Issue 82, 2022

Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Abstract

Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.

Graphical abstract: Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

Supplementary files

Article information

Article type
Communication
Submitted
24 Aug. 2022
Accepted
16 Sept. 2022
First published
16 Sept. 2022

Chem. Commun., 2022,58, 11507-11510

Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

C. J. McMonagle, G. F. Turner, I. Jones, D. R. Allan, M. R. Warren, K. V. Kamenev, S. Parsons, P. A. Wright and S. A. Moggach, Chem. Commun., 2022, 58, 11507 DOI: 10.1039/D2CC04649K

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