Issue 25, 2022

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Abstract

Metal–organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo.

Graphical abstract: Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Supplementary files

Article information

Article type
Communication
Submitted
15 Febr. 2022
Accepted
25 Febr. 2022
First published
07 Marts 2022

Chem. Commun., 2022,58, 4028-4031

Author version available

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

K. M. Fahy, M. R. Mian, M. C. Wasson, F. A. Son, T. Islamoglu and O. K. Farha, Chem. Commun., 2022, 58, 4028 DOI: 10.1039/D2CC00925K

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