Issue 32, 2019

Stepwise and hysteretic sorption of CO2 in polycatenated metal–organic frameworks

Abstract

Two polycatenated metal–organic framework materials with different metal centers (Zn2+ for 1 and Cd2+ for 2) were synthesized, which underwent pronounced framework phase transition upon desolvation, and exhibited uncommon temperature-dependent stepwise adsorption and hysteretic desorption of CO2 around room temperature.

Graphical abstract: Stepwise and hysteretic sorption of CO2 in polycatenated metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
17 Maijs 2019
Accepted
08 Jūl. 2019
First published
08 Jūl. 2019

CrystEngComm, 2019,21, 4696-4700

Stepwise and hysteretic sorption of CO2 in polycatenated metal–organic frameworks

D. Chen and X. Zhang, CrystEngComm, 2019, 21, 4696 DOI: 10.1039/C9CE00760A

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