Issue 81, 2022

Data-driven efficient synthetic exploration of anionic lanthanide-based metal–organic frameworks

Abstract

The synthesis of lanthanide metal–organic frameworks with terephthalate (Ln-BDC-MOFs) was investigated using a data-driven approach. Visually mapping the previously reported synthetic conditions suggested the existence of unexplored search spaces for novel Ln-BDC-MOFs. By focusing on the unexplored chemical reaction space, we successfully synthesized a series of new anionic Ln-BDC-MOFs, KGF-15, which demonstrated potential as luminescent sensors for Cu2+ ions. This synthetic exploration approach can significantly reduce the experimental effort required to discover new materials.

Graphical abstract: Data-driven efficient synthetic exploration of anionic lanthanide-based metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
09 Sept. 2022
Accepted
16 Sept. 2022
First published
16 Sept. 2022

Chem. Commun., 2022,58, 11426-11429

Data-driven efficient synthetic exploration of anionic lanthanide-based metal–organic frameworks

Y. Kitamura, Y. Nakamura, K. Sugimoto, H. Yoshikawa and D. Tanaka, Chem. Commun., 2022, 58, 11426 DOI: 10.1039/D2CC04985F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements