Issue 98, 2021

Pd-catalyzed bidentate auxiliary assisted remote C(sp3)–H functionalization

Abstract

Pd-catalyzed C–H functionalisation affords effective synthetic tools to construct C–C and C–X bonds. Despite the challenges, the distal functionalization of C(sp3)–H bonds has witnessed significant developments and the use of bidentate auxiliaries has garnished this area by providing an opportunity to control reactivity as well as selectivity beyond proximal sites. This article covers the recent developments on the Pd-catalyzed bidentate auxiliary-assisted distal C(sp3)–H functionalization and is categorized based on the nature of functionalizations.

Graphical abstract: Pd-catalyzed bidentate auxiliary assisted remote C(sp3)–H functionalization

Article information

Article type
Highlight
Submitted
20 Sept. 2021
Accepted
09 Nov. 2021
First published
10 Nov. 2021

Chem. Commun., 2021,57, 13221-13233

Pd-catalyzed bidentate auxiliary assisted remote C(sp3)–H functionalization

K. Talukdar, T. A. Shah, T. Sarkar, S. Roy, P. K. Maharana and T. Punniyamurthy, Chem. Commun., 2021, 57, 13221 DOI: 10.1039/D1CC05291H

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