Issue 5, 2021

A self-assembled tetrathiafulvalene box

Abstract

A M8L2 metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.

Graphical abstract: A self-assembled tetrathiafulvalene box

Supplementary files

Article information

Article type
Research Article
Submitted
08 Dec. 2020
Accepted
07 Janv. 2021
First published
08 Janv. 2021

Org. Chem. Front., 2021,8, 883-890

A self-assembled tetrathiafulvalene box

S. Krykun, V. Croué, O. Alévêque, E. Levillain, M. Allain, C. Mézière, V. Carré, F. Aubriet, Z. Voïtenko, S. Goeb and M. Sallé, Org. Chem. Front., 2021, 8, 883 DOI: 10.1039/D0QO01543A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements