Issue 35, 2024

New insights into aging in LiNiO2 cathodes from high resolution paramagnetic NMR spectroscopy

Abstract

Bulk degradation processes are examined in the LiNiO2 cathode using high resolution solid-state NMR, combined with magnetometry and X-ray diffraction. Capacity decay is correlated with bulk heterogeneity, whereby multiple structural domains coexist in the charged state, and the Li content and electrochemical activity of these domains is unraveled for the first time.

Graphical abstract: New insights into aging in LiNiO2 cathodes from high resolution paramagnetic NMR spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
01 Febr. 2024
Accepted
02 Apr. 2024
First published
05 Apr. 2024

Chem. Commun., 2024,60, 4707-4710

New insights into aging in LiNiO2 cathodes from high resolution paramagnetic NMR spectroscopy

H. Nguyen, P. Kurzhals, M. Bianchini, K. Seidel and R. J. Clément, Chem. Commun., 2024, 60, 4707 DOI: 10.1039/D4CC00504J

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