Issue 28, 2022

Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation

Abstract

To prepare N2-derived cationic boryldiazenido-tungsten complexes as models of semimetallic metal-borinium frustrated Lewis pairs activating N2, we have attempted halide abstraction from trans-(diarylboryl)diazenido-halo-tungsten complexes. Reactions with Tl+ led to adducts in which coordination of the cation differs depending on the boryldiazenide substituents and the ancillary ligand. Chloride scavenging was not observed.

Graphical abstract: Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation

Supplementary files

Article information

Article type
Communication
Submitted
18 Nov. 2021
Accepted
10 Dec. 2021
First published
10 Dec. 2021

Dalton Trans., 2022,51, 10697-10701

Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation

A. Bouammali, A. Coffinet, L. Vendier and A. Simonneau, Dalton Trans., 2022, 51, 10697 DOI: 10.1039/D1DT03905A

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