Issue 93, 2021

Polypseudorotaxanes constructed from pillar[5]arenes and polyamides by interfacial polymerization

Abstract

Polypseudorotaxanes constructed from pillar[5]arene rings and polyamide chains were successfully synthesized by interfacial polymerization between diamines and dicarbonyl chlorides in the presence of pillar[5]arene. The dicarbonyl chloride length and the assocation constants of dicarbonyl chloride-pillar[5]arene complexes were important factors in producing polypseudorotaxanes with high cover ratio of pillar[5]arene rings.

Graphical abstract: Polypseudorotaxanes constructed from pillar[5]arenes and polyamides by interfacial polymerization

Supplementary files

Article information

Article type
Communication
Submitted
15 Aug. 2021
Accepted
25 Okt. 2021
First published
25 Okt. 2021

Chem. Commun., 2021,57, 12468-12471

Author version available

Polypseudorotaxanes constructed from pillar[5]arenes and polyamides by interfacial polymerization

T. Ogoshi, M. Yoshiki, T. Kakuta, T. Yamagishi and M. Mizuno, Chem. Commun., 2021, 57, 12468 DOI: 10.1039/D1CC04491E

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