Issue 65, 2019

Thiocyanate radical mediated dehydration of aldoximes with visible light and air

Abstract

We developed a new means of activating aldoximes by an in situ generated thiocyanate radical from ammonium thiocyanate and molecular oxygen at room temperature. With a catalytic amount of organic dye aizenuranine as the photocatalyst, the dehydration of aldoximes proceeds smoothly under visible light irradiation, providing a simple to handle, excellent functional group tolerance, and metal-free protocol for a wide range of nitriles.

Graphical abstract: Thiocyanate radical mediated dehydration of aldoximes with visible light and air

Supplementary files

Article information

Article type
Communication
Submitted
12 Jūl. 2019
Accepted
18 Jūl. 2019
First published
18 Jūl. 2019

Chem. Commun., 2019,55, 9701-9704

Thiocyanate radical mediated dehydration of aldoximes with visible light and air

Y. Ban, J. Dai, X. Jin, Q. Zhang and Q. Liu, Chem. Commun., 2019, 55, 9701 DOI: 10.1039/C9CC05354A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements