Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation

Emanuele Spatola; Francesco Rispoli; Daniele Del Giudice; Roberta Cacciapaglia; Alessandro Casnati; Luciano Marchiò; Laura Baldini; Stefano Di Stefano

doi:10.1039/D1OB02096J

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Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation†

Emanuele Spatola,

‡^a Francesco Rispoli,

‡^b Daniele Del Giudice,

‡^a Roberta Cacciapaglia,

^a Alessandro Casnati,

^b Luciano Marchiò,

^b Laura Baldini

*^b and Stefano Di Stefano

*^a

Author affiliations

* Corresponding authors

^a Dipartimento di Chimica Università di Roma La Sapienza and ISB-CNR Sede Secondaria di Roma - Meccanismi di Reazione, P.le A. Moro 5, I-00185 Roma, Italy
E-mail: stefano.distefano@uniroma1.it

^b Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università degli Studi di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy
E-mail: laura.baldini@unipr.it

Abstract

The temporal control (ON/OFF/ON) of the fluorescence of a dichloromethane/acetonitrile 1 : 1 solution of calixarene 3 decorated with two pyrenyl moieties at the upper rim is attained by the addition of CCl₃CO₂H used as a convenient chemical fuel.

This article is part of the themed collection: Supramolecular chemistry in OBC

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DOI: https://doi.org/10.1039/D1OB02096J
Article type: Paper
Submitted: 26 Okt. 2021
Accepted: 12 Nov. 2021
First published: 12 Nov. 2021

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Org. Biomol. Chem., 2022,20, 132-138

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Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation

E. Spatola, F. Rispoli, D. Del Giudice, R. Cacciapaglia, A. Casnati, L. Marchiò, L. Baldini and S. Di Stefano, Org. Biomol. Chem., 2022, 20, 132 DOI: 10.1039/D1OB02096J

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Organic & Biomolecular Chemistry

Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation†

Abstract

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Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation

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