Issue 8, 2019

Recent advances in iminyl radical-mediated catalytic cyclizations and ring-opening reactions

Abstract

Iminyl radicals have emerged as versatile synthons for N-heterocycle constructions and ring-opening reactions. Iminyl radicals are a special class of N-centered radicals that display unique reactivity, enable H-abstraction to generate more stable carbon radicals, and serve as radical-type electrophiles, thus providing opportunities to explore novel transformations.

Graphical abstract: Recent advances in iminyl radical-mediated catalytic cyclizations and ring-opening reactions

Article information

Article type
Perspective
Submitted
06 Dec. 2018
Accepted
17 Janv. 2019
First published
17 Janv. 2019

New J. Chem., 2019,43, 3254-3264

Recent advances in iminyl radical-mediated catalytic cyclizations and ring-opening reactions

W. Yin and X. Wang, New J. Chem., 2019, 43, 3254 DOI: 10.1039/C8NJ06165C

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