Issue 37, 2021

The electrochemical reduction of a flexible Mn(ii) salen-based metal–organic framework

Abstract

A new metal–organic framework (MOF) containing a Mn(II) salen complex (BET surface area = 967 ± 6 m2 g−1) undergoes a reversible crystalline-to-amorphous transformation. Experimental studies and computational calculations show that the MOF is stable to a one-electron reduction at more anodic potentials than the corresponding discrete complex.

Graphical abstract: The electrochemical reduction of a flexible Mn(ii) salen-based metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug. 2021
Accepted
29 Aug. 2021
First published
31 Aug. 2021

Dalton Trans., 2021,50, 12821-12825

The electrochemical reduction of a flexible Mn(II) salen-based metal–organic framework

M. B. Solomon, C. Hua, B. Chan, T. L. Church, S. M. Cohen, C. P. Kubiak, K. A. Jolliffe and D. M. D'Alessandro, Dalton Trans., 2021, 50, 12821 DOI: 10.1039/D1DT02589A

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