C–H bond activation reactions by TpMe2Ir(iii) centres. Generation of Fischer-type carbenes and development of a catalytic system for H/D exchange

Laura L. Santos, Kurt Mereiter, Margarita Paneque, Christian Slugovc and Ernesto Carmona

New J. Chem., 2003, 27, 107
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Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry

Christophe Copéret, Mathieu Chabanas, Romain Petroff Saint‐Arroman and Jean‐Marie Basset

Angew Chem Int Ed, 2003, 42, 156
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Deuterium labeling of norbornene derivatives by iridium catalyzed H/D exchange catalysis

Christian Slugovc and Bernhard Perner

Inorganica Chimica Acta, 2004, 357, 3104
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Hydrogenolysis of Cycloalkanes on a Tantalum Hydride Complex Supported on Silica and Insight into the Deactivation Pathway by the Combined Use of 1D Solid‐State NMR and EXAFS Spectroscopies

Franck Rataboul, Mathieu Chabanas, Aimery de Mallmann, Christophe Copéret, Jean Thivolle‐Cazat and Jean‐Marie Basset

Chemistry A European J, 2003, 9, 1426
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Well-Defined Surface Species [(≡Si—O—)W(═O)Me3] Prepared by Direct Methylation of [(≡Si—O—)W(═O)Cl3], a Catalyst for Cycloalkane Metathesis and Transformation of Ethylene to Propylene

Ali Hamieh, Yin Chen, Safwat Abdel-Azeim, Edy Abou-hamad, Serena Goh, Manoja Samantaray, Raju Dey, Luigi Cavallo and Jean Marie Basset

ACS Catal., 2015, 5, 2164
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C−H Bond Activation by a Hydrotris(pyrazolyl)borato Ruthenium Hydride Complex

Siu Man Ng, Wai Han Lam, Chi Chuen Mak, Chun Wai Tsang, Guochen Jia, Zhenyang Lin and Chak Po Lau

Organometallics, 2003, 22, 641
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Homogene und heterogene Katalyse – Brückenschlag durch Oberflächen‐Organometallchemie

Christophe Copéret, Mathieu Chabanas, Romain Petroff Saint‐Arroman and Jean‐Marie Basset

Angewandte Chemie, 2003, 115, 164
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Isolated Surface Hydrides: Formation, Structure, and Reactivity

Christophe Copéret, Deven P. Estes, Kim Larmier and Keith Searles

Chem. Rev., 2016, 116, 8463
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C–H Bond Activation of Benzene, Toluene, 3,3‐Dimethyl‐1‐butene and Methane by Silica‐Supported TaV Imido Amido Surface Complex

Hong‐Peng Jia, Yasemin Kaya, Catherine Chow, Mostafa Taoufik and Elsje Alessandra Quadrelli

Zeitschrift anorg allge chemie, 2015, 641, 56
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C−H Bond Activation and Organometallic Intermediates on Isolated Metal Centers on Oxide Surfaces

Christophe Coperet

Chem. Rev., 2010, 110, 656
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Preparation and characterization of metallacalixarenes anchored to a mesoporous silica SBA-15 LP as potential catalysts

Jeff Espinas, Jeremie Pelletier, Kai C. Szeto, Nicolas Merle, Erwan Le Roux, Christine Lucas, Aimery De Mallmann, Jean-Marie Basset, Mostafa Taoufik and Jean Thivolle-Cazat

Microporous and Mesoporous Materials, 2014, 188, 77
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Metal–Metal Synergy in Well-Defined Surface Tantalum–Iridium Heterobimetallic Catalysts for H/D Exchange Reactions

Sébastien Lassalle, Ribal Jabbour, Pauline Schiltz, Pierrick Berruyer, Tanya K. Todorova, Laurent Veyre, David Gajan, Anne Lesage, Chloé Thieuleux and Clément Camp

J. Am. Chem. Soc., 2019, 141, 19321
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Surface Organometallic Chemistry of Main Group Elements: Selective Synthesis of Silica Supported [≡Si−OB(C6F5)3]−[HNEt2Ph]+

Nicolas Millot, Andrew Cox, Catherine C. Santini, Yann Molard and Jean-Marie Basset

Chem. Eur. J., 2002, 8, 1438
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CH Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes: Formation of a μ‐Alkylidene Hydride Complex, Its H–D Exchange, and β‐H Abstraction by a Hydride Ligand

Li Wang, Seth C. Hunter, Zhimin Song, Carlos A. Steren, Tianniu Chen, Zhenhong Wei, Hu Cai and Zi‐Ling Xue

Chemistry A European J, 2014, 20, 6033
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Poisoning Experiments Aimed at Discriminating Active and Less‐Active Sites of Silica‐Supported Tantalum Hydride for Alkane Metathesis

Guillaume Saggio, Mostafa Taoufik, Jean‐Marie Basset and Jean Thivolle‐Cazat

ChemCatChem, 2010, 2, 1594
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σ-Bond Metathesis of Alkanes on a Silica-Supported Tantalum(V) Alkyl Alkylidene Complex: First Evidence for Alkane Cross-Metathesis

Christophe Copéret, Olivier Maury, Jean Thivolle-Cazat and Jean-Marie Basset

Angew. Chem., 2001, 113, 2393
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Facile and Efficient Synthesis of the Surface Tantalum Hydride (≡SiO)2TaIIIH and Tris-Siloxy Tantalum (≡SiO)3TaIII Starting from Novel Tantalum Surface Species (≡SiO)TaMe4 and (≡SiO)2TaMe3

Yin Chen, Samy Ould-Chikh, Edy Abou-Hamad, Emmanuel Callens, Janet C. Mohandas, Syed Khalid and Jean-Marie Basset

Organometallics, 2014, 33, 1205
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Stabilizing reactive intermediates through site isolation

Christophe Copéret

Pure and Applied Chemistry, 2009, 81, 585
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Ammonia and Dinitrogen Activation by Surface Organometallic Chemistry on Silica‐Grafted Tantalum Hydrides

Catherine Chow, Mostafa Taoufik and Elsje Alessandra Quadrelli

Eur J Inorg Chem, 2011, 2011, 1349
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Reactivity of a Silica-Supported Mo Alkylidene Catalyst toward Alkanes: A DFT Study on the Metathesis of Propane

Estefanía Díaz, Albeiro Restrepo and Francisco Núñez-Zarur

Organometallics, 2018, 37, 2023
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Hydrogen/Deuterium Exchange Kinetics by a Silica-Supported Zirconium Hydride Catalyst: Evidence for a σ-Bond Metathesis Mechanism

Gary L. Casty, Michael G. Matturro, Gary R. Myers, Robert P. Reynolds and Richard B. Hall

Organometallics, 2001, 20, 2246
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Fabrication of atomically dispersed barium hydride catalysts for the synthesis of deuterated alkylarenes

Yongli Cai, Li Rao, Yun Wang, Fei Chang, Teng He, Yang Zhao, Jiafeng Yu, Hong Wen, Jingai Hao, Anan Wu, Bing-Tao Guan, Jianping Guo and Ping Chen

Nat Commun, 2025, 16
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H/D Exchange on Silica-Grafted Tantalum(V) Imido Amido [(≡SiO)2Ta(V)(NH)(NH2)] Synthesized from Either Ammonia or Dinitrogen: IR and DFT Evidence for Heterolytic Splitting of D2

Priscilla Avenier, Xavier Solans-Monfort, Laurent Veyre, Filippo Renili, Jean-Marie Basset, Odile Eisenstein, Mostafa Taoufik and Elsje Alessandra Quadrelli

Top Catal, 2009, 52, 1482
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