Issue 40, 2022

Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

Abstract

A covalent connection between two orthogonal functional groups (–NH2 and –OH) in metal–organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66–2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66–2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

Graphical abstract: Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

Supplementary files

Article information

Article type
Communication
Submitted
20 Febr. 2022
Accepted
06 Apr. 2022
First published
07 Apr. 2022

Chem. Commun., 2022,58, 5948-5951

Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

D. Kim, H. Yoo, K. Kim, D. Kim, K. T. Kim, C. Kim, J. Y. Kim, H. R. Moon and M. Kim, Chem. Commun., 2022, 58, 5948 DOI: 10.1039/D2CC01031C

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