel and Massimiliano Delferro

Organometallics, 2017, 36, 3921
DOI: 10.1021/acs.organomet.7b00544

Magnesium‐Mediated Cyanosilylation and Hydroboration of Arene and N‐Heteroarene Aldehydes: An Experimental and Theoretical Study

Darakshan Parveen, Sougata Saha, Rahul Kumar Yadav, Swapan K. Pati and Dipak Kumar Roy

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401853

Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions

Kuntal Manna, Pengfei Ji, Francis X. Greene and Wenbin Lin

J. Am. Chem. Soc., 2016, 138, 7488
DOI: 10.1021/jacs.6b03689

Hydroboration of substituted alkynes using a solid polymeric carboxylic acid catalyst

Caroline B. Hoyt, Michele L. Sarazen and Christopher W. Jones

Journal of Catalysis, 2019, 369, 493
DOI: 10.1016/j.jcat.2018.11.021