Issue 72, 2021

Selective dimerization of a trinuclear mixed-metal sandwich complex: construction of an axially chiral metal skeleton

Abstract

Certain metal sandwich complexes undergo dimerization through metal–metal bond formation. Here, we found that a reductive dimerization of mixed-metal Pd2Pt or PdPt2 sandwich complexes proceeds through selective Pt–Pt bond formation. A restricted rotation at the Pt–Pt bond of the PdPt2 dimer gave a unique axially chiral structure derived from a heterometal arrangement in a mixed-metal cluster.

Graphical abstract: Selective dimerization of a trinuclear mixed-metal sandwich complex: construction of an axially chiral metal skeleton

Supplementary files

Article information

Article type
Communication
Submitted
10 Jūl. 2021
Accepted
09 Aug. 2021
First published
19 Aug. 2021

Chem. Commun., 2021,57, 9120-9123

Author version available

Selective dimerization of a trinuclear mixed-metal sandwich complex: construction of an axially chiral metal skeleton

H. Yamaura, K. Yamamoto and T. Murahashi, Chem. Commun., 2021, 57, 9120 DOI: 10.1039/D1CC03719F

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